• Title/Summary/Keyword: Tetradecane

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Physical Properties of Microencapsulated Phase Change Material Slurries (미립잠열슬러리의 물성에 관한 실험적 연구)

  • 이효진;홍재창;이재구
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.9
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    • pp.860-869
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    • 2000
  • The thermal conductivity and density of slurries entrained with the particles of Micro-PCM are measured with respect to its temperatures as well as concentrations. For the thermal conductivity of slurries, a device made from P.A. Hilton (Model No. H470) is adopted. There is a well-scaled 0.3 mm gap between shells into which the slurry is injected. The temperatures of the slurry are changed to $5~25^{\circ}C$ , for which it is controled by the supplied voltage and cooling water circulated around the outer shell. The concentrations of Micro-PCM slurries are varied from 5 wt% to 50 wt%. Some general equations such as Maxwell's equation, are evaluated for their applicability with Micro-PCM slurry. As a result, it happens to be some 20% discrepancy between the experiment and the applied equations. The density measurements of Micro-PCM slurry to its temperature and concentration are peformed by hydrometer. For the experiment, tetradecane encapsulated slurry (($t_m≒6^{\circ}C$) and a mixed wax ($t_m≒50^{\circ}C$) are tested. The temperature changes of tetradecane are applied for $0^{\circ}C\;to\;$20^{\circ}C$and a mixed wax for $20^{\circ}C\;to\;$60^{\circ}C$ and its concentrations are changed from 5 wt% to 30 wt%. The results are compared with a general equation and the referenced data. For the conclusion, the experimental result and a general equation are well agreed.

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Changes of Flavor Components in Chewing Gum during Storage by Gas Chromatography/Mass Spectrometry (GC/MS에 의한 저장중 츄잉껌 향기성분 변화연구)

  • Shin, Seong-Kee;Kim, Sang-Ho;Lee, Yoon-Hyung;Rhee, Kyu-Soon
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.25-28
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    • 1992
  • The changes of amount in flavor components of chewing gum during storage of various relative humidity were studied by GC/MS. The volatile components in chewing gum were extracted by sample preperation and 15 volatile components were identified by NIST/NBS library searching. According to the period of storage, quantities of major volatile components extracted by tetrahydrofuran-methanol solutions were determined by using tetradecane as internal standard. Until 4 weeks, comparing with starting peak area ratio, the decrease of chewing gum flavor components were rapid at 33, 75 than 53 R.H(%). And after 16 weeks, amount of chewing gum flavor at all storage conditions similarly decreased to $45{\sim}49%$ of the initial amount.

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Thermal Storage and Thermodynamic Characteristics of Phase Change Materials Slurries

  • Kwon, Ki-Hyun;Jeong, Jin-Woong;Kim, Jong-Hoon;Kim, Yong-Joo;Choi, Chang-Hyun
    • Food Science and Biotechnology
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    • v.18 no.6
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    • pp.1392-1397
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    • 2009
  • This study was aimed at developing a low cost cold storage system for agricultural products. Three kinds of slurries: $K_1$, $K_2$, and $K_3$ slurries were developed using phase change materials (PCMs) such as tetradecane, octadecane, and sodium polyacrylate to maintain the desired temperature ranges. The slurries were manufactured by in-situ polymerization. Tetradecane and octadecane were capsulated in a core with melamine at the surface. The thermodynamic characteristics of the slurries were measured and analyzed. The latent heats of the $K_1$, $K_2$, and $K_3$ slurries at the melting points were 206.41, 186.88, and 147.91 kJ/kg, respectively. A transportable cold storage container was built to investigate the performance of the slurries as thermal storage media. The temperatures at the insides of the container could be maintained in the ranges of 0-5, 5-10, and $10-15^{\circ}C$ for more than 23, 27, and 60 hr with the $K_1$, $K_2$, and $K_3$ slurries, respectively.

