• Bulletin of the Korean Chemical Society
• /
• v.32 no.5
• /
• pp.1564-1568
• /
• 2011

A solvent extraction separation, preconcentration and determination of thorium with a new crown, 2-ethyl-N-benzyl-4,7,10,13,16-pentaoxa-1-azacyclooctadecane (MACE), is described in the study. The amount of thorium in the aqueous phase and organic phase was determined by Inductively Coupled Plasma-Optical Emission Spectroscopy and Ultraviolet-Visible, respectively. Thorium loaded organic phase was quantitatively stripped in a stage by using 1.0 M $HNO_3$. Thorium was effectively extracted with MACE in the pH range of 6-7 to produce a 3:2 complex ratio in the chloroform. A highly sensitive and rapid spectrophotometric method was described for determination of trace amounts of thorium with MACE. The effective molar absorption coefficient at 281 nm is $1.98{\times}10^3\;mol^{-1}cm^{-1}$, and the system complies with Beer's law in the range from 0.464 to 2.32 ${\mu}gm\;L^{-1}$ of thorium. Thorium was also determined in standard and environmental samples.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.11 no.3
• /
• pp.235-240
• /
• 2001

This study was performed to compare the lead levels of 20 quality control standard samples(KOSHA:18-2000) and 72 field samples in lead-acid battery manufacturing plant between ICP and portable-XRF methods. 1. While the proficiencies of 20 quality control standard samples by ICP were 100%, those of analytic result values by XRF were 75%. 2. The correlation coefficient(r) between the reference values for quality control (REF) and the analytic result values by ICP (ICP) was 1.0(p<0.05), and simple linear regression equation and the coefficient(R2) were REF = -0.0009 + 1.016 ICP and 0.9997, respectively. 3. The correlation coefficient(r) between the analytic result values of quality control standard samples by ICP (ICP) and by XRF (XRF) was 0.975(p<0.05), and simple linear regression equation and the coefficient(R2) were ICP = -0.0003 + 1.002 XRF and 0.950, respectively. 4. The correlation coefficient(r) between the analytic result values for lead samples of a lead-acid battery manufacturing plant by ICP (ICP) and by XRF (XRF) was 0.993(p<0.05), and simple linear regression equation and the coefficient(R2) were ICP = -2.058 + 0.996 XRF and 0.987, respectively. 5. While the frequency distributions of XRF /ICP(Ratio) for each ICP concentration levels in a lead-acid battery manufacturing plant revealed high proportion in ratio range of 0.876-1.125 than in ration range of 1.126-1.375. Also, ICP concentration level in ration range of 0.786-1.125 was increased with increase of frequency distribution of XRF/ICP. 6. The limit of detection of XRF on lead was determined to be $6.11{\mu}g$/filter The data presented in this study indicated that relationship for lead level of quality control samples and field samples in a lead -acid battery manufacturing plant by ICP and portable-XRF methods was proved. The practicing industrial hygienist can use portable-XRF to produce a rapid on-site determination of lead exposure that can immediately becommunicated to workers and help identify appropriate levels of personal protection.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.3
• /
• pp.178-184
• /
• 2014

In this study, monitoring method which is more economic and easier in maintenance comparing to existing monitoring system was scrutinized for application to sewer intercepting chamber of 10.2 ha basin area by estimating CSOs (Combined Sewer Overflows) quantity and quality with 2 rainfall events using electrical conductivity data and civil research model. The result showed that determination coefficient of flow estimation by EC (Electrical Conductivity) dilution ratio and observed data was over 0.86 for all cases and the accuracy of estimation was improved from 0.5 to 0.8 for determination coefficient ($R^2$) and from 54.1% to 68.5% for accumulation frequency of relative error by considering antecedent dry days and rainfall duration. CSOs water quality estimation results by civil research model showed that determination coefficients were 0.64~0.97 for BOD and 0.70~0.95 for SS.

