• The Journal of Korean Academy of Prosthodontics
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• v.45 no.1
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• pp.85-97
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• 2007

Statement of problem: Recently, anodic oxidation of cp-titanium is a popular method for treatment of titanium implant surfaces. It is a relatively easy process, and the thickness, structure, composition, and the microstructure of the oxide layer can be variably modified. Moreover the biological properties of the oxide layer can be controlled. Purpose: In this study, the roughness, microstructure, crystal structure of the variously treated groups (current, voltage, frequency, electrolyte, thermal treatment) were evaluated. And the specimens were soaked in simulated body fluid (SBF) to evaluate the effects of the surface characteristics and the oxide layers on the bioactivity of the specimens which were directly related to bone formation and integration. Materials and methods: Surface treatments consisted of either anodization or anodization followed thermal treatment. Specimens were divided into seven groups, depending on their anodizing treatment conditions: constant current mode (350V for group 2), constant voltage mode (155V for group 3), 60 Hz pulse series (230V for group 4, 300V for group 5), and 1000 Hz pulse series (400V for group 6, 460V for group 7). Non-treated native surfaces were used as controls (group 1). In addition, for the purpose of evaluating the effects of thermal treatment, each group was heat treated by elevating the temperature by $5^{\circ}C$ per minute until $600^{\circ}C$ for 1 hour, and then bench cured. Using scanning electron microscope (SEM), porous oxide layers were observed on treated surfaces. The crystal structures and phases of titania were identified by thin-film x-ray diffractmeter (TF-XRD). Atomic force microscope (AFM) was used for roughness measurement (Sa, Sq). To evaluate bioactivity of modified titanium surfaces, each group was soaked in SBF for 168 hours (1 week), and then changed surface characteristics were analyzed by SEM and TF-XRD. Results: On basis of our findings, we concluded the following results. 1. Most groups showed morphologically porous structures. Except group 2, all groups showed fine to coarse convex structures, and the groups with superior quantity of oxide products showed superior morphology. 2. As a result of combined anodization and thermal treatment, there were no effects on composition of crystalline structure. But, heat treatment influenced the quantity of formation of the oxide products (rutile / anatase). 3. Roughness decreased in the order of groups 7,5,2,3,6,4,1 and there was statistical difference between group 7 and the others (p<0.05), but group 7 did not show any bioactivity within a week. 4. In groups that implanted ions (Ca/P) on the oxide layer through current and voltage control, showed superior morphology, and oxide products, but did not express any bioactivity within a week. 5. In group 3, the oxide layer was uniformly organized with rutile, with almost no titanium peak. And there were abnormally more [101] orientations of rutile crystalline structure, and bonelike apatite formation could be seen around these crystalline structures. Conclusion: As a result of control of various factors in anodization (current, voltage, frequency, electrolytes, thermal treatment), the surface morphology, micro-porosity, the 2nd phase formation, crystalline structure, thickness of the oxide layer could be modified. And even more, the bioactivity of the specimens in vitro could be induced. Thus anodic oxidation can be considered as an excellent surface treatment method that will able to not only control the physical properties but enhance the biological characteristics of the oxide layer. Furthermore, it is recommended in near future animal research to prove these results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3246-3252
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• 2009

The interest on the recovery of thermal energy using the waste has been rising to solve the problems of continuous increase of waste generation and the depletion of the fossil fuel recently. The incineration has been used most popularly as a treatment process of the waste for the energy recovery. However, it is expected that incineration and design cost will increase in the treatment of air contaminant emitted from incinerator. This research has simulated the actual incinerator and the flue gas treatment system using the Aspen plus which is the software to simulate the chemical process. The incineration process is composed of the 1st and 2nd combustor to burn the waste, SNCR process to reduce the $NO_x$ using the urea, and the steam generation process to save the energy during incineration. The $Ca(OH)_2$ slurry was used as an acid gas (HCl, $SO_2$) treatment materials and the removal efficiency for the products from the neutralization of acid gas in SDA and combustion ash was simulated at the bag filter. The simulation result has been corresponded with the treatment efficiency of emitted gas from the actual industrial waste incinerator and it is presumed to be used to forecast the efficiencies of flue gas treatment system in the future.