The Study of Encapsulation Technique for Microcapsule Using Core Materials with Low Melting Point (저융점을 가진 Core 물질을 이용한 내구성 Microcapsule 제조 기술)

  • Noh, Kun-Ae;Gang, Eu-Gene;Kim, Sang-Hern
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.273-284
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    • 2001
  • A series of microcapsule were synthesized by using several PCM(Phase Change Material) as a core material and gelatin/arabic gum, melamine/formaldehyde as a shell material. Coacervation technique and in situ polymerization were adopted in synthesizing microcapsules. In the microencapsulation by coacervation, tetradecane and octadecane were used as core materials. In the microencapsulation by situ polymerization tetradecane, pentadecane, hexadecane, heptadecane, octadecane, and nonadecane were used as core material. The synthesized microcapsule was examined to observe the shape of the microcapsule. The particle size analysis was performed by particle size analyzer. The thermal properties(e.g. melting point, heat of melting, crystallization temperature, heat of crystallization, differences between melting point and crystallization temperature) were obtained by DSC(Differential Scanning Calorimeter). The stirring rate effect was investigated during the microencapsulation. It was found that with increasing the stirring rate much smaller microcapule was produced. However, this did not necessarily lead to formation of spherical microcapsule.

Studies on the Production of Microbial Cell Protein from Hydrocarbon (탄화수소로부터 균체단백질의 생산에 관한 연구)

  • 정동효;박준희
    • Microbiology and Biotechnology Letters
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    • v.6 no.4
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    • pp.173-179
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    • 1978
  • 1) To study the productivity of single cell protein from the n-paraffin utilizing yeast, 235 yeast strains were isolatea from 90 samples 2) Optimum cell growth temperature of three strains selected was 40~45$^{\circ}C$ and these were identified as Candida tropicalis, Candida krusei and Torulopsis molischiana. 3) A-28 strain easily assimilated tetradecane, hexadecane and octadecane, but B-8 strain and C-15 strain assimilated more hexadecane than other n-paraffins. 4) Out of the selected three strains, the mass doubling time, specific growth rate and cell yield were 3.4~4.0 hours, 0.170~0.215, 86~98%, respectively. 5) Crude protein, fat, fiber, ash and nitrogen free extract of the selected three strains were found to be 48.2~61.2% 3.7~8.0%, 3.5~4.2%, 5.6~6.7%, 23.5~31.8%, respectively, and thiamine and riboflavin contents of dried yeast cell were 0.78~0.93 mg% and 6.03~7.3 mg%, respectively. 6) Yeast protein contained evenly most of amino acid, but the sulfur-containing amino acids were particularly low.

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Monitoring of Hazardous Chemicals for Effluents of STPs and WWTP in the Nakdong River Basin (낙동강수계 주요 하·폐수처리장 방류수내 미량유해물질 모니터링)

  • Kim, Gyung-A;Seo, Chang-Dong;Lee, Sang-Won;Ryu, Dong-Choon;Kwon, Ki-Won
    • Journal of Environmental Science International
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    • v.23 no.7
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    • pp.1253-1268
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    • 2014
  • This study was investigated twenty two hazardous chemicals compounds for effluents of nine sewage treatment plants (STPs) and one waste water treatment plant (WWTP) in the Nakdong Ri-ver Basin. They are eleven phthalates(DMP, DEP, DIBP, DBP, BEEP, DNPP, DHP, DCP, DEHP, DNOP, Dinonyl phthalate, seven aliphatic hydrocarbons(n-Tridecane, n-Tetradecane, n-Pentadecan-e, n-Hexadecane, n-Heptadecane, n-Octadecane, n-Nonadecane, Isoquinoline, 2-Chloropyridine, 2-N-itrophenol, and Benzophenone. The twenty two compounds were analyzed by gas chromatograp-hy mass spectrometry (GC/MS) with liquid-liquid extraction (LLE). Twenteen of twenty two subs-tances were detected. They were DMP, DEP, DIBP, DBP, DEHP, n-Tetradecane, n-Pentadecane, n-Heptadecane, n-Octadecane, n-Nonadecane, Isoquinoline and Benzophenone. Among these, DEHP, DEP and Benzophenone were most frequently observed. They were obtained as $ND{\sim}36.881{\mu}g/L$, $ND{\sim}0.950{\mu}g/L$, $ND{\sim}2.019{\mu}g/L$, respectively. When the substances were calculated the average concentration at 10 points, the maximum average detection concentration was investigated at the Dalseocheon STP.

