• Title/Summary/Keyword: Tetrachloroethylene

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The Effects of Polar Compounds on the Rate of Dye Exhaustion in Solvent Dyeing (용제염색에서 극상 화합물이 염착속도에 미치는 영향)

  • 이대수;안태환
    • Textile Coloration and Finishing
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    • v.2 no.1
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    • pp.21-30
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    • 1990
  • In order to obtain high dye uptake initially, polyethylene terephthalate (PET) filaments were dyed with C.I.Disperse Orange 3 and Red 1 in mixed solvents of tetrachloroethylene acidic solvent, ethyl alcohol and tetrachloroethylene basic solvent, DMF. The dyeing behavior in the mixed solvent of tetrachloroethylene and basic solvent, DMF, the initial uptake of disperse dyes increased rapidly. The shrinkage of PET increased when the solubility parameter values of PET fiber and mixed solvent approached graduately.

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A Study on Properties Changes of Vapor-Permeable Waterproofed Fabrics by Laundering and Drycleaning (투습성 방수포의 세탁방법에 따른 물성변화에 관한 연구)

  • 정경자;최석철
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.5
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    • pp.674-681
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    • 1994
  • In this study, four kinds of vapor-permeable waterproofed fabrics were selected and their properties and the changes of properties were investigated after laundering, petroleum drycleaning or tetrachloroethylene drycleaning (each 1, 5, 10 times). The results were as follows: 1) In the water resistance, only Gore Tex satisfied its minimum property requirements, $1.0kg/cm^2$ It decreased after laddering and drycleaning. Hipora-1000, Hipora-2000, Aitac decreased slightly by petroleum drycleaning and Gore Tex decreased slightly by all three methods. 2) In the moisture vapor transmission, three except Hipora-2000 satisfied its minimum property requirement, $4000g/m^2{\cdot}24hr$.24hr. After laundering and drycleaning, it increased regardless of cleaning methods. 3) In the water repellency, Hipora-lOOG, Hipora-2000 were not almost decreased after laundering and drycleaning. Aitac decreased slightly by petrolem drycleaning and Gore Tex decreased slightly by laundering and petroleum drycleaning. 4) Air permeability of Aitac increased with increasing of cleaning times regardless of cleaning methods. 5) In the bond strength, only Gore Tex dissatisfied its minimum property requirements, 250g/cm. Regardless of cleaning method, bond strength decreased with increasing of cleaning times. 6) Color difference was large in case of Hipora-1000 by laundering, Hipora-2000 by laundering and tetrachloroethylene drycleaning Aitac by tetrachloroethylene drycleaning, Gore Tex by laundering. To diminish property change of vaper-permeable waterproofed fabric, petroleum drycleaning is more effective than laundering and tetrachloroethylene drycleaning.

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In Vitro Effects of Four Drugs on Vermicidal and Laying Capacity Inhibitory Action on Eurytrema Pancreaticum of Korean Cattle (한우췌질(韓牛膵蛭)에 대(對)한 사종약물(四種藥物)이 시험관내(試驗管內)에서의 살충효력(殺蟲效力) 및 배란억제효력(排卵抑制效力)에 관(關)한 실험(實驗))

  • Yoon, Y.H.;Lee, C.E.
    • Korean Journal of Veterinary Research
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    • v.8 no.2
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    • pp.68-73
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    • 1968
  • Four drugs, bithionol, hexachlorophee, hexachloroethane and tetrachloroethylene, were tested on the in vitro effects of vermicidal and laying capacity inhibitory action to the Eurytrema Pancreaticum of Korean cattle, and the results obtained were as follows : 1) Of the four drugs, bithionol was most effective at both high and low concentrations. 2) The effects of hexachlorophene, hexachloroethane and tetrachloroethylene were less effective than that of bithionol, and the laying activity, at low concentration, was observed to increase at the early stage and decrease gradually thereafter. 3) Tetrachloroethylene was least effective of the four drugs.

