• Title/Summary/Keyword: Thermal Ablation

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Ablation of Polypropylene for Breathable Packaging Films

  • Sohn, Ik-Bu;Noh, Young-Chul;Choi, Sung-Chul;Ko, Do-Kyeong;Lee, Jong-Min;Choi, Young-Jin
    • Laser Solutions
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    • v.9 no.3
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    • pp.15-21
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    • 2006
  • A Polypropylene (PP) film was ablated using a femtosecond laser with a center wavelength of 785 nm, a pulse width of 184 fs and a repetition rate of 1 kHz. Increments of both pulse energy and the shot number of pulses lead to co-occurrence of photochemical and thermal effect, demonstrated by the spatial expansion of rim on the surface of PP. The shapes of the laser-ablated PP films were imaged by a scanning electron microscope (SEM) and measured a 3D optical measurement system (NanoFocus). And, the oxygen transmission rate (ORT) of periodically laser-ablated PP film were characterized by oxygen permeability tester for modified atmosphere packaging (MAP) of fresh fruit and vegetable. Our results demonstrate that femtosecond pulsed laser is efficient tools for breathable packaging films in modifying the flow of air and gas into and out of a fresh produce container, where the micropatterns are specifically tailored in size, location and number which are easily controlled by laser pulse energy and pulse patterning system.

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Parametric comparative study of Rocket Nozzle Convective Heat Transfer Coefficient Application of Combustion gas characteristic and Method of Analysis (해석방법 및 연소가스특성 적용에 따른 로켓 노즐 대류열전달계수의 매개변수적 비교 고찰)

  • Kim, Yonggu;Bae, Joochan;Kim, Jinok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.651-663
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    • 2017
  • Experimental results of $30^{\circ}-15^{\circ}$ nozzles were compared with numerically calculated convective heat transfer coefficients using FLUENT, Boundary Layer Integration Method and Bartz predictions. Also, the convective heat transfer coefficients were calculated by using FLUENT and boundary layer integration method for NASA HIPPO nozzles according to the characteristics of combustion gas and the correlation between pressure and pressure was compared. Finally, thermal analysis of NASA HIPPO nozzle was performed to compare the ablation thickness and char depth according to the combustion gas characteristics.

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Nd:YVO4 Laser Patterning of Various Transparent Conductive Oxide Thin Films on Glass Substrate at a Wavelength of 1,064 nm

  • Wang, Jian-Xun;Kwon, Sang Jik;Cho, Eou Sik
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.59-62
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    • 2013
  • At an infra-red (IR) wavelength of 1,064 nm, a diode-pumped Q-switched $Nd:YVO_4$ laser was used for the direct patterning of various transparent conductive oxide (TCO) thin films on glass substrate. With various laser beam conditions, the laser ablation results showed that the indium tin oxide (ITO) film was removed completely. In contrast, zinc oxide (ZnO) film was not etched for any laser beam conditions and indium gallium zinc oxide (IGZO) was only ablated with a low scanning speed. The difference in laser ablation is thought to be due to the crystal structures and the coefficient of thermal expansion (CTE) of ITO, IGZO, and ZnO. The width of the laser-patterned grooves was dependent on the film materials, the repetition rate, and the scanning speed of the laser beam.

Real Time Monitoring of Ionic Species Generated from Laser-Ablated Pb$(Zr_{0.52}Ti_{0.48})O_3$ Target Using Pulsed-Field Time-Of-Flight Mass spectrometer

  • 최영구;임훙선;정광우
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.830-835
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    • 1998
  • The characteristics of the ablation plume generated by 532 nm Nd: YAG laser irradiation of a Pb(Zr0.52Ti0.48)O3 (PZT) target have been investigated using a pulsed-field time-of-flight mass spectrometer (TOFMS). The relative abundance of O+, Ti+, Zr+, Pb+, TiO+, and ZrO+ ions has been measured and discussed. TiO+ and ZrO+ ions were also found to be particularly stable within the laser ablation plasma with respect to PbO+ species. The behavior of the temporal distributions of each ionic species was studied as a function of the delay time between the laser shot and the ion extraction pulse. The most probable velocity of each ablated ion is estimated to be Vmp=1.1-1.6x 105 cm/s at a laser fluence of 1.2 J/cm2, which is typically employed for the thin film deposition of PZT. The TOF distribution of Ti+ and Zr+ ions shows a trimodal distribution with one fast and two slow velocity components. The fast velocity component (6.8x 10' cm/s) appears to consist of directly ablated species via nonthermal process. The second component, originated from the thermal evaporation process, has a characteristic velocity of 1.4-1.6 x 105 cm/s. The slowest component (1.2 x 105 cm/s) is composed of a dissociation product formed from the corresponding oxide ion.

Development of C/SiC Composite Parts for Rocket Propulsion (로켓 추진기관용 C/SiC 내열부품 개발)

  • Kim, Yunchul;Seo, Sangkyu
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.68-77
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    • 2019
  • C/SiC composites were developed by a liquid silicon infiltration(LSI) method for use as heat-resistant parts of solid and liquid rocket propulsion engines. The heat resistance characteristics according to the composition ratio (carbon / silicon / silicon carbide) were evaluated by specimen test through arc plasma, supersonic torch test. An ablation equation for oxidation reactions was presented. Through the combustion test it was verified that various parts such as nozzle insert, exit cone and combustion chamber heat resistant parts for rocket propulsion can be manufactured and proved high ablation performance and thermal structure performance.

