• Journal of the Korean Electrochemical Society
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• v.2 no.3
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• pp.123-129
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• 1999

Initial electrochemical characteristics of $LiCoO_2$ electrode for lithium ion battery with various content of super s black as conductive material were evaluated through the charge/discharge with the potential range of 4.3V to 2.0V versus $Li^+/Li^+$. The rate of C/4 and C/2 by the 3 electrode test cell composed with an electrolytic solution of 1 mol/l $LiPF_6/EC+DEC(1:3\;by\; weight)$. Lithium was used as reference electrode. High impedance charge behavior was observed at early stage of charge. In the case of $3\%w/w$ of super s black as conductive material, the specific resistance of the high impedance releasing was $3.82\;{\Omega}\;{\cdot}\;g-LiCoCo_2$ at the current density of $0.5 mA/cm^2$, which corresponds 7 times of the specific resistance of electrode $(0.728 g-LiCoO_2)$. At second charge, the specific resistance of the high impedance releasing was 63 mn · g-Lico02, which corresponds 12eio of the specific resistance of electrode and only $1.7\%$ of that of the first charge. The first charge and discharge specific capacities at C/4 rate were 160-161 and $153\~155mAh/g-LiCoO_2$, respectively, to lead $95.4\~96.4\%$ of coulombic efficiencies and ca. $6 mAh/g-LiCoO_2$ of initial irreversible specific capacity. Specific resistance at the end of charge and rest showed low value at content of super s black between 2 and $7\%w/w$, which agreed with characteristics of irreversible specific capacity. Capacity densities were reduced by the increasing the content of conductive material. They were 447 and 431mAh/ml when 2 and $2.9\%w/w$ of super s black were used, respectively, at the rate of C/4.

• Journal of the Korean Electrochemical Society
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• v.15 no.3
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• pp.198-205
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• 2012

Carbon-supported manganese oxide composite were fabricated as an air cathode material for Li-air batteries by hydrothermal method. The composite materials of carbon and manganese oxide were investigated by the implementation of X-ray diffraction, FE-SEM and BET surface area measurer. The manganese oxide synthesized at $170^{\circ}C$ for 12 h has a rod like shape morphology with 40-50 nm long in size. A Lithium-air battery with coin type, of which electrodes are composed of cathode composite materials synthesized $170^{\circ}C$-12 h and lithium metal anode, reveals its first discharge capacity of 3,852 mAh/g and four discharge-charge cycles.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.12
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• pp.842-849
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• 2007

For a $CO_2$ two-stage twin rotary compressor used for heat pump water heater system, changes of $CO_2$ solubility in PAG oil were investigated along the gas passages from the first stage suction to final discharge. Only slight changes in solubility took place in suction chambers for both of the first and second stages, but for compression chambers, solubility variation ranged from 0.115 to 0.136, and from 0.133 to 0.182, respectively for the first and second stages. Calculation of gas flashing in parts of leakage oil flows and of oil contained in control volumes due to solubility changes was conducted and included in gas pressure calculation. For the second stage, gas flashing amounts to around $5%\sim6%$ for most leakage flows. Cooling capacity, compressor input, and COP obtained by calculation were well compared to the experimental results. Effects of operation speed on the compressor performance was also studied: as the shaft speed increased, adiabatic efficiency decreased rapidly due to increased over-compression loss.

• Bulletin of the Korean Chemical Society
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• v.20 no.5
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• pp.508-516
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• 1999

Polycrystalline powder of LixNi0.85Co0.15O2 was synthesized by pyrolyzing a powder precursor obtained by the PVA-precursor method. Coin cells of lithium-ion rechargeable battery were assembled, whose the cathodes were fabricated from the crystalline powders of LixNi0.85Co0.15O2 synthesized by the method. The effect of synthetic variation on the property of the cell was tested by carrying out 100 consecutive cycles of charge-dis-charge on the cells. The property of the cell was largely influenced by the pyrolysis conditions applied for the synthesis of the LixNi0.85Co0.15O2. Depending on whether the pyrolysis was carried out in standing air or in the flow of dry air, the discharge capacity and cycle-reversibility of the cell varied in large extent. When the powder precursor was pyrolyzed in standing air, a minor phase of lithium carbonate was remained in the LixNi0.85Co0.15O2. The carbon containing powder precursor had to be pyrolyzed in the flow of dry air to eliminate the minor phase. In the flow of dry air, the lithium carbonate in the precursor was eliminated over 500-700。C without any prominent heat event. By controlling the flow of air over the precursor during its pyrolysis, particle size could also be altered. The effect of flowing dry air, during first step pyrolysis or during second step heat treatment, on the property of the cell was discussed.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.10
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• pp.530-538
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• 2004

A electromagnetic waves are used for sensing in insulation diagnosis at electric machine or equipment. When it a method, waves are transformed into the FFT(Fast Fourier Transform); a kind of the process for data transformation. In a general way, a scientist use frequncy band 30[㎒]～l[㎓] to applied field. If we are measured high frequency band, we will need to a high capacity hardware. Also a antenna has a fault on atmospheric phenomena, outside environment and the like. In this paper We proposed new method for detecting electric equipment faulty state using only electric voltage which is generally measured in the electric and electronic field. It is called the Partition-FFT The analytic method is this first divide measured voltage waves into equal parts, second each deal with give effect to the FFT, finally each results deal with a graphic method and gather graphic. We are compare Partition-FFT with discharge form by tracking tester. As the result it demonstrated that the Partition-FFT is applicable.