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혐기성 PCE 탈염소화 미생물 농화 배양 및 미생물 군집 해석

  • 문부영;이태호;박태주
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.332-336
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    • 2004
  • An anaerobic PCE(tetrachloroethylene) dechlorinating bacterial culture from a landfill soil was enriched and characterized. The enrichment culture could dechlorinate 60$\mu$mol/$m\ell$ of PCE during a month of incubation and cis-DCE(cis-dichloroethylene) was observed as a main product of PCE dechlorination. Microbial analysis of the dechlorinating enrichment culture by rising PCR-DGGE (Polymerase chain reaction-Denaturing gradient gel electrophoresis) method showed that at least three microorganisms were related to the anaerobic PCE dechlorination.

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Determination of Organic Pollutants in Dyeing Wastewater (염색폐수 중의 유기오염물질 분석)

  • Yook, Keun-Sung
    • Analytical Science and Technology
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    • v.10 no.5
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    • pp.332-342
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    • 1997
  • Fifteen volatile organic pollutants were spiked in blank water at the concentration of $20{\mu}g/L$ and analyzed with Purge and Trap and GC/MS. As a result, the overall mean recovery of 100% was obtained with a mean relative standard deviation of 3.6%. The method detection limits were in the range of $1.9{\sim}3.3{\mu}g/L$. In the wastewater analysis of Banwol dyeing comlex, 15 organic compounds were identified and three of these were quantified. Among the compounds identified, only trichloroethylene and tetrachloroethylene are regulated in wastewater by the Korea Ministry of Environment. But, the concentration of these two compounds were below the government allowance level.

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The Identification and Anlaysis of C. bifermentans DPH, an Anaerobic Bacterium that can Dechlorinate by Reductive Dechlorination of Tetrachloroethylene or Other Halogenated Aliphatic Compounds (PCE 포함한 각종 유기염소화합물 분해능을 보유한 C. bifermentans DPH 균주의 동정 및 성질)

  • Chang, Young-Cheol;Jeong, Kweon;Yoo, Young-Sik;Kim, Min-Young;Shin, Jae-Young
    • Journal of Environmental Health Sciences
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    • v.26 no.2
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    • pp.6-13
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    • 2000
  • PCE(tetrachloroethylene) 분해능을 보유한 그람 양성, 내생포자 형성의 혐기성균이 일본 기후현의 한 전자제품공장으로부터 분리되었다. 이 균은 생화학적 특성 및 16S rRNA 분석결과에 의하여 C. bifermentans인 것을 거쳐 cDCE(cis-1,2-dichloroethylene)로 전환되었다. 전자공여체로서 효모엑기스는 PCE 분해에 있어 가장 효과적이었으며 효모엑기스를 공급한 조건에서의 PCE 탈염소화 속도는 0.41 $\mu$mol/h.mg protein 이었다. 한편 본 균주는 PCE 뿐만 아니라 각종 유기염소화합물에 대해서도 분해능을 보유하고 있는 신종의 PCE 분해균으로서 각종 유기염소화합물에 오염된 지하수 및 토양에서의 In situ bioremediation 적용에 있어 유용할 것으로 기대된다.

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Biochemical and molecular characterization of a tetrachloroethylene (PCE) dechlorinating Clostridium bifermentans DPH-1

