• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.4
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• pp.430-439
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• 1985

Conjugate natural convection in double enclosed annuli between horizontal concentric cylinders has been studied by the numerical analysis and experimental measurements. The interface conditions between the liquid and the solid of middle shell are obtained through the correlation factor based on the ratio of solid to fluid thermal conductivities and the Prandtl number. The characteristics of conjugate heat transfer are discussed under various dimensionless parameters such as conductivity ratios, shell thickness, diameter ratios, Prandtl number, and Rayleigh number. It is found that the average equivalent conductivity K over var $_{eq}$ does not depend on the conductivity ratios and shell thickness. The K over bar $_{eq}$ however, depends on the Prandtl number and the Rayleigh number.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.4
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• pp.306-311
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• 2000

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity impedance spectroscopy and electrochemical properties of PDF/PAN electrolytes as a function of a mixed ratio were reported for PVDF/PAN based polymer electrolyte films which were prepared by thermal gellification method of preweighed PVDF/PAN plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10$\^$-3/S/cm. 20PVDF5PEN LiCiO$\_$4//PC$\_$10//EC$\_$10/ electrolyte has the better conductivity compared to others. 20PVDF5PANLICIO$\_$4//PC$\_$10//EC$\_$10/ electroylte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance were used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5PANLiCO$\^$4//PC$\_$10//EC$\_$10/ electrolyte is 0.48.

• Macromolecular Research
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• v.12 no.4
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• pp.422-426
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• 2004

Solid polymer electrolytes based on poly(ethylene glycol)-polyurethane (PEG-PU) complexed with LiClO$_4$ salt have been prepared by the solvent casting method. A PEG-PU material (PEG:4,4'-diphenylmethane diisocyanate: l,4-butanediol = 1:2:1) was synthesized through a typical two-step condensation reaction. We investigated the effects of the salt concentration on the ionic conductivity ($\sigma$) and the glass transition temperature (T$_{g}$ ) of the complex electrolytes by using alternating current impedance spectroscopy, differential scanning calorimetry, and dynamic mechanical thermal analysis. The measured values of both $\sigma$ and T$_{g}$ exhibited similar tendencies in that they had maxima within the range studied, probably because of two opposite effects, i.e., the increased number of carrier ions and the decreased chain mobility (or increased T$_{g}$ ) caused by the increase in the salt concentration. The highest conductivity, on the order of 2.43 ${\times}$ 10$^{6}$ S$cm^{-1}$ /, was obtained at an [O]/[Li$^{+}$] ratio of ca. 16 (0.92 ㏖ salt per kg of matrix polymer).

• Applied Chemistry for Engineering
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• v.32 no.2
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• pp.143-148
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• 2021

A thermally conductive 200 ㎛ thick polyimide-based film was made from a polyamic acid (PAA) precursor containing graphene prepared from graphite rod using an electrostatic discharge method in order to improve the thermal conductivity and expand the applicability of polyimide (PI) film. Properties of graphene produced by electrostatic discharge were measured by Raman spectroscopy, transmission electron microscopy and X-ray photoelectron spectroscopy (XPS). As a result of Raman spectrum and XPS analyses of as-prepared graphene, the ID/IG ratio was 0.138 and C/O value was 24.91 which are excellent structural and surface chemical properties. Moreover, thermal conductivities of polyimide films increased exponentially according to graphene contents but when the graphene content exceeded 40%, the polyimide film could not maintain its shape. The thermal conductivity of carbonized PI film made from PAA containing 40 wt% of graphene was 51 W/mK which is greatly enhanced from the pristine carbonized PI film (1.9 W/mK). This result could be originated from superior properties of graphene prepared from the electrostatic discharge method.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.765-768
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• 2006

This paper investigates the properties of light weight foamed concrete with variances in adding ratio of stability agent(PS). Test showed that an increase of PS adding ratio decreased fluidity due to higher viscosity and increased unit weight of specimens. A sinking depth declined as the adding ratio of PS inclines, but all specimens including control concrete was ranging in KS; 0.5 to 10mm. Compressive strength value of specimens increased as PS adding ratio inclines. As for the tensile strength, any significant feature was not observed, compared with control concrete, but the ratios of camp. to tens. increased. Appearance density of concrete increased, and thermal conductivity was satisfied in KS, except for a specimen adding 0.07 percent of PS.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.3
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• pp.219-224
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• 2013

