• Title/Summary/Keyword: Tensile Property

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A Study on Synthesis Acrylic Polymer Resin and Mechanical Properties Containing Monoammonium Phosphate (Monoammonium phosphate를 포함한 아크릴 수지의 합성 및 물성에 관한 연구)

  • Lee, Joo-Youb;Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.500-508
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    • 2014
  • For this research, synthesis acrylic resin by ethyl acrylate monomer(EAM) and prepared samples which set by difference amount of monoammonium phosphate solution in waterborne acrylic resin. Use these resins, analyzed mechanical properties and thermal stability by films and leather surface coated. The test of DSC experiment sample WAC-APS3 was $410^{\circ}C$ Tm values which means the highest content of monoammonium phosphate had highest thermal stability in acrylic resin. According to measure data for solvent resistance, all samples showed good property. As known in the results, increase of ammonium phosphate constant did not influence to big change of resin properties. In abrasion test WAC-APS3 was good abrasion properties(68.729 mg.loss). Test of tensile strength, as increase as monoammonium phosphate resin analyzed low properties $1.505kgf/mm^2$ to $1.275kgf/mm^2$. In elongation case, same as strength test result 425 % to 384 % by increase to monoammonium phosphate amount in acrylic resin.

A Study on the Commercialization of Polyamide 66/Polypropylene Blend (폴리아마이드 66/폴리프로필렌 블렌드의 상업화 연구)

  • Kim, Seog-Jun;Nam, Byeong-Uk
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.262-272
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    • 2003
  • Maleic anhydride-grafted-polypropylene(PP-g-MA) were used as a blend component and a compatibilizer, respectively, for two reactive blends of polyamide 66(PA 66)PP-g-MA binary blends and PA 66/polypropylene(PP)/PP-g-MA ternary blends. The goal of this work was to investigate the property differences between binary and ternary blends. Tensile strength, flexural modulus, heat deflection temperature, impact strength, melt flow index, and the dependence of melt viscosity on the shear rate were examined. The impact strengths of binary blends were higher than those of ternary blends at all compositions, since the in situ synthesis of PP-g-PA 66 copolymer through the imide formation between the amine end group of PA 66 and the anhydride group of PP-g-MA gave the increase of molecular weight and was more popular in binary blends than in ternary blends. In case of ternary blends, most of the properties were superior to those of binary blends, owing to the better properties of PP compared with PP-g-MA. The toughened binary blends with 70/30(PA 66/PP-g-MA) and 80/20 ratios were not commercially applicable due to their poor processibility. So, the ternary blends which showed lower melt viscosities were recommended for the commercial applications.

A Study on the Non-combustible Properties of High-density Fiber Cement Composites Mixed with Hemp Fibers (마 섬유 혼입에 따른 고밀도 섬유 시멘트 복합체의 불연 특성 연구)

  • Jang, Kyong-Pil;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.314-320
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    • 2022
  • The function of reinforcing fibers used in building materials is to maintain resistance to bending loads and to function for cracking caused by drying shrinkage. High-density fiber-cement composites are mainly used for linear plates and are used to increase bending resistance. Therefore, tensile properties, bonding strength with cement hydrate, alkali resistance, and the like are required. Recently, as the non-combustible performance has been strengthened, a function to minimize the occurrence of sparks during high-temperature heating has been added. Therefore, the use of organic fibers is limited. In this study, a study was conducted to replace polypropylene used as reinforcing fiber with hemp fiber with excellent heat resistance. Hemp fibers have excellent heat resistance, good affinity with cement, and excellent alkali resistance. Based on the total volume of polypropylene fibers used in the existing formulation, the non-combustible performance was compared and evaluated by using hemp fibers instead of the polypropylene fibers, and basic physical properties such as flexural strength were tested. As a result of conducting a non-combustibility and physical property test using hemp fibers with a fiber length of 7 mm using 2 % and 3 % by weight, it was found that there is no remaining time of the flame, and the flexural strength can be secured at 95 % level of the existing polypropylene fiber.

