• Polymer(Korea)
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• v.35 no.1
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• pp.40-46
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• 2011

The synthesis of well-defined poly(styrene-b-isobutylene-b-styrene) (SIBS) triblock copolymers was accomplished by cationic sequential block copolymerization of isobutylene (IB) with styrene (St) using 1,4-di(2-chloro-2-propyl) benzene (DCC) /$TiCl_4$/2,6-di-tert-butylpyridine(DtBP) as an initiating system in methyl chloride ($CH_3Cl$)/methylcyclohexane(MeChx) (50/50 v/v) solvent mixture at $-80^{\circ}C$. The triblock copolymers exhibited excellent thermoplastic and elastomeric characteristics. Tensile strengths and Shore hardness increased with increasing polystyrene (PS) content, while elongation at break decreased. The blood-compatibility of SIBS was assessed by SEM observation of the platelet adhesion, blood clotting time and haemolysis ratio. The haemolysis ratios were below 5% which met the medical materials standard. The platelet adhesion test further indicated that SIBS block copolymers had a good blood compatibility.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.22-28
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• 2015

In this study, Waterborne polyurethanes (WPU) using Epoxy group were synthesized with polyester polyol, epoxy resin, 4,4-dicyclohexylmethane diisocyanate ($H_{12}MDI$), dimethylol propionic acid (DMPA) to improve the hydrolysis resistance and adhesion. In addition, the properties of the synthesized waterborne polyurethane was evaluated through DSC, UTM, adhesion strength. Tg of the synthesized waterborne polyurethane is shown in the vicinity of $-50^{\circ}C$. Tg were increased with as epoxy resin contents increased. The tensile strength was increased as the content of epoxy resin increases, elongation was decreased. Optimum adhesion and hydrolysis-resistance strength were obtained when polyol : epoxy ratio was 99 : 1.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.05a
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• pp.350-352
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• 2009

The effect of porosity on the high-cycle fatigue properties of Al-Si-Mg casting aluminum alloys was investigated in this study. Microstructure examination, tensile and high-cycle fatigue test were conducted on both Al-Si-Mg casted (F) and heat-treated (T6) conditions. Porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The microstructure observation results showed that eutectic Si particles were homogeneously dispersed in the matrix of the Al-Si-Mg casting alloys, but there were porosities formed as cast defects. The high-cycle fatigue results indicated that the fatigue strength of the 356-T6 alloy was higher than that of the 356-F alloys because of the significant reduction in volume fraction of pores by heat treatment. The SEM fractography results showed that porosity affected detrimental effect on the fatigue life: 80% of all tested samples fractured as a result of porosity which acted as the main crack initiation site. It was found that fatigue life decreased as the size of the surface pore increased. A comparison was made between surface pore and inner pore fur its effect on the fatigue behavior. The results showed that the fatigue strength with the inner pores was higher than that of the surface pore.

• Journal of Welding and Joining
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• v.3 no.1
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• pp.22-31
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• 1985

Hot straining embrittlement is one of the most important factors which cause the brittle fracture initiation even in the service temperature in the case of mild steel and high tensile steel. Therefore it is necessary to analyze thoroughly the hot straining embrittlement occurred in weld HAZ of the structural steels. The behaviors of plastic deformation and fracture toughness at the notch tip of the hot strained weld HAZ in structural steels (SB 41 KS, SA 588-Grade A ASTM) have been studied by the recrystallization technique and crack opening displacement (COD) test method. The obtained results are summarized as follows; 1. The plastic zone is formed at the notch tip of weld HAZ owing to nomotonic and cyclic hot stran, and the maximum plastic strain increases with the accumulated hot straining amounts. 2. The distribution of the effective strain at the plastic deformed zone in HAZ can be determined as follows; (.epsilon. over bar $_{p}$ )$_{\chi}$=.epsilon. over bar $_{cr}$ ( $R_{/chi}$/.chi.)$^{m}$ where, .epsilon. over bar $_{cr}$ : (SB 41; .epsilon. over bar $_{cr}$ = 0.2, SA 588; .epsilon. over bar $_{cr}$ = 0.1) 3. The embrittlement of weld HAZ in SB 41 and SA 588 is influenced by hot strain, and the degree of embrittlement becomes deeper with hot straining amounts. 4. The embrittlement of weld HAZ of SB 41 is not influenced by the hot straining amounts until .epsilon. over bar $_{max}$ = 0.36, $R_{\chi}$ = 0.065mm, however the embrittlement of structure in SA 588 is considerably influenced even by a small quantity of the hot straining amounts.s.

• Journal of Welding and Joining
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• v.32 no.1
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• pp.15-21
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• 2014

FCAW(Flux Cored Arc Welding), SAW(Submerged Arc Welding), EGW(Electro Gas Welding), and three-pole SAW are applicable in manufacturing the offshore wind tower. In this paper, mechanical properties of these welded-joints for TMCP steels were evaluated in all above welding processes. The tensile strength of welded-joints for all the welding methods satisfied the standard guideline (KS D 3515). No cracking on weldment was found after the bending test. Changes of weldedments hardness with welding processes were observed. In a weld HAZ (heat-affected zone), a softened HAZ-zone was formed with high heat input welding processes (SAW and EGW). However, the welded-joint fractures were found in the base metal for all cases and small decrease in welded-joint strength was caused by a softened zone. The multi-pole SAW welds exhibited similar mechanical properties comparing to the one with one-pole SAW process.

