• Title/Summary/Keyword: Thermal Conductivity Ratio

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Behavior of $Li^{+}$ in PAN/PVDF based Polymer Electrolyte for Lithium Polymer Battery (리튬 폴리머전지용 PAN/PVDF계 고분자 전해질의 리튬 이온 거동)

  • 이재안;김상기;김종욱;구할본;박계춘
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.540-543
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio were reported for PAN/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. The conductivity of PAN/PVDF electrolytes was $10^{-3}$S/cm. $PAN_{10}$$PVDF_{10}$$LiClO_4$$PC_{5}$$EC_{5}$ electrolyte has the better conductivity compared to others. The interfacial resistance behavior between the lithium electrode and PAN/PVDF based polymer electrolyte has also been investigated and compare with that between the lithium electrode and the PAN/PVDF based polymer electrolyte.

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Physical and Mechanical Properties, Thermal Conductivity and Fire-Proof Performance of Wood-Cement Board (목질.시멘트보드의 물리.기계적 성질, 열전도성 및 내화성)

  • 서진석;박종영
    • Journal of the Korea Furniture Society
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    • v.14 no.2
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    • pp.31-38
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    • 2003
  • This study was carried out to investigate characteristics of wood-based panels and wood-cement board for the possible uses as flooring and wall materials. The optimum cement/wood ratio(C/W ratio) of wood~cement board manufactured by clamp-pressing was from 2.7 to 3.2. The dimesional stability was superior in the C/W ratio of 3.2. Particularly, the dimensional stability of cement board using fine particle for particleboard face layer was favorable through three levels of C/W ratio. According to types of wooden material, bending strength of cement board using coarse particle for particleboard core layer or old newspaper(ONP) fiber was relatively higher than others. Thermal conductivities of wood-cement boards were no lower than that of gypsum board, and higher than those of plywood and boards. In case of wood-cement board of the C/W ratio of 2.7, the fire-proof performances of cement composite boards were greater than that of gypsum board, and weight loss reached to about a half of gypsum board. Then, wood-cement boards showed superior fire-proof performance compared to wood-based panels.

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Thermal Conductivity and Pore Characteristics of Low-Temperature Sintered Lightweight Aggregates Mode from Waste Glass and Bottom Ash (바텀애쉬와 폐유리를 사용하여 제조한 저온소성 경량골재의 열전도율과 기공특성)

  • Lee, Han-Baek;Ji, Suk-Won;Seo, Chee-Ho
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.851-858
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    • 2010
  • In this study, waste glass and bottom ash were used as basic materials in order to secure a recycling technology of by-products which was mostly discarded and reclaimed. In addition, because softening point of waste glass is less than $700^{\circ}C$ and bottom ash includes combustible material, it was possible to manufacture low-temperature sintering lightweight aggregates for energy saving at $800{\sim}900^{\circ}C$ that it is as much as 20~30% lower than sintering temperature of existing lightweight aggregates. Thermal conductivity of newly-developed lightweight aggregates was 0.056~0.105W/m. K and its porosity was 40.36~84.89%. A coefficient of correlation between thermal conductivity and porosity was -0.97, it showed very high negative correlationship. With this, we were able to verify that porosity is key factor to affect thermal conductivity. Microstructure of lightweight aggregates by $CaCO_3$ content and replacement ratio of bottom ash in the variation of temperature were that $CaCO_3$ content increased along with pore size while replacement ratio of bottom ash increased as pore size decreased. Specially, most pores were open pore instead of closed pore of globular shape when replacement ratio of bottom ash was 30%, and pore size was small about 1/10~1/5 as compared with case in bottom ash 0~20%. In addition, open pore shapes were remarkably more irregular form of open pore in $900^{\circ}C$ than $700^{\circ}C$ or $800^{\circ}C$ when replacement ratio of bottom ash was 30%. We reasoned hereby that these results will influence on absorption increase, strength and thermal conductivity decrease of lightweight aggregates.

Study on Analysis Technique Comparison and Evaluation of High Thermal Conductivity Concrete with Magnetite Aggregates and Steel Powder (자철광 및 철분말을 혼입한 고열전도 콘크리트의 열전도 평가 및 해석기법 비교에 대한 연구)

  • Lee, Hack-Soo;Kim, Min-Kyu;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.315-321
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    • 2014
  • Concrete as a construction material is widely used in nuclear vessel and plant for excellent radiation shielding. However the isolation characteristics in concrete may affect adversely in the case of fire and melt-down in nuclear vessel since temperature cooling down is very difficult from outside. This study is for development of high thermal conductive concrete, and its mechanical and thermal properties are evaluated. Magnetite aggregates with volume ratio of 42.3% (maximum) and steel powder of 1.5% are replaced with normal aggregates and thermal properties are evaluated. Thermal conductivity little increases by 30% addition of magnetite but rapidly increases afterwards. Finally thermal conductivity is magnified to 2.5 times in the case of 42.3% addition of magnetite. Steel powder has a positive effect on high thermal conduction to 106~113%. Several models for thermal conduction like ACI, DEMM, and MEM are compared with test results and they are verified to reasonably predict the thermal conductivity with increasing addition of magnetite aggregates and steel powder.