Deposition of Polytetrafluoroethylene Thin Films by IR-pulsed Laser Ablation (Nd:YAG 레이저에 의한 폴리테트라플루오르에틸렌 박막 증착)

  • Park Hoon;Seo Yu-Suk;Hong Jin-Soo;Chae Hee-Baik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.1
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    • pp.58-63
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    • 2005
  • PTFE (polytetrafluoroethylene) thin films were prepared from the pellets of the graphite doped PTFE via pulsed laser ablation with 1064 nm Nd:YAG laser. The graphite powder converts the absorbed photon energy into thermal energy which is transmitted to nearby PTFE. The PTFE is decomposed by thermal process. The deposited films were transparent and crystalline. SEM (scanning electron microscopy) and AFM (atomic force microscopy) analyses indicated that the film surface morphology changed to fibrous structure with increasing thickness. The fluorine to carbon ratios of the film were 1.7 and molecular axis was parallel with (100) Si-wafer substrate. These results obtained by XPS (X-ray photoelectron spectroscopy), FTIR (fourier transform infrared spectroscopy) and XRD (X-ray diffraction).

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Effects of Solid Propellant Cases on the Thermal Response of Nozzle Liner (노즐 내열재 열반응에 미치는 고체 추진제 연소가스의 영향)

  • Hwang, Ki-Young;Yim, Yoo-Jin;Ham, Hee-Cheol;Kang, Yoon-Goo;Bae, Joo-Chan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.2
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    • pp.26-36
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    • 2007
  • The thermal response characteristics of nozzle liner for a solid rocket motor applying highly aluminized PCP or HTPB propellant with slotted tube grain have been investigated. The SEM photographs of aluminum oxide particles taken from nozzle liner show that the PCP propellant with the finer and less contents of oxidizer can offer greater possibility for increasing aluminum agglomeration than the HTPB propellant. The PCP propellant shows locally greater mechanical erosion at 4 circumferential areas of the nozzle entrance in line with grain slot due to the impingement of large particles, but the HTPB propellant shows greater thermochemical ablation at the nozzle blast tube, the throat insert and the exit cone because of relatively much more mole fraction of $H_2O\;and\;CO_2$ in combustion gases.

A Study of the Effect of Operating Time of a Rocket Motor on the Convective Heat Transfer Coefficient of Nozzle (로켓 모터의 작동시간이 노즐 열전달 계수에 미치는 영향에 관한 연구)

  • Kim, Jinsoo;Kim, Kyungsik;Cho, Seunghwan;Kwon, Youngdoo;Kwon, Soonbum
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.2
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    • pp.24-30
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    • 2013
  • To guarantee the exact control of missile warhead, it is inevitable to ensure the stabilities in the view points of structural and fluid/thermo dynamics of the rocket motor. Specially, despite of shortness in operating time of the rocket motor which is initial turning type of missile, it occurs frequently some problems of ablation at the neighborhood of the nozzle throat, with the result that the system itself gets to failure. In these connections, in the present study, the effect of the operating time of a rocket motor on the coefficient of convective heat transfer at the nozzle wall is investigated by numerical analysis. As a result, it is turned out that the heat transfer coefficient is largest at the just ahead of nozzle throat and decreases with the increase of operating time of the rocket motor. Furthermore, we found that the radius of curvature of throat becomes smaller, the maximum coefficient of convective heat transfer becomes larger.

Growth of $SiO_2$ nanowire by VS method. (기상증착방법에 의한 이산화규소 나노와이어의 성장)

  • 노대호;김재수;변동진;진정근;김나리;양재웅
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.115-115
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    • 2003
  • Silica nanostructures have been attached considerable attention because of theirs potential application in mesoscopic research and the potential use of large surface area structure of catalysts. SiO2 nannowire and nanorods was synthesized various methods including thermal evaporation, chemical vapor deposition (CVD), and laser ablation methods. In this experiments, SiO2 nanowire were grown using thermal evaporation method followed by VS (Vapor-Solid) growth mechanisms. Grown SiO2 nanowires were amorphous phases because of its low growth temperatures. Grown nanowires diameters were about 20-40nm at all growth conditions, but its microstructres were different by that used substrate because of it's oxygen contents.

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STUDY ON NUMERICAL ANALYSIS AND TURBULENCE MODELS FOR ARC DISCHARGES IN HIGH-VOLTAGE INTERRUPTERS (초고압 차단부 아크방전 수치해석 및 난류모델에 관한 연구)

  • Lee, J.C.
    • Journal of computational fluids engineering
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    • v.15 no.3
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    • pp.9-15
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    • 2010
  • In this study, we calculated arc discharges and flow characteristics driven by arcs in a thermal puffer chamber, which is one of most outstanding high-voltage interrupters, for understanding the complex physics and the probability of thermal breakdown. The four main parts of arc model for this virtual-reality are radiation, PTFE ablation, Cu evaporation, and turbulence. Among these important parts the turbulence model can be critical to the reliability of computation results during the whole arcing history because the plasma flow is affected by high heat energy and mass momentum. Two turbulence models, the Prandtl's mixing length model and the standard $k-\varepsilon$ model, are applied for these calculations and are compared with pressure-rise inside chamber and arc voltage between the contacts as well as flow characteristics near current zero.