• Proceedings of the KSRS Conference
• /
• 2003.11a
• /
• pp.103-106
• /
• 2003

Retrieval of ocean color information from Multispectral Camera (MSC) on KOMPSAT-2 was investigated to study and characterize small-scale biophysical features in the coastal oceans. Prior to the derivation of such information from space-acquired ocean color imageries, the atmospheric effects largely from path and the air-sea interface should be removed from the total signal recorded at the top of the atmosphere (T$_{TOA}$). In this study, the 'path-extraction' is introduced and demonstrated on the TM and SeaWiFS imageries of highly turbid coastal waters of Korea. The algorithms for retrieval of ocean color information were explored from the remote reflectance (R$_{rs}$) in the visible wavebands of MSC. The determination of coefficient (R$^{2}$) for log-transformed data [ N = 500] was 0.90. Similarly, the R$^{2}$ value for log-transformed data [ N = 500] was found to be 0.93.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.52 no.1
• /
• pp.1-11
• /
• 2010

Generation and transportation of runoff and pollutant loads within watershed generated eutrophication at Daecheong reservoir. To improve water quality at Daecheong reservoir, the best management practices should be developed and applied at upper watersheds for water quality improvement at downstream areas. In this study, two small watersheds of upper Daecheong reservoir were selected. The Long-Term Hydrologic Impact Assessment (L-THIA) model has been widely used for the estimation of the direct runoff worldwide. To apply the L-THIA ArcView GIS model was evaluated for direct runoff and water quality estimation at small watershed. And the Web-based Hydrograph Analysis Tool (WHAT) was used for direct runoff separating from total flow. As a result, the $R^2$ (Coefficient of determination) value and Nash-Sutcliffe coefficient value for direct runoff comparison at An-nae watershed were 0.81 and 0.71, respectively. And the $R^2$ value and Nash-Sutcliffe coefficient value at Wol-oe were 0.95 and 0.93. The $R^2$ value of BOD, TOC, T-N and T-P at An-nae watershed were BOD 0.94, TOC 0.81, T-N 0.94 and T-P 0.89. And the $R^2$ value of BOD, TOC, T-N and T-P at Wol-oe watershed were BOD 0.80, TOC 0.93, T-N 0.86 and T-P 0.65. The result that estimated pollutant loadings using the L-THIA ArcView GIS model reflected well the measured pollutant loadings except for T-P in Wol-oe watershed. With L-THIA ArcView GIS model, the direct runoff and non-point pollutant (NPS) loadings in the watershed could be analyzed through simple input data such as daily rainfall, land uses, and hydrologic soil group.

• Journal of the Korean Applied Science and Technology
• /
• v.29 no.4
• /
• pp.585-593
• /
• 2012

The EO separation and quantitative determination of polysorbate 20, polysorbate 40, polysorbate 60 and polysorbate 80 was carried out by reversed phase HPLC. The water/acetonitrile was used for the mobile phase of gradient conditions. An YMC Pack Ph ($250mm{\times}4.6mm$ i.d., $5{\mu}m$) and Phenomenex C4 ($250mm{\times}4.6mm$ i.d., $5{\mu}m$) and the selected ELSD detector was applied. The analysis results of HPLC showed good linearity with correlation coefficient of $r^2$=0.997 in the rage of $180.2{\sim}980.5{\mu}g/mL$ and detection limit.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.7
• /
• pp.1516-1520
• /
• 2009