Combustion Characteristics of Hydrogen by the Thermodynamic Properties Analysis

  • Han, Sung Bin
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.84-90
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    • 2015
  • Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

An Experimental Study on the Properties of Mortar Mixing Paper Ash (제지애쉬를 혼입한 모르터의 특성에 관한 실험적 연구)

  • Lee, Si-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.3
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    • pp.115-121
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    • 2002
  • The purpose of this study is investigating characteristics of paper-ash mortar according to partial replacement of fine aggregate by Paper-ash. For this purpose, selected test variables were mixing ratio with two levels of mortar(1:2, 1:3), and 3 types of paper-ash(A, B, C), and paper-ash content with four levels(5%,, 10%, 15%, 20%). As a result of this study, in all mixes with partial replacement of fine aggregate by Paper-ash generally Produced Paper-ash mortar with decreased compressive strength at ail age as compared to ordinary mixes. The mixing rate 1:2 was the higher increasing rate of strength than the mixing rate 1:3. The flow value and unit weight of paper-ash mortar were decreased with increasing of the paper-ash content. And the thermal conductivity of the thermal conductivity of the paper-ash mortar was lower than normal mixing without paper-ash.

The Preparation Characteristic of Polyphenylenediamine -V$_2$O$_5$ Composite film (Polyphenylenediamine-V$_2$O$_5$ 복합 필름의 제막특성)

  • 박수길;나재진;이홍기;임기조;김상욱;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.218-220
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    • 1996
  • A composite films were prepared by using Polyphenylenediamine(PPD) synthesized in our lab. and crystalline V$_2$O$_{5}$ in various mixture ratio for using positive active material of polymer film battery. The thermal stability of prepared composite film was carried out by using TGA. Electrical conductivity of composite film were also measured by using four-probe method in dry box. The thermal stability of prepared composite film is more than 35$0^{\circ}C$. The electrical conductivity of composite film increased and showed the highest value(about 23 S/cm) when doped at 0.4% LiCiO$_4$solution.n.

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The Preparation Characteristic of Polyphenylenediamine -Dimercaptan Composite film (Polyphenylenediamine-Dimercaptan 복합 필름의 제막특성)

  • 박수길;나재진;이홍기;임기조;김상욱;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.105-108
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    • 1996
  • The positive active material for polymer film battery was prepared by using Polyphenylenediamine(PPD) synthesized in our lab. and 2.5-dimercapto-1, 3, 4-thiadiazole(DMcT) in various mixture ratio. The transference measurement of surface morphology and thermal stability of prepared composite film was carried out by using SEM and TGA, respectively. Electrocyhemical property and electrical conductivity of composite film were also measured by using cyclic voltammetry and four-probe method in dry box, respectively. The thermal stability of prepared composite film is more than 20$0^{\circ}C$. The electrical conductivity of composite film increased and showed the highest value(about 3 S/cm)when doped at 0.4% LiClO$_4$solution. And we could confirm that DMcT effect on reactiviation of PPD through cyclic voltammogram.

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A Computational Study of Natural Convection in Vertical Rectangular Enclosures with Partiton Plates of Finite Thermal Conductivity (유한열전도율(有限熱傳導率)의 격판(隔板)을 갖는 수직구형(垂直矩形) 밀폐공간(密閉空間)에서의 자연대류(自然對流)에 관(關)한 수치적(數値的) 연구(硏究))

  • Park, Man-Heung;Lee, Jae-Heon
    • Solar Energy
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    • v.2 no.1
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    • pp.1-8
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    • 1982
  • A theoretical study by numerical method has been performed on the natural convection of an air contained in enclosures. The enclosures have rectangular cross section with one vertical wall heated and the other cooled, and with two horizontal partition plates of finite thermal conductivity. Steady two-dimensional flow was assumed. The computation was executed by means of the Implicit Alternating Direction (I.A.D) finite-difference method. Two partition plates of Aluminium whose thickness were 0.05mm was employed in computation. Isothemals, streamlines, local Nusselt numbers and mean Nusselt numbers were obtained for various Grashof numbers and aspect ratio and these results were compared with those in the case of the enclosure with two horizontal insulated plates. From the present results, the heat transfer in the case of partition plates was greater than that in the case of insulation. This study suggests a method to measure the overall heat-transfer of coefficient in double walls which supported by partition plates for insulative construction.

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Improvement of Electrical and Thermal Characteristics of Nano-Micro Epoxy Composite

  • Cho, Sung-Hoon;Kim, Yu-Min;Kwon, Jung-Hun;Lim, Kee-Joe;Jung, Eui-Hwan;Lee, Hung-Kyu;Shin, Pan-Seok
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.4
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    • pp.160-163
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    • 2011
  • Polymer nanocomposite has been attracting more attention as a new insulation material because homogeneous dispersion of nano-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy-based nanocomposites were made, and the AC breakdown strengths of Nano filler and micro-$SiO_2$ filler mixtures of epoxy-based composites were analyzed using sphere-to-sphere electrodes. Moreover, nano- and microfiller combinations were investigated as an approach to practical application of nanocomposite insulation materials. Its composition ratio was 100 (resin):82 (hardener):1.5 (accelerator). AC breakdown tests were performed at room temperature ($25^{\circ}C$), $80^{\circ}C$, and $100^{\circ}C$ in the vicinity of $T_g$ ($90^{\circ}C$). Thermal conductivity was measured using TC-30.