• Korean Journal of Food Science and Technology
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• v.38 no.3
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• pp.385-391
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• 2006

Physicochemical properties of hydroxypropylated waxy rice starches were investigated to reduce steeping-time of yukwa (Korean oil-puffed rice snack) processing. Swelling power of hydroxypropylated waxy rice starch increased at relatively higher temperature $(60^{\circ}C)$ than native waxy rice starch $(70^{\circ}C)$. Solubility of hydroxypropylated waxy rice starches increased with increasing propylene oxide content. Pasting temperature $(66.3-66.9^{\circ}C)$ and peak viscosity (216-232 RVU) of hydroxypropylated waxy rice starch were higher than those of native starch (179 RVU) and increased with increasing propylene oxide content. DSC thermal transitions of hydroxypropylated waxy rice starches shifted toward higher temperature. Amylopectin melting enthalpy of hydroxypropylated waxy rice starch (8.4-9.2 J/g) was similar to native starch (9.0 J/g). X-ray diffraction patterns of native and hydroxypropylated waxy rice starches showed typical A-type pattern with no significant differences between them, suggesting hydroxypropylation only affected amorphous region. Results suggest hydroxypropylated waxy rice starch is not applicable for yukwa due to low puffing efficiency and dark color.

• Korean Journal of Food Science and Technology
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• v.32 no.3
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• pp.500-506
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• 2000

The effects of sodium stearoyl lactylate(SSL) on the thermal properties of wheat starch and amylopectin, and the crystallinity properties of amylopectin were investigated using differential scanning calorimetry(DSC) and X-ray diffractometer. On the rescan(second heating), amylopectin produced the featureless thermogram shown at the second heating, and SSL alone melted at $40{\sim}55^{\circ}C$, while the mixture of amylopectin containing 8% water and SSL(10:1), presenting the evidence of AP-SSL complex, showed differentiate melting temperature(other crystallinity) from SSL alone. Also, the melting enthalpy of AP and SSL mixture by subsequent heating and cooling were continuously increased. Further, the mixtures of wheat starch: SSL (5:1, w/w) and amylopectin: SSL(5:1, w/w), indicated AP-SSL complex, showed the reversible melting peak at temperature range of $60{\sim}70^{\circ}C$ together with melting peak of SSL observed at temperature range of $40{\sim}55^{\circ}C$. AP-SSL complex in the X-ray diffraction, compared V-form of amylose-lipid complex, exhibited characteristic peaks($2{\theta}$, 5.57, 20.903, 23.227). The gelatinization enthalpy value of wheat starch in the presence of SSL, observed at temperature range of $50{\sim}70^{\circ}C$, was decreased at total water content 60%, whearas had no significant effect at total water content 40, 50%, and also, SSL increased melting enthalpy of amylose-lipid complex. The extent of AP and wheat starch retrogradation wasreduced significantly by SSL.

• Journal of The Korean Astronomical Society
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• v.51 no.4
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• pp.89-110
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• 2018

Active Galactic Nucleus (AGN) variability can be used to study the physics of the region in the vicinity of the central black hole. In this paper, we investigated intra-night optical variability of AGN in the COSMOS field in order to understand the AGN instability at the smallest scale. Observations were performed using the KMTNet on three separate nights for 2.5 to 5 hours at a cadence of 20 to 30 min. We find that the observation enables the detection of short-term variability as small as ~ 0.02 and 0.1 mag for R ~ 18 and 20 mag sources, respectively. Using four selection methods (X-rays, mid-infrared, radio, and matching with SDSS quasars), 394 AGN are detected in the $4deg^2$ field of view. After differential photometry and ${\chi}^2$-test, we classify intra-night variable AGN. The fraction of variable AGN (0-8%) is statistically consistent with a null result. Eight out of 394 AGN are found to be intra-night variable in two filters or two nights with a variability level of 0.1 mag, suggesting that they are strong candidates for intra-night variable AGN. Still they represent a small population (2%). There is no sub-category of AGN that shows a statistically significant intra-night variability.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.599_600
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• 2009

In superconducting magnetic energy storage (SMES) systems, the current leads are usually divided into two parts. Normal metals like brass or copper are often used in the first part from the room temperature to the 1st stage of the cryocooler. Their dimensions were decided to minimize the conduction heat penetration and Ohm's heat generation. The second part down to the cryogenic coil is made of high temperature superconductor (HTS). HTS current leads can reduce the conductive heat penetration because they have poor thermal conductivity and generate no Ohm's heat generation. The brass current lead and the HTS current lead were designed and fabricated for application to the 10kJ class SMES system. The HTS current lead is 300A class. The HTS current lead was stacked with 2 HTS layers using the $Bi_2Sr_2Ca_2Cu_3O_x$ (BSCCO)/Ag. In this paper, we introduce the design procedure of the current leads and discuss the test results of the current leads.

