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http://dx.doi.org/10.5012/jkcs.2009.53.3.345

Development of Crosslinked Sulfonated Poly(ether sulfone)s as Novel Polymer Electrolyte Membranes  

Oh, Young-Seok (Department of Chemistry, University of Incheon)
Lee, Myung-Gun (Department of Chemistry, University of Incheon)
Kim, Tae-Hyun (Department of Chemistry, University of Incheon)
Publication Information
Journal of the Korean Chemical Society / v.53, no.3, 2009 , pp. 345-354 More about this Journal
Abstract
Sulfonated poly(ether sulfone)s (PESs) with a network structure were prepared by heat-induced crosslinking of the allyl-terminated telechelic sulfone polymers using a bisazide and their structure was analyzed by $^1H$ NMR. Having both uniform distribution of the hydrophilic conductive sites and controlled hydrophobic nature by minimized crosslinking, the crosslinked polymer (PES-60) membrane offered excellent proton conductivity at high temperature with a good thermal stability. In addition, selectivity of the crosslinked membrane (PES-60) was more than three times than that of Nafion$^{(R)}$.
Keywords
Polymer electrolyte membrane; Sulfonated poly(ether sulfone)s; Crosslinking; Proton conductivity; Selectivity;
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