A sensitive technique for the determination of trace Co(II) in various samples after column preconcentration by adsorbing onto silica gel loaded with 1-nitroso-2-naphthol was developed. Several experimental conditions, such as pH of sample solution, the amount of silica gel loaded with 1-nitroso-2-naphthol, the flow rate for adsorption and so forth, were optimized. The interfering effects of diverse concomitant ions were investigated. Fe(III) interfered with more than any other ions, but the interference by Fe(III) was completely eliminated by adjusting the amount of silica gel loaded with 1-nitroso-2-naphthol to 0.30 g. The dynamic range, the correlation coefficient ($R^2$), and the detection limit obtained by the proposed technique were 3.0-140.0 ng m$L^{-1}$, 0.9942, and 1.81 ng m$L^{-1}$, respectively. For validating the technique, the aqueous samples (tap water, reservoir water, stream water, and wastewater) and the plastic samples were used as real samples. Recovery yields of 93.0-107.0% were obtained. These measured data were not different from ICP-MS data at the 95% confidence level by F test. Based on the results of the experiment, it has been found that the proposed technique can be applied to the determination of Co(II) in various real samples.

• Journal of Korean Society of Water and Wastewater
• /
• v.19 no.4
• /
• pp.487-496
• /
• 2005

Chlorine bulk decay tests were carried out by bottle test under controlled conditions in a laboratory. Experiments were performed at different temperatures: $5^{\circ}C$, $15^{\circ}C$, $25^{\circ}C$, and the water temperatures when samples were taken from the effluent just before entering to its distribution system. 38 bulk tests were performed for water of Al (water treatment plant), 4 bulk tests for A2 (large service reservoir), and A3(pumping station). Residual chlorine concentrations in the amber bottles were measured over time till about 100 hours and bulk decay coefficients were evaluated by assuming first-order, parallel first-order, second-order. and $n^{th}-order$ reaction. The $n^{th}-order$ coefficients were obtained using Fourth-order Runge-Kutta Method. A good-fit by the average coefficient of determination ($R^2$) was first-order ($R^2=0.90$) < parallel first-order ($R^2{_{fast}}=0.92$, $R^2{_{slow}}=0.95$) < second-order ($R^2=0.95$) < $n^{th}-order$ ($R^2=0.99$). But if fast reaction of parallel first-order bulk decay were applied to the effluent of large service reservoir with ca. 20 hours of travel time and slow reaction in the water distribution system following the first 20 hours, parallel first-order bulk decay would be best and easy for application of water quality modeling technique.

• ALGAE
• /
• v.28 no.3
• /
• pp.289-296
• /
• 2013

For the quantitative detection of algal toxin, microcystin, a chemiluminescence immunochromatographic assay method was developed. The developed system consists of four parts, chemiluminescence assay strip (nitrocellulose membrane), horse radish peroxidase labeled microcystin monoclonal antibodies, chemiluminescence substrate (luminol and hydrogen peroxide), and luminometer. The performance of the chemiluminescence immunochromatographic assay system was compared with high performance liquid chromatography (HPLC) detection. The detection limit of chemiluminescence immunochromatographic assay system is several orders of magnitude lower than with HPLC. The chemiluminescence immunochromatography and HPLC results correlated very well with the correlation coefficient ($r^2$) of 0.979.

• Journal of Biosystems Engineering
• /
• v.43 no.3
• /
• pp.229-236
• /
• 2018

Purpose: Makgeolli is a traditional alcoholic beverage made from rice with a fermentation starter called "nuruk." The concentration of alcohol in makgeolli depends on the temperature of the fermentation tank. It is important to monitor the alcohol concentration to manage the makgeolli production process. Methods: Data were collected from 84 makgeolli fermentation tanks over a year period. Independent variables included the temperatures of the tanks and the room where the tanks were located, as well as the quantity, acidity, and water concentration of the source. Software for the multilayer perceptron model (MLP) was written in Python using the Scikit-learn library. Results: Many models were created for which the optimization converged within 100 iterations, and their coefficients of determination $R^2$ were considerably high. The coefficient of determination $R^2$ of the best model with the training set and the test set were 0.94 and 0.93, respectively. The fact that the difference between them was very small indicated that the model was not overfitted. The maximum and minimum error was approximately 2% and the total MSE was 0.078%. Conclusions: The MLP model could help predict the alcohol concentration and to control the production process of makgeolli. In future research, the optimization of the production process will be studied based on the model.