• Elastomers and Composites
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• v.45 no.2
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• pp.129-136
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• 2010

In this work, PLLA/EGMA blends were prepared by melt blending of biodegradable Poly-L-lactic acid(PLLA) with Poly(ethylene-co-glycidyl methacrylate)(EGMA) and Engage as impact modifiers by twin screw extruder. Blend compositions of PLLA/Impact modifier blends were 100/0, 75/25, 50/50, 25/75 and 0/100, respectively. Also, Talc was added to 3 PLLA rich phases on PLLA/EGMA blends. The morphology, viscoelastic/mechanical properties were characterized by FESEM, DMA, UTM and Izod impact tester. DMA and Izod impact test data showed that storage modulus at room temperature with increasing EGMA and Engage contents decreased, and impact strength increased. However, storage modulus at room temperature increased by adding talc. From FESEM image, we observed that domain phase was well dispersed into matrix. Although the tensile strength and flexural modulus were decreased with increasing the content of EGMA and Engage in them, they could be supplemented by adding talc.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.6
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• pp.83-95
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• 1996

The normal cement concrete is widely used material to build the construction recently, but it has a fault to increase the dead load on account of its unit weight is large compared with strength. So, main purpose of this study was to establish the physical and mechanical properties of lightweight concrete using expanded polystyrene bead on fine aggregate and natural gravel, expanded clay and pumice stone on coarse aggregate. The test rusults of this study are summarized as follows; 1. The water-cement ratio of concrete using pumice stone was larger than that of the concrete using natural gravel and expanded clay. 2. The unit weights of concrete using pumice stone and expanded caly were shown less than 1,000g/$m^3$. 3. The compressive strengths of all types were shown less than 60kg/$cm^2$, tensile and bending strengths were shown less than l3kg/$cm^2$ and 3lkg/$cm^2$$^2$, respectively. 4. The pulse velocity of concrete was shown similar with using natural gravel and pumice stone, and shown the lowest using pumice stone. 5. The dynamic modulus of elasticity of concrete was shown considerably smaller, and shown the lowest using pumice stone. 6. The static modulus of elasticity of concrete using expanded clay and pumice stone were shown considerably smaller, and shown 22% ~29% as compared with the dynamic modulus of elasticity. 7. The stress-strain curves of concrete were shown similar, generally. And the curves were repeated at short intervals increase and decreased irregularly.

• Proceedings of the KOSOMBE Conference
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• v.1995 no.05
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• pp.27-33
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• 1995

A time-dependent large deformation fracture theory is developed for application to soft biological tissues. The theory uses the quasilinear viscoelastic theory of Fung, and particularizes it to constitutive assumptions on polyvinyl-chloride (PVC) (Part I) and cartilage (Part II). This constitutive theory is used in a general viscoelastic theory by Christensen and Naghdi and an energy balance to develop an expression for the fracture toughness of the materials. Experimental methods are developed for measuring the required constitutive parameters and fracture data for the materials. Elastic stress and reduced relaxation functions were determined using tensile and shear tests at high loading rates with rise times of 25-30 msec, and test times of 150 sec. The developed method was validated, using an engineering material, PVC to separate the error in the testing method from the inherent variation of the biological tissues. It was found that the the proposed constitutive modeling can predict the nonlinear stress-strain and the time-dependent behavior of the material. As an approximation method, a pseudo-elastic theory using the J-integral concept, assuming that the material is a time-independent large deformation elastic material, was also developed and compared with the time-dependent fracture theory. For PVC. the predicted fracture toughness is $1.2{\pm}0.41$ and $1.5{\pm}0.23\;kN/m$ for the time-dependent theory and the pseudo-elastic theory, respectively. The methods should be of value in quantifying fracture properties of soft biological tissues. In Part II, an application of the developed method to a biological soft tissue was made by using bovine humeral articular cartilage.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.6
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• pp.21-29
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• 2014

This paper deals with the bonding characteristic of grouted joint connections of monopile support structures for offshore wind power facilities. For the integration of pile connection of wind power supporting structure, fiber reinforced high performance cementeous grout was developed and the ultimate compressive strength of it is 125MPa and the direct tensile strength is 7.5 MPa at 7 days. To assess the bond strength of grout filled in pile connection, small scaled direct bond tests under axially loaded was performed and analyzed according the existing guidelines. The fiber volume fraction (0%, 0.5% and 0.9%), aspect ratio of fiber (60 and 80) and the ratio of height to spacing of shear key (0.013 and 0.056) were adopted as the experimental variables. From the test results, the maximum bond strength among the all specimens was 30.8MPa and the bond strength of grouted connection was affected by the ratio of height to spacing of shear key than the fiber volume fraction.

• Elastomers and Composites
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• v.36 no.3
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• pp.169-176
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• 2001

Ethyl-branched polyethylene[PE(2)] containing 2mole% ethyl branch and three ethylene-propylene rubbers(EPR's) haying the same ethylene(E)-propylene(P) molar ratio(E/P=50/50) with different stereoregularity, that is, random EPR(r-EPR), alternating-EPR(alt-FPR) and isotactic-alternating-EPR(iso-alt-EPR) were mixed for the investigation of their properties depending on the stereoregurarity. The three blends were immiscible at room temperature, and showed the simple additivity effect in density behavior. The melting point depression with blend composition increased in order of PE(2)/r-EPR>PE(2)/alt-EPR>PE(2)/iso-alt-EPR. In the tensile test, this blend systems have the lowest value or the breaking strength at FE(2) fraction of 0.5. This phenomenon results from the greastest separated phase morphology at this blend composition.