• Title/Summary/Keyword: Thermal NOx

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Redox activities of spinel type metal oxides as oxygen carriers (산소공여매체로서의 스핀넬 구조 금속산화물의 redox 활성 연구)

  • Jeong, J.H.;Park, J.W.;Joo, Y.K.;Park, J.S.;Jung, H.;Lee, H.T.;Yoon, W.L.
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.11a
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    • pp.191-194
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    • 2002
  • 매체 순환식 연소(Chemical-Looping Combustion, CLC)는 금속 산화물(산소공여매체, oxygen carrier)의 산소를 이용하여 화석연료를 산화(연료 연소 공정)시키고, 환원된 금속을 다시 산화(매체 산화 공정)시키는 간접적인 연소 공정의 하나이다. 이 방식은 온실효과의 주발생원인 $CO_2$를 원천적으로 회수할 수 있고, 또한 화염이 없는 상태에서 연소반응이 진행됨으로 thermal NOx의 발생을 미연에 방지할 수 있어 고효율의 환경친화적인 연소공정이다.(중략)

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Flame Stability and Emission Characteristics of Can-type Burner for Condensing Gas Boiler (응축 가스보일러용 원통형 연소기의 화염 안정성 및 배기 특성)

  • 이석희;정영식;금성민;이창언
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2000.11a
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    • pp.237-242
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    • 2000
  • This study was carried out to optimize burner of the condensing gas boiler which can save energy by utilizing the latent heat of combustion gas and reduce pollutants emission. Three reasonable distances between burner and heat exchanger were decided through the experiments of model flat burner. The optimum burner geometry was determined from flame stability, pollutant emission characteristics and applicability to practical boiler system. The boiler designed by this research reaches turn-down ratio 5:1 in the domain of equivalence ratio 0.68∼0.85 and thermal efficiency of 98%. Emission of NOx and CO concentration was under 35ppm and 104ppm.

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Measurement of Efficiency and Flue Gas Concentration of 90 kW Woodchip Boiler (90kW급 우드칩 온수 보일러 특성 및 성능 시험)

  • Kang, Sae-Byul;Kim, Jong-Jin;Choi, Kyu-Sung;Lee, Woong-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.194-197
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    • 2008
  • We measured the efficiency and flue gas concentration of a 90kW woodchip boiler which is for heating water of lodging. At nominal operating condition, the fuel, woodchip is fed into the boiler at a rate of 22.6 kg/h. In order to determine the efficiency of the boiler, we measured the water flow rate, woodchip flow rate, heating value and water content of woodchip, temperature of inlet and outlet of heating water. The results of test show that the power output of the woodchip boiler is 90.0 kW(77,400 kcal/h) and the thermal efficiency of the boiler is 88.5%. By using a gas analyser, flue gas concentrations are measured. The results show that O2 in the flue gas is 10.2%, CO concentration is 393 ppm and NOx concentration is 74 ppm.

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Study on the Criteria of Raw Materials for RDF (폐기물 고형연료(RDF)의 원료 기준 연구)

  • Nho, Namsun;Shin, Daehyun;Bae, Dalhee;Kong, Seungdae;Cho, Seoyoung;Kim, Kwangho
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.187.1-187.1
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    • 2011
  • RDF(Refuse-Derived Fuel) is a fuel of pelletized form made of combustible solid wastes and can not only be used as alternative energy to fossil fuel but also solve troubles in thermal uses of incinerator. As the first stage for obtaining elementary data required to develop criteria of raw materials appropriate to RDF combustion facilities actively spread recently in Korea, preliminary experiments were conducted on CO, SOx, NOx and HCl production and reduction characteristics in combustion of RDF. RDF samples weighing 2~3 g per a sample were manufactured in a lab-scale way and combustion tests of RDF were carried out in electric furnace with quartz tube of 50 mm inside diameter.

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An Experimental Study on High Temperature and Low Oxygen Air Combustion (고온, 희박공기 연소에 관한 실험적 연구)

  • Chung, D.H.;Yang, J.B.;Noh, D.S.;Kim, W.B.
    • Journal of the Korean Society of Combustion
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    • v.3 no.1
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    • pp.49-57
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    • 1998
  • High temperature preheated and diluted air combustion has been developed as the technology to realize higher thermal efficiency. In this type of combustion, there are many interesting phenomena which cannot be observed in room temperature air combustion. The characteristics of the combustion, investigated using a 3500 kcal/h LPG fired test facility, are described. The flame is demonstrated to have a blue and green in color and has a large volume. As the preheated air temperature increased up to $1000\;^{\circ}C$, the NOx emission incrased exponentially over a few hundred ppm with 11% $O_2$ correction. But, it drastically reducedabout 20ppm when the air was diluted from 21% $O_2$ to 5% $O_2$.

