• Title/Summary/Keyword: Thermal Conductivity at High Temperature

Search Result 343, Processing Time 0.027 seconds

Sintering of Aluminum Nitride (I) : Pressureless Sintering (질화알루미늄의 소결(I) : 상압소결)

  • Choi, Sang-Wook;Lee, Hee-Chul;Rhee, Jhun;Lee, Im-Chang
    • Journal of the Korean Ceramic Society
    • /
    • v.28 no.6
    • /
    • pp.457-464
    • /
    • 1991
  • Aluminum nitride (AlN) has excellent properties such as high thermal conductivity and electrical resistivity, whereas it has some disadvantages such as low sinterability and tendency to be hydrolyzed by moisture at room temperature. In the present work, the relative density, modulus of rupture and microhardness were examined for pressure-less-sintered AlN (synthetic and commercial) bodies which were prepared under the conditions of various sintering temperatures, holding times and additions of CaCO3 which showed the best effect on sinterability among the various sintering aids. As a result, the AlN bodies with 1.0 wt% CaCO3 (0.56wt% CaO) which were sintered at 1800$^{\circ}C$ for 20 min showed good densification. In this case, the relative densities were 95.9% and 95.2%, and microhardnesses were 10.3 GPa and 9.8 GPa for synthetic and commercial AlN respectively. And as the holding time at 1800$^{\circ}C$ was increased from 10 min to 60 min, the relative density was increased from 91.9% to 96.5%. It was considered that impurities of metals and oxygen promoted the densification of AlN at low temperature (1600$^{\circ}C$).

  • PDF

COSMOS : A Computer Code for the Analysis of LWR $UO_2$ and MOX Fuel Rod

  • Koo, Yang-Hyun;Lee, Byung-Ho;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
    • /
    • v.30 no.6
    • /
    • pp.541-554
    • /
    • 1998
  • A computer code COSMOS has been developed based on the CARO-D5 for the thermal analysis of LWR UO$_2$ and MOX fuel rod under steady-state and transient operating conditions. The main purpose of the COSMOS, which considers high turnup characteristics such as thermal conductivity degradation with turnup and rim formation at the outer part of fuel pellet, is to calculate temperature profile across fuel pellet and fission gas release up to high burnup. A new mechanistic fission gas release model developed based on physical processes has been incorporated into the code. In addition, the features of MOX fuel such as change in themo-mechanical properties and the effect of microscopic heterogeneity on fission gas release have been also taken into account so that it can be applied to MOX fuel. Another important feature of the COSMOS is that it can analyze fuel segment refabricated from base irradiated fuel rods in commercial reactors. This feature makes it possible to analyze database obtained from international projects such as the MALDEN and RISO, many of which were collected from refabricated fuel segments. The capacity of the COSMOS has been tested with some number of experimental results obtained from the HALDEN, RISO and FIGARO programs. Comparison with the measured data indicates that, although the COSMOS gives reasonable agreement, the current models need to be improved. This work is being performed using database available from the OECD/NEA.

  • PDF

Experimental Study to Evaluate Thermal and Mechanical Behaviors of Frozen Soils according to Organic Contents (유기물 함유량에 따른 동토 시료의 열적·역학적 거동 평가를 위한 실험적 연구)

  • Sangyeong Park;Hyeontae Park;Hangseok Choi;YoungSeok Kim;Sewon Kim
    • Journal of the Korean Geosynthetics Society
    • /
    • v.23 no.2
    • /
    • pp.53-62
    • /
    • 2024
  • Recently, development of non-traditional energy such as oil sands has been actively conducted in the cold region such as Canada. Frozen soil has different thermal and mechanical characteristics from general soil due to its high organic contents. This study evaluated the impact of organic matter content on the thermal and mechanical behavior of frozen soil samples collected from Alberta, Canada, and Gangwon Province, South Korea. As the organic content increases, the maximum dry unit weight decreases and the optimum moisture content increases in compaction tests. In uniaxial compression tests under frozen conditions, the strength of the frozen specimens increased as the temperature decreased. The strength of Canada soil sample increased with higher organic matter content at low temperatures. However, the strength of frozen soil was not significantly affected by organic matter content due to the complex behavior and unfrozen water content. Thermal conductivity tests showed higher thermal conductivity in frozen conditions compared to unfrozen conditions, due to the higher thermal conductivity of ice compared to water. These findings provide essential data for geotechnical design and construction in large-scale projects such as oil sands development in cold regions. Further research is needed to explore the impact of organic matter content on different types of frozen soils.