Thermal performance of the spherical capsule system using paraffin as the thermal storage material (파라핀 축열재를 사용한 구형캡슐 시스템의 전열성능)

  • Cho, K.N.;Choi, S.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.3
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    • pp.354-363
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    • 1997
  • The purpose of the present work is to show the best thermal storage material and the sensitivity of the parameters on the thermal performance by experimentally investigating the effects of the parameters on the thermal performance of the spherical capsule system using paraffins superior to the commercial one. The paraffins were n-Tetradecane and the mixture of n-Tetradecane 40% and n-Hexadecane 60%. The experimental parameters were the Reynolds number of 8, 12, and 16 and the inlet temperature of-7, -4, -1, and $2^{\circ}C$. The charging and the discharing time, the dimensionless thermal storage amount, and the averge heat transfer coefficient in the tank were obtained by utilizing the local temperature variation in the tank. The local charging and discharging time in the tank was axially and radially different a lot. The effects of the inlet temperature on the charging and the discharging time were larger during the charging process than during the discharging process, but the effects of the Reynolds number on the charging and the discharging time were in reverse order. The paraffins were better by 11~72% than the water with the inorganic material in the charging time aspect, but no difference in the discharging time aspect. The effects of the Reynolds number on the dimensionless thermal storage amount were smaller than the effects of the inlet temperature during the charging process, but in reverse order during the discharging process within the working range of the experimental parameters. The effects of the inlet temperature and the Reynolds number on the average heat transfer coefficient were larger during the discharging process than during the charging process. The average heat transfer coefficient for the paraffins was larger by 40% maximum than that for the commercial material during the charing and the discharging process.

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Isolation and Characterization of Oil Degrading Bacteria from Southern Sea of Korea (남해안 해수로부터 원유 분해 세균의 분리 및 특성)

  • 김학주;김봉조;공재열;구헌서
    • KSBB Journal
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    • v.15 no.1
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    • pp.27-34
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    • 2000
  • A marine bacterium having a high oil-degrading activity was isolated form the oil-polluted southern sea of Korea, and was identified as Pseudomonas aeruginosa and was named Pseudomonas aeruginosa BYK-2. The optimal tmeperatur, culture time, pH and NaCl concentration for biosurfactant production and cell growth showed $25^{\circ}C$, 48h, 7.0 and 0%(w/v), respectively. After cultivation at $25^{\circ}C$, 180 rpm in 250 mL erlenmeyer flask for 7days, 1%(w/v) arabian light crude oil and bunker C oil which are considered to be hardly degradable compounds were degraded 92.1%(w/w) and 76%(w/w) respectively. And then, cell adherence was measured on various carbon sources. The cell adherence indicated over 80% on hydrocarbons(arabian light crude oil, kuwait curde oil, bunker C oil, n-paraffine, n-hexadecane, n-tetradecane) as carbon sources. Lecithin among fatty acids(oleic acid, olive oil, lecithin) showed highest cell adherence of 91.5%. The cell adherence of sugars(arabinose, trehalose, dextrose, galactose, lactose, fructose, maltose, sorbitol, sucrose) observed to be less than 70% except for arabinose, galactose, sorbitol and sucrose.

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Physiological Characteristics of Biosurfactant-Producting Bacillus subtilis TBM 3101 (Biosurfactant를 생산하는 Bacillus subtilis TBM 3101의 생리학적 특성)

  • Kim, Seon-A;Lee, Young-Guen;Choi, Yong-Lark;Hwang, Cher-Won;Jeong, Yong-Kee;Joo, Woo-Hong
    • Applied Biological Chemistry
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    • v.50 no.1
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    • pp.12-17
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    • 2007
  • A biosurfactant-producing strain, Bacillus subtilis TBM 3101 was isolated from the soil sample at Tae-Baek Mountain through an antifungal test and emulsification assessment. The strain was assessed, regarding to the microbial growth, by physical and chemical test, surface tension, emulsification activity and stability. The surface tension of the isolate sharply decreased to the minimum 29mN/m at 48 h growth. Of note, its emulsification was stabilized to the highest degree when tributyrin was utilized as a substrate, indicating that in comparison to a variety of synthetic surfactants, the biosurfactant produced by the isolate was significantly similar to synthetic surfactant, tween 20. In addition, the biosurfactant showed high emulsification activity when soybean oil, crude oil and tetradecane were used as a substrate. Thus, these studies could contribute to the detection and development of biosurfactant beneficial to the environment and humans.