• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.1095-1099
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• 2008

Critical state theory involves two state boundary surface. One is Roscoe surface and the other is Hvorslev surface. The shape of these boundary surface was changed because of several parameters : Critical state constant(M), spacing ratio (r) and critical state pore pressure coefficient($\wedge$). As these constants make difference to each model and the way of solution, they may affect the shape of state boundary surface. Specially, spacing ratio (r) is important. On this study, triaxial compression test was performed using remolded weathered mudstone soil and investigated variation of state boundary surface because of spacing ratio. In the results of prediction, critical state point was located highly and the shape of boundary surface was changed more tightly curve as decreasing spacing ratio.

• Geotechnical Engineering
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• v.8 no.2
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• pp.45-58
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• 1992

An elasto-plastic constitutive model for geological materials, which satisfies the flezibility and stability at the same time, can be used in a number of geotechnical problems. Using the spacing ratio of critical state, a flexible model is proposed based on the stability of modified Camflay model. The spacing ratio of critical state can be simply evaluated, and practically used in describing the undrained shearing behavior of clay. The proposed model has precisely predicted the stress paths and stress -strain relationships, compared with the modified Camflay model, with respect to undrained triaxial test results. Besides, the effects of strain rate, creep, and relaxation can also be considered. Using the quasi-state boundary surface, the constitutive relations are well predicted. Therefore, it is found that the assumption of associative flow rule is well posed for undrained behavior of normally consolidated clay.

• International Journal of Naval Architecture and Ocean Engineering
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• v.7 no.5
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• pp.906-919
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• 2015

The Deep Draft Semi-Submersible (DDS) concepts are known for their favourable vertical motion performance. However, the DDS may experience critical Vortex-Induced Motion (VIM) stemming from the fluctuating forces on the columns. In order to investigate the current-induced excitation forces of VIM, an experimental study of flow characteristics around four square-section cylinders in a square configuration is presented. A number of column spacing ratios and array attack angles were considered to investigate the parametric influences. The results comprise flow patterns, drag and lift forces, as well as Strouhal numbers. It is shown that both the drag and lift forces acting on the cylinders are slightly different between the various L/D values, and the fluctuating forces peak at L/D = 4.14. The lift force of downstream cylinders reaches its maximum at around ${\alpha}=15^{\circ}$. Furthermore, the flow around circular-section-cylinder arrays is also discussed in comparison with that of square cylinders.

• Journal of the Korean Geotechnical Society
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• v.21 no.4
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• pp.31-40
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• 2005

This study proposed a new yield function considering the spacing ratio of the critical state to predict the undrained shear behavior of anisotropic field ground. We have suggested a nonassociated constitutive model that used a newly modified plastic potential function in order to apply the yield function of the modified Cam-Clay model to the anisotropic consolidation. In this paper, we predicted undrained shear behavior of the remolded weathered mudstone soils in Phohang isotorpically and anisotropically consolidated using the suggested model. To evaluate the reliability of proposed model, we predictied undrained shear behavior of Bankok Clay isotropically, nomally consolidated and Drammen Clay Ko consolidated. The predicted results are consistent with the observed behavior.

• Geotechnical Engineering
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• v.10 no.1
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• pp.7-18
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• 1994

A new model for describing the behavior of clay under monotonic and cyclic loading is proposed. This model uses the hyperbolic representation for the stress -strain relationship in overconsolidated state and it describes undrained effective stress path on the basis of the critical state theory. The developed constitutive model by using an energy dissipation equation can describe the behavior of clay in heavily overconsolidated state as u.ell as lightly overconsolidated state under monotonic loading. In order to extend the model for the behavior of clay under cyclic loading, a shift function of undrained stress spacing ratio is introduced in the constitutive model developed for monotonlc loading. A single additional parameter is required to represent the cyclic effect and it can be reasonably deter mined from the test results. The measured behavior in undrained cyclic triaxial tests has been easily and precisely predicted by the newly developed constitutive model.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.11.2-11.2
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• 2011

Polymer based organic photovoltaics have attracted a great deal of attention due to the potential cost-effectiveness of light-weight and flexible solar cells. However, most BHJ polymer solar cells are not thermally stable as subsequent exposure to heat drives further development of the morphology towards a state of macrophase separation in the micrometer scale. Here we would like to show three different approaches for developing new electroactive polymers to improve the thermal stability of the BHJ solar cells, which is a critical problem for the commercialization of these solar cells. For one of the examples, we report a new series of functionalized polythiophene (PT-x) copolymers for use in solution processed organic photovoltaics (OPVs). PT-x copolymers were synthesized from two different monomers, where the ratio of the monomers was carefully controlled to achieve a UV photo-crosslinkable layer while leaving the ${\pi}-{\pi}$ stacking feature of conjugated polymers unchanged. The crosslinking stabilizes PT-x/PCBM blend morphology preventing the macro phase separation between two components, which lead to OPVs with remarkably enhanced thermal stability. The drastic improvement in thermal stabilities is further characterized by microscopy as well as grazing incidence X-ray scattering (GIXS). In the second part of talk, we will discuss the use of block copolymers as active materials for WOLEDs in which phosphorescent emitter isolation can be achieved. We have exploited the use of triarylamine (TPA) oxadiazole (OXA) diblock copolymers (TPA-b-OXA), which have been used as host materials due to their high triplet energy and charge-transport properties enabling a balance of holes and electrons. Organization of phosphorescent domains in TPA-b-OXA block copolymers is demonstrated to yield dual emission for white electroluminescence. Our approach minimizes energy transfer between two colored species by site isolation through morphology control, allowing higher loading concentration of red emitters with improved device performance. Furthermore, by varying the molecular weight of TPA-b-OXA and the ratio of blue to red emitters, we have investigated the effect of domain spacing on the electroluminescence spectrum and device performance.