In this study, the inorganic insulating material was fabricated with quartzite, ordinary portland cement(OPC), lime and anhydrous gypsum. After characteristic analysis of slurry, the optimum mixing ratio was derived with different $CaO/SiO_2$ mole ratio. Based on derived mixing ratio, the inorganic insulating material was fabricated at different water content and hydrothermal synthesis conditions. Specific gravity was $0.26g/cm^3$, compressive strength was 0.4 MPa, and thermal conductivity was 0.064 W/mK. This properties were enhanced performance of conventional ALC (Autoclaved Lightweight Concrete). And it can replace organic insulation with harmless inorganic insulation through continues research and development.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.386-391
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• 2003

Ready mixed mortar has been originated from lime industry of Germany and is being used widely in the world at present. In recent years, the studies of mortar with new faculty have been progressed. In this study, we used elvan instead of using sand in order to make cement mortar and investigated characteristics of elvan and mortar that used elvan. The major compositions of elvan were $SiO_2$ and $Al_2O_3$. The crystal phases of elvan were composed of quartz and sillimanite. Elvan had a lot of pore and absorption ratio was 2.09%. The compressive strength of mortar that used elvan satisfied korean industrial standards under 1:3 (mixing ratio) and water retentivity increased according to increase of elvan contents. Far infrared radiation and deodorization ratio increased and thermal conductivity decreased according to increase of elvan contents.

• Journal of the Korea Concrete Institute
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• v.28 no.4
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• pp.435-444
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• 2016

In Korea, approximately 48% of all households live in apartments, which are a form of multi-unit dwellings, and this figure increases up to 58%, when row houses and multiplex houses are included. As such, majority of the population reside in multi-unit dwellings where they are exposed to the problem of floor impact noise that can cause disputes and conflicts. Accordingly, this study was conducted to manufacture a high-weight, high-stiffness foamed concrete in order to develop a technology to reduce the floor impact noise. For the purpose of deriving the optimum mixing ratio for the foamed concrete that best reduces the floor impact noise, the amounts of the foaming agent, lightweight aggregate and binder were varied accordingly. Also, the target characteristics of the concrete to be developed included density of over $0.7t/m^3$, compressive strength of over $2.0N/mm^2$ and thermal conductivity of under 0.19 W/mK. The results of the experiment showed that the fluidity was very excellent at over 190 mm, regardless of the type and input amount of foaming agent and lightweight aggregate. The density and compressive strength measurements showed that the target density and compressive strength were satisfied in the specimen with 50% foam mixing ratio for foamed concrete and in all of the mixtures for the lightweight aggregate foamed concrete. In addition, the thermal conductivity measurements showed that the target thermal conductivity was satisfied in all of the foamed concrete specimens, except for VS50, in the 25% replacement ratio case for Type A aggregate, and all of the mixtures for Type B aggregate.

• Journal of the Korean Ceramic Society
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• v.49 no.1
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• pp.111-117
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• 2012

Dependencies of thermal properties on the crystallization behavior of $0.9CaMgSi_2O_6-0.1MgSiO_3$ glass-ceramics were investigated as a function of heat-treatment temperature from $750^{\circ}C$ to $950^{\circ}C$. The crystallization behavior of the specimens depended on the heat-treatment temperature, which could be evaluated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) analysis by the Rietveld-reference intensity ratio (RIR) combined procedure. With an increase of the heat-treatment temperature, the thermal conductivity and thermal diffusivity of the heat-treated specimens increased. These results could be attributed to the increase of crystallization with heat-treatment temperature. However, the specific heat capacity of the heat-treated specimens was not affected by the heat-treatment temperature. The thermal conductivities measured from $25^{\circ}C$ to $100^{\circ}C$ were also discussed for application to lighting-emitting diode (LED) packages and substrate materials.

• Journal of the Korea Institute of Building Construction
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• v.12 no.5
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• pp.548-557
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• 2012

In this study the thermal performance of G-PCM replaced for find aggregate in mortar specimens was evaluated using TG-DTA. As a result, it was found that when solid changed into liquid, it absorbed heat, and when liquid changed into solid, it radiated heat. In addition, the fluidity and the compressive strength of mortar with G-PCM can be applied to the floor mortar and a wall finish material. Also the higher the replacement ratio, the larger the latent heat capacity. It was found that the mortar with G-PCM slowed the increase and decrease of temperature. Thus, the duration of pleasant indoor temperature is extended by the floor and wall mortar with G-PCM. In conclusion, G-PCM is expected to reduce the heating energy consumption.