The Study of poly-Si Eilm Crystallized on a Mo substrate for a thin film device Application (박막소자응용을 위한 Mo 기판 위에 고온결정화된 poly-Si 박막연구)

  • 김도영;서창기;심명석;김치형;이준신
    • Journal of the Korean Vacuum Society
    • /
    • v.12 no.2
    • /
    • pp.130-135
    • /
    • 2003
  • Polycrystalline silicon thin films have been used for low cost thin film device application. However, it was very difficult to fabricate high performance poly-Si at a temperature lower than $600^{\circ}C$ for glass substrate because the crystallization process technologies like conventional solid phase crystallization (SPC) require the number of high temperature (600-$1000^{\circ}C$) process. The objective of this paper is to grow poly-Si on flexible substrate using a rapid thermal crystallization (RTC) of amorphous silicon (a-Si) layer and make the high temperature process possible on molybdenum substrate. For the high temperature poly-Si growth, we deposited the a-Si film on the molybdenum sheet having a thickness of 150 $\mu\textrm{m}$ as flexible and low cost substrate. For crystallization, the heat treatment was performed in a RTA system. The experimental results show the grain size larger than 0.5 $\mu\textrm{m}$ and conductivity of $10^{-5}$ S/cm. The a-Si was crystallized at $1050^{\circ}C$ within 3min and improved crystal volume fraction of 92 % by RTA. We have successfully achieved a field effect mobility over 67 $\textrm{cm}^2$/Vs.

Demonstration of Heat Dissipation Performance of Copper Plate in Engineered Barrier System

  • Minsoo Lee;Jin-Seop Kim;Min-Seop Kim;Seok Yoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.22 no.2
    • /
    • pp.105-115
    • /
    • 2024
  • In this study, we employed a small-scale experiment to demonstrate the introduction of a thin copper heat dissipation plate into a bentonite buffer layer of an engineered barrier system. This experiment designed for spent nuclear fuel disposal can effectively reduce the maximum temperature of the bentonite buffer layer, and ultimately, make it possible to reduce the area of the disposal site. For the experiment, a small-scale engineered barrier system with a copper heat dissipation plate was designed and manufactured. the thickness of the cylindrical buffer was about 2 cm, which was about 1/20 of KAERI Repository System (KRS). At a power supply of 250 W, the maximum buffer temperature reduced to a mere 1.8℃ when the thin copper plate was introduced. However, the maximum surface temperature reduced to a remarkable 9.1℃, when a U-collar copper plate was introduced, which had a good contact with the other barrier layers. Consequently, we conclude that the introduction of the thin copper plate into the engineered barrier system for spent nuclear fuel disposal can effectively reduce the maximum buffer temperature in high-level radioactive waste disposal repositories.

A Study on Fabrication and Characterization of Inorganic Insulation Material by Hydrothermal Synthesis Method (2) (수열합성법을 이용한 무기계 단열소재 제조방법 및 특성에 관한 연구 (2))

  • Seo, Sung-Kwan;Chu, Yong-Sik;Lee, Jong-Kyu;Song, Hun;Park, Jae-Wan
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.1 no.3
    • /
    • pp.225-232
    • /
    • 2013
  • The inorganic insulating material was fabricated with quartzite, ordinary portland cement(OPC), lime, anhydrous gypsum and foaming agent by hydrothermal reaction. The inorganic insulating material was fabricated by using autoclave chamber under high-temperature and high-pressure. The inorganic insulating material is a porous lightweight concrete. Because of its porous structure, properties of inorganic insulating material were light-weight and high-heat insulation property. Properties of fabricated inorganic insulating material were $0.26g/cm^3$ in specific gravity, 0.4MPa in compressive strength and 0.064W/mK in thermal conductivity. In this study, the inorganic insulating material was fabricated and analyzed at different size of quartzite/OPC, various foaming reagent and functional additives to improve the properties. Consequently, polydimethylsiloxane can improve density and thermal conductivity. Especially, polydimethylsiloxane showed excellent improvement in compressive strength.

Fluctuation Features and Numerical Model for Underground Temperature in Shallow Subsurface Soil (천층 토양 내 지중온도 변동 특성과 수치모델 평가)

  • Jeong, Jaehoon;Kim, Gyoobum;Park, Hyoungki;Kim, Hyoungsoo;Kim, Taehyung
    • Journal of the Korean GEO-environmental Society
    • /
    • v.16 no.5
    • /
    • pp.35-42
    • /
    • 2015
  • This is conducted to observe underground temperature and to analyze its change affected by climate condition and soil infiltration in the mountainous area, Yesan region, Chungcheong-namdo province. Additionally, underground temperature change is also simulated using air temperature and soil thermal properties with a numerical model. Soil temperature monitoring data acquired from each depth, 20 cm, 50 cm, and 100 cm, indicates that the data within 50 cm in depth shows peak-shaped big fluctuation directly affected by air temperature and it at 100 cm has open-shaped small fluctuation. Underground temperature variation, a difference between high and low values, during monitoring period is weakly proportional to hydraulic conductivity of the sediment and it is assumed that water plays a part in delivering air temperature in soil. The underground temperature estimated by a numerical model is very similar to the observed data with an average value of 0.99 cross-correlation coefficient. From the result of this study, the aquifer unsaturated hydraulic conductivity of the soil and the groundwater recharge is likely to be able to estimate with underground temperature profile calculated using a numerical model.