• Journal of the Korean Ceramic Society
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• v.47 no.6
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• pp.638-642
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• 2010

The spinel material $Li_4Ti_5O_{12}$ has attracted considerable attention as an anode electrode material for many battery applications owing to its light weight and high energy density. However, the real capacity of $Li_4Ti_5O_{12}$ powder as determined by the solid-state method is lower than the ideal capacity. In this study, we investigated the effect of the dopants in M-doped spinel $Ba_xLi_{4-2x}Ti_5O_{12}$(x=0.005, 0.05, 0.1) powders prepared by the solid-state reaction method and used as the anode material in lithiumion batteries. The results confirmed the effect of the Ba and Sr dopants on the powder properties of the spinel $Li_4Ti_5O_{12}$, which exhibited a pure spinel structure without any secondary phase in its XRD pattern. Moreover, the electrochemical properties of the spinel M-LTO materials were investigated using a half cell. The electrochemical data show that cells with anodes made of undoped $Li_4Ti_5O_{12}$ and Ba- and Sr-doped $Li_4Ti_5O_{12}$ have discharge capacities of 97, 130, and 112 mAh/g, respectively, at the first cycle. Moreover, the Ba- and Sr-doped spinel $Li_4Ti_5O_{12}$ demonstrated good properties in the mid-voltage range at 1.55 V, showing stable cyclic voltammogram properties which surpassed those of the same material without Ba or Sr at 1 C after 100 cycles.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.396-396
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• 2015

Frequent urban floods affect the human safety and economic properties due to a lack of the capacity of drainage system and the increased frequency of torrential rainfall. The drainage system has played an important role in flooding control, so it is necessary to establish the effective countermeasures considering the connection between drainage system and surface flow. To consider the connection, we selected SWMM5 model for analyzing transportation capacity of drainage system and FLUMEN model for calculating inundation depth and time variation of inundation area. First, Thiessen method is used to delineate the sub-catchments effectively base on drainage network data in SWMM5. Then, the output data of SWMM5, hydrograph of each manhole, were used to simulate FLUMEN to obtain inundation depth and time variation of inundation area. The proposed method is applied to Sadang area for the event occurred in $27^{th}$ of July, 2011. A total of 11 manholes, we could check the overflow from the manholes during that event as a result of the SWMM5 simulation. After that, FLUMEN was utilized to simulate overland flow using the overflow discharge to calculate inundation depth and area on ground surface. The simulated results showed reasonable agreements with observed data. Through the simulations, we confirmed that the main reason of the inundation was the insufficient transportation capacities of drainage system. Therefore cooperation of both models can be used for not only estimating inundation damages in urban areas but also for providing the theoretical supports of the urban network reconstruction. As a future works, it is recommended to decide optimized pipe diameters for efficient urban inundation simulations.

• Journal of Hydrogen and New Energy
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• v.32 no.4
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• pp.256-262
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• 2021

A carbon felt electrode was prepared using ozone and ammonia sequential treatment and applied as an electrode for a vanadium redox flow battery (VRFB). The physical and electrochemical analyses demonstrate that the oxygen groups facilitate nitrogen doping in the carbon felt. Carbon felt (J5O3+NH3), which was subjected to ammonia heat treatment after ozone treatment, showed higher oxygen and nitrogen contents than carbon felt (J5NH3+O3), which was subjected to ammonia heat treatment first and then ozone treatment. From the charging/discharging of VRFB, the J5O3+NH3 carbon felt electrode showed 14.4 Ah/L discharge capacity at a current density of 150 mA /cm², which was 15% and 33% higher than that of J5NH3+O3 and non-activated carbon felt (J5), respectively. These results show that ozone and ammonia sequential treatment is an effective carbon felt activation method to increase the performance of the vanadium redox flow battery.

• Environmental Engineering Research
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• v.17 no.4
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• pp.197-203
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• 2012

Phosphorus removal during discharge of wastewater is required to achieve in a very high level because eutrophication occurs even at a very low phosphorus concentration. However, there are limitations in the traditional technologies in the removal of phosphorus at very low concentration, such as at a level lower than 0.1 mg/L. Through a series of experiments, a possible technology which can remove phosphate to a very low level in the final effluent of wastewater was suggested. At first Al, Zn, Ca, Fe, and Mg were exposed to phosphate solution by impregnating them on the surface of activated alumina to select the material which has the highest affinity to phosphate. Kinetic tests and isotherm tests on phosphate solution have been performed on four media, which are Ca-impregnated activated alumina, activated alumina, Ca-impregnated loess ball, and loess ball. Results showed that Ca-impregnated activated alumina has the highest capacity to adsorb phosphate in water. Scanning electron microscope image analysis showed that activated alumina has high void volume, which provides a large surface area for phosphate to be adsorbed. Through a continuous column test of the Ca-impregnated activated alumina it was discovered that about 4,000 bed volumes of wastewater with about 0.2 mg/L of phosphate can be treated down to lower than 0.14 mg/L of concentration.

• Journal of the Korean Electrochemical Society
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• v.15 no.3
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• pp.160-164
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• 2012

The lead-acid batteries are the most often used in human life, because of their low cost, good reversibility and high potential but they have limit cycle ability with low capacitance. The main causes of this problem are forming recrystallization of $PbSO_4$ on electrodes surface during cycles which the recrystallization of $PbSO_4$ is known as sulfation. In this study, formation process of sulfation was investigated depending on charge and discharge cycle numbers. And we decomposed sulfation to renew cycle ability of lead-acid batteries. The renewed lead-acid batteries recovered to 84% compared to first capacity after 600 cycles.