• Journal of Microbiology and Biotechnology
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• v.30 no.8
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• pp.1207-1213
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• 2020

Aflatoxin B1 (AFB1) is a mycotoxin produced by Aspergillus flavus (A. flavus). AFB1 is reported to have high thermal stability and is not decomposed by heat treatment during food processing. Therefore, in this study, knowing that AFB1 is metabolized by cytochrome P450 (CYP), our aim was to develop a method to detoxify A. flavus-contaminated maize, under normal temperature and pressure, using Escherichia coli expressing human CYP3A4. First, the metabolic activity of AFB1 by recombinant human CYP3A4 was evaluated. As a result, we confirmed that recombinant human CYP3A4 metabolizes 98% of AFB1. Next, we found that aflatoxin Q1, a metabolite of AFB1 was no longer mutagenic. Furthermore, we revealed that about 50% of the AFB1 metabolic activity can be maintained for 3 months when E. coli expressing human CYP3A4 is freeze-dried in the presence of trehalose. Finally, we found that 80% of AFB1 in A. flavus-contaminated maize was metabolized by E. coli expressing human CYP3A4 in the presence of surfactant triton X-405 at a final concentration of 10% (v/v). From these results, we conclude that AFB1 in A. flavus-contaminated maize can be detoxified under normal temperature and pressure by using E. coli expressing human CYP3A4.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.4
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• pp.1923-1930
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• 2012

Mn-Cu catalysts were tested for selective catalytic reduction of NOx with NH3. Influence of initial reaction temperature was studied for NOx conversion in which reaction temperature was changed three patterns. NOx conversion of catalysts calcined at 200, 300 and $340^{\circ}C$ was measured during the changing temperature. Hydrogen conversion efficiency of calcined catalysts was also measured in the $H_2$-TPR system. The deactivation effect of $SO_2$ on catalyst was investigated with the on-off control of $SO_2$ supply. The catalyst which calcined above $340^{\circ}C$ was somewhat deactivated with thermal shock. The reason of deactivation was draw from the results of surface area and hydrogen conversion.

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1777-1783
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• 2014

Four $Cd^{II}$ MOFs, $[Cd_2({\mu}-succinate)_2(H_2O)_2]{\cdot}H_2O$ (1A), $[Cd_2({\mu}-succinate)_2({\mu}-4,4^{\prime}-bpy)_2]{\cdot}H_2O$ (1B), $[\{Cd_2({\mu}-succinate)_2\}({\mu}-bpa)_2\{Cd(H_2O)_2\}(NO_3)_2]{\cdot}H_2O$ (2), and $[Cd({\mu}-succinate)({\mu}-bpp)_2]{\cdot}2H_2O$ (3), with various bipyridyl ligands (4,4'-bipyridine (4,4'-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of $Cd^{II}$-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

• Advances in concrete construction
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• v.10 no.5
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• pp.443-454
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• 2020

In recent years, many studies have been done on the performance of concrete containing glass powder (GP). For the purpose of widespread use of GP in concrete mixes, a knowledge of the performance of such a mixture after a fire is essential for the perspective of structural use. This research work was carried out to evaluate the performance of High Performance Concrete (HPC) made with GP after being exposed to elevated temperature. The studied mixtures include partial replacement of cement by GP with up to 30%. The mechanical performance and structural alterations were assessed after high temperature treatment from 200℃ to 800℃. The mechanical performance was evaluated by testing the specimens to the compressive and tensile strength. In addition, the mass loss and the porosity were measured to notice the structural alterations. Changes in microstructure due to temperature was also investigated by the X-ray diffraction (XRD) and thermal gravimetric analyses (TGA) as well as porosity adsorption tests. The results of the concrete strength tests showed a slight difference in compressive strength and the same tensile strength performance when replacing a part of the cement by GP. However, after high temperature exposition, concrete with GP showed better performance than the reference concrete for temperature below 600℃. But, after heating at 800℃, the strength of the concrete with GP drop slightly more than reference concrete. This is accompanied by an important increase in mass loss and water porosity. After the microstructure analysis, no important changes happened differently for concrete with GP at high temperature except a new calcium silica form appears after the 800℃ heating.