Development of Crosslinked Sulfonated Poly(ether sulfone)s as Novel Polymer Electrolyte Membranes (새로운 연료전지용 술폰화된 PES계 가교 고분자 전해질 막의 개발)

  • Oh, Young-Seok;Lee, Myung-Gun;Kim, Tae-Hyun
    • Journal of the Korean Chemical Society
    • /
    • v.53 no.3
    • /
    • pp.345-354
    • /
    • 2009
  • Sulfonated poly(ether sulfone)s (PESs) with a network structure were prepared by heat-induced crosslinking of the allyl-terminated telechelic sulfone polymers using a bisazide and their structure was analyzed by $^1H$ NMR. Having both uniform distribution of the hydrophilic conductive sites and controlled hydrophobic nature by minimized crosslinking, the crosslinked polymer (PES-60) membrane offered excellent proton conductivity at high temperature with a good thermal stability. In addition, selectivity of the crosslinked membrane (PES-60) was more than three times than that of Nafion$^{(R)}$.

A comparison on the heat load of HTS current leads with respect to uniform and non-uniform cross-sectional areas

  • Han, Seunghak;Nam, Seokho;Lee, Jeyull;Song, Seunghyun;Jeon, Haeryong;Baek, Geonwoo;Kang, Hyoungku;Ko, Tae Kuk
    • Progress in Superconductivity and Cryogenics
    • /
    • v.19 no.3
    • /
    • pp.44-48
    • /
    • 2017
  • Current lead is a device that connects the power supply and superconducting magnets. High temperature superconductor (HTS) has lower thermal conductivity and higher current density than normal metal. For these reasons, the heat load can be reduced by replacing the normal metal of the current lead with the HTS. Conventional HTS current lead has same cross-sectional area in the axial direction. However, this is over-designed at the cold-end (4.2 K) in terms of current. The heat load can be reduced by reducing this part because the heat load is proportional to the cross-sectional area. Therefore, in this paper, heat load was calculated from the heat diffusion equation of HTS current leads with uniform and non-uniform cross-sectional areas. The cross-sectional area of the warm-end (65K) is designed considering burnout time when cooling system failure occurs. In cold-end, Joule heat and heat load due to current conduction occurs at the same time, so the cross-sectional area where the sum of the two heat is minimum is obtained. As a result of simulation, current leads for KSTAR TF coils with uniform and non-uniform cross-sectional areas were designed, and it was confirmed that the non-uniform cross-sectional areas could further reduce the heat load.

Temporal Brittleness of the Mod.9Cr-1Mo Steel (Mod.9Cr1Mo강에서 발생되는 일시적 취성현상)

  • Hur, Sung-Kang;Gu, Ji-Ho;Shin, Kee-Sam;He, Yincheng;Shin, Jong-Ho
    • Korean Journal of Materials Research
    • /
    • v.21 no.11
    • /
    • pp.592-595
    • /
    • 2011
  • It is well known that modified 9Cr-1Mo steel has a low thermal expansion and high thermal conductivity with excellent high temperature properties compared to austenitic stainless steel. For these advantages, the steel is very popular for the boiler tube of thermal power plants. Normalizing is commonly utilized to obtain martensite in this steel, which shows an unusual toughness for martensite. However, some accidents related to this steel have been reported recently, opening the necessity for further study. As a particular behavior of the steel, an abrupt drop of the impact value has been identified upon tempering at 750$^{\circ}C$ for about 1 hour. It is well known that $Fe_3C$ forms during autotempering and turns to $Cr_2C$ at an early stage and then transforms to $Cr_{23}C_6$. In this study, the cause of the abrupt drop of the impact value was investigated with an impact test, microstructural observation, nanodiffraction and phase analyses using instruments such as optical and transmission electron microscopes (TEM) with an extraction carbon replica of the carbides. The analyses revealed that the $M_2C$ that formed when retained for about 1 hour at 750$^{\circ}C$ causes a drastic decrease in the mechanical properties. The sharp drop in mechanical properties, however, disappeared as the $M_2C$ transformed into $M_{23}C_6$ with longer retention.