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An Experimental Study on the Effect of Mixture Distribution in the Constant Volume Combustion Chamber on the Combustion Characteristics (정적 연소실내 혼합기 분포가 연소특성에 미치는 영향에 관한 실험적 연구)

  • 이기형;이창희;안용흠
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.10-18
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    • 2004
  • It is well known that the stratified charge combustion has many kind of advantages to combustion characteristics, such as higher thermal efficiency and less CO, NOx levels than conventional homogeneous mixture combustion. Although this combustion can be caused low fuel consumption, it is produced the high unburned hydrocarbon and soot levels because of different equivalence ratio in the combustion chamber. Moreover it has a lot of possibility of low output and misfire if the mixture gas would not be in existence around the spark plug. In this paper, fundamental studies for stratified combustion were carried out using a constant volume combustion chamber. The effect of locally mixture gas distribution according to control the direct injection and premixed injection in the chamber were examined experimentally. In addition, the effects of turbulence on stratified charge combustion process were observed by schlieren photography.

Unsteady Flamelet Modeling of Turbulent Nonpremixed Flames (비정상 층류화염편 모델을 이용한 비예혼합 난류화염 해석)

  • Kim, Seong-Ku;Kang, Sung-Mo;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.133-141
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    • 2000
  • The present study is focused on modeling the transient behavior of the local flame structure which is especially important for slow reaction processes, such as NOx formation in the radiating flame field. The recently developed unsteady flamelet model has been applied to analyze a steady, turbulent jet flame. Numerical results are compared with experimental data and numerical results of the conventional steady flamelet model. The numerical result reveals that the unsteady flamelet model correctly predicts the nonequilibrium effect upsteam and the subsequent decay of the superequilibrium radical concentrations the further downstream.

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Catalytically Stabilized Combustion Characteristics of Methane on Platinum Catalyst (백금 촉매에 의해 안정화된 메탄의 연소 특성)

  • Hwang, C.H.;Jeong, Y.S.;Lee, C.E.
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.152-161
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    • 2000
  • The catalytically stabilized combustion of $CH_4$-air mixture on platinum catalyst was investigated numerically using a 2-D boundary layer model with detailed heterogeneous and homogeneous chemistries. The actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. The comparisons were made between results for cases where only heterogeneous chemistry was allowed and both heterogeneous and homogeneous chemistries were allowed. It was found that the homogeneous reaction in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. The contributions of each reactions related with CO formation were discussed on the surface. The effects of operation conditions such as equivalence ratio, temperature, velocity and pressure at the entrance were studied. In thermal combustor, CO and NOx was produced less than 1 ppm at the exit and the production of $N_{2}O$ was more dominant than that of NO.

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Unsteady Flamelet Modeling of Turbulent Nonpremixed Flames (비정상 층류화염편 모델을 이용한 비예혼합 난류화염 해석)

  • Kim, Seong-Ku;Kang, Sung-Mo;Seo, Bo-Sun;Kim, Yong-Mo
    • Journal of ILASS-Korea
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    • v.6 no.3
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    • pp.8-16
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    • 2001
  • The present study is focused on modeling the transient behavior of the local flame structure which is especially important for slow reaction processes, such as NOx formation in the radiating flame field. The unsteady flamelet model recently developed has been applied to analyze a steady, turbulent jet flame. Numerical results are compared with experimental data and numerical results of the conventional steady flamelet model. The numerical result reveals that the unsteady flamelet model correctly predicts the nonequilibrium effect upsteam and the subsequent decay of the superequilibrium radical concentrations further downstream.

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The Sensing Characteristics of $WO_3$ Thin Films for $NO_x$ Gas Detection with the Change of Deposition Methods (증착방법에 따른 $NO_x$가스 감지용 $WO_3$박막센서의 특성 변화 연구)

  • 김태송;김용범;유광수;성기숙;정형진
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.387-393
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    • 1997
  • In order to apply WO3 thin films to the semiconducting NOx gas sensors as a sensing material, which have been expected to show good electrical properties, such as large sensitivity, rapid responsibility, and high selectivity, the fabrication method and their sensing characteristics were studied. The variations of surface morphologies, crystallographic orientations and crystallinity with the WO3 thin film growing methods thermal evaporation and DC sputtering methods were investigated by using scanning electron microscopy (SEM) and X-ray diffraction(XRD) analysis. As a result of sensitivity (Rgas/Rair) measurements for the 5 ppm NO2 test gas, the sensitivity values were 113 for the sputtered films and 93 for the evaporated films. It was also observed that the recovery rate of a sensing signal after measuring sensitivity was faster in the sputtered films than in the evaporated films.

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