  • Chang, Young-Cheol;Toyama, Tadashi;Kikuchi, Shintaro
    • Journal of environmental and Sanitary engineering
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    • v.23 no.2
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    • pp.1-18
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    • 2008
  • The tetrachloroethylene (PCE) dehalogenase of Clostridium bifermentans DPH-1 (a halorespiring organism) was purified, cloned, and sequenced. This enzyme is a homodimer with a molecular mass of ca. 70 kDa and exhibits dehalogenation of dichloroethylene isomers along with PCE and trichloroethylene (TCE). Broad range of substrate specificity for chlorinated aliphatic compounds (PCE, TCE, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene, 1,1-dichloroethylene, 1,2-dichloropropene, and 1,1,2-trichloroethane) for this enzyme was also observed. A mixture of propyl iodide and titanium citrate caused a light-reversible inhibition of enzymatic activity suggesting the involvement of a corrinoid cofactor. A partial sequence (81 bp) of the encoding gene for PCE dehalogenase was amplified and sequenced with degenerateprimers designed from the N-terminal sequence (27 amino acid residues). Southern analysis of C. bifermentans genomic DNA using the polymerase chain reaction product as a probe revealed restriction fragment bands. A 5.0 kb ClaI fragment, harboring the relevant gene (designated pceC) was cloned (pDEHAL5) and the complete nucleotide sequence of pceC was determined. The gene showed homology mainly with microbial membrane proteins and no homology with any known dehalogenase, suggesting a distinct PCE dehalogenase. So, C. bifermentans could play some important role in the initial breakdown of PCE and other chlorinated aliphatic compounds in sites contaminated with mixtures of halogenated substances.

Gas phase Photocatalytic Oxidation of PCE with $TiO_2$ ($TiO_2$를 이용한 PCE의 기상 광산화처리)

  • 조인철;변종환;변은숙;이동근;김성우
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.57-66
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    • 2001
  • Gas phase photocatalytic oxidation of tetrachloroethylene (PCE) under 370 nm ultra-violet irradiation was investigated with TiO$_2$ catalyst. During the photocatalytic oxidation of PCE vapor several kinds of intermediate were produced, and the reaction pathways were proposed on the basis of the production sequency of the intermediates. The intermediates in the pathways of PCE oxidation were hexachloroethane, pentachlotoethane, 1, 1, 2-trichloroethane, carbon tetrachl-oride, dichloroacetylchloride, chloroform, 1,1-dichloroethane, phosgene, CO, $CO_2$, HCl, Cl$_2$.

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Reductive Dechlorination of Tetrachloroethylene in Soils by Fe(II)-Based Degradative Solidification/Stabilization

  • Hwang, Inseong;Batchelor, Bill
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.49-52
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    • 2001
  • An experimental study was conducted to test the feasibility of degradative solidification/stabilization (DS/S) process in treating tetrachloroethylene (PCE) in solid phase systems. The Fe(II)-based ds/s process successfully treated PCE in a soil at the reaction rates that would not allow significant release of the contaminant in the environment. A leach model was also developed that could describe the relative importance of leaching and degradation in ds/s. The first and second Damkohler numbers and dimensionless time were important parameters that determined leaching precesses in wastes treated by ds/s.

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Biological Monitoring of Human Exposure to Volatile Halogenated Hydrocarbons Using Urinalysis with Capillary GC-ECD

  • Jung, Won-Tae;Sohn, Dong-Hun
    • Archives of Pharmacal Research
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    • v.15 no.2
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    • pp.109-114
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    • 1992
  • For the risk assessment of human exposure to volatile halogenated hydrocarbons, a dynamic purge trap/on-column cryofocusing method using capillary gas chromatograph-$^{63}Ni$ electron capture detector and thermal desorption unit was applied to analyze the free forms, metabolites of 1, 1, 2-trichloroethylene and 1, 1, 2, 2-tetrachloroethylene. The urine sample was diluted with distilled water, hydrolyzed and sealed. Then the inert gas was infused to purge out free 1, 1, 2-trichloroethylene, free 1, 1, 2, 2-tetrachloroethylene and urichloroethanol. These compounds were trapped to $Tenax^R$ / GC-gas trap device throughout clean up tube. Being undertectable to gas chromatograph directly, trichloroacetic acid was methyl esterificated and trapped in the manner above mentioned. The optimal incubation time to get best recovery of methyl ester was 4 hours at $60^circ$C. The concentrations of free volatile halogenated hydrocarbons and their metabolites in urine were obtained of free volatile halogenated hydrocarbons and their metabolites in urine were obtained from 5 healthy volunteers. This analytical method is expected to make the biological monitoring more precise and convenient.

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