A Study on Evaluation of Rock Brittleness Index using Punch Penetration Test (압입시험을 이용한 암석의 취성도 평가에 관한 연구)

  • Hoyoung Jeong
    • Tunnel and Underground Space
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    • v.33 no.1
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    • pp.29-41
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    • 2023
  • The brittleness of rocks plays an important role in determining the fragmentation and failure behavior of rock. However, there is still no standard method to evaluate the brittleness of rock, and previous studies have suggested the several definitions for estimation of brittleness of rock. Even in the process of mechanical rock excavation and drilling, the brittleness of rock is considered as an important property for evaluating the excavation efficiency of mechanical excavators or boreability of rock. The previous studies have been carried out to investigate the correlation between different brittleness of rock and cutting efficiency and boreability of rock. This study introduced a method for calculating the brittleness of rock from punch penetration test, and analyzed the correlation between the brittleness of rock calculated by the uniaxial compressive and Brazilian tensile strengths and that from punch penetration test. From the results of correlation analysis, the relationship between various brittleness was confirmed, and it was found that PSI and BI3 showed a good correlation with the strength-based brittleness index. In addition, the results indicated that B3 and B4 are suitable to represent the brittleness of rock in the field of mechanical rock excavation.

Preparation and Properties of EPDM/Thermoplastic Polyurethane Scrap Blends (EPDM/열가소성 폴리우레탄 스크랩 블렌드의 제조 및 물성)

  • Lee, Young-Hee;Kang, Bo-Kyung;Yoo, Hye-Jin;Kim, Jung-Soo;Jung, Young-Jin;Lee, Dong-Jin;Kim, Han-Do
    • Clean Technology
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    • v.15 no.3
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    • pp.172-179
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    • 2009
  • The thermoplastic polyurethane waste (TPU-S) with good tensile properties, hardness, NBS abrasion resistance, specific gravity and low wet coefficient of kinetic friction was melt-blended with ethylene propylene diene monomer rubber (EPDM) with high wet slip resistance and low mechanical properties to form EPDM/TPU-S blend films, and their composition-property relationship was investigated to find the optimum composition for shoe outsole material. The properties except the wet slip resistance increased with increasing TPU-S contents in the blend. All the properties except elongation at break, specific gravity and the wet coefficient of kinetic friction in the range of $0{\sim}65\;wt%$ of TPU-S did not attain the values predicted by the simple additive rule. The optimum weight ratio of EPDM/TPU-S for the application to the typical shoe outsole material was found to be 30/70.

Rock Mass Stability of the Buddha Statue on a Rock Cliff using Fracture Characteristics and Geological Face-Mapping (마애불 암반의 단열특성과 지질맵핑을 이용한 안정성 해석)

  • Ihm, Myeong Hyeok
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.1
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    • pp.539-544
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    • 2023
  • The subject of this study is the Maae Buddha statue in granodiorite of the Mesozoic Cretaceous period, which is concerned about stability as a standing stone cultural property located in ◯◯-dong, Gyeongsangbuk-do. For stability analysis, three-dimensional face mapping, geological properties of joints, three-dimensional scanning, ultrasonic velocity, polarization microscopy, electron microscopy analysis and XRD analysis were performed. In addition, the safety factor of the Maaebul was calculated by analyzing the damage status investigation, stereographic projection analysis, rock classification, and limit equilibrium analysis. The types and scales of damage and possible collapse by section depend on the degree of weathering of the rock and the orientation and characteristics of the joints, but wedge-failure and toppling-failure are expected to be small-scale. The safety factor of Maaebul in dry and wet conditions is less than 1.2, so stability is concerned. The types of damage were mainly observed, such as exfoliation, cracking, granular decomposition, and vegetation growth. The Maaebul rock is granodiorite, and the surface discoloration materials are K, Fe, and Mg. The 4 sets of joints are developed, J1 is tensile joint and the others are shear joint. The uniaxial compressive strength estimated by ultrasonic exploration is 514kgf/cm2, which corresponds to most soft rocks and some weathered rocks. Rock classification(RMR) is estimated to be grade 5, very poor rock mass. These technique along with the existing methods of safety diagnosis of cultural properties are expected to be a reasonable tool for objective interpretation and stability review of stone cultural properties.

Relations between Physical Parameters and Improvement of Mechanical Properties in Jute Fiber Green Composites by Maleic Anhydride Coupler (Jute fiber Green Composite의 커플링제에 의한 물리적 인자의 변화와 기계적 특성 향상)

  • Lee, Jung-H.;Byun, Joon-H.;Kim, Byung-S.;Park, Joung-M.;Hwang, Byung-S.
    • Composites Research
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    • v.20 no.1
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    • pp.23-31
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    • 2007
  • In order to improve the mechanical properties of jute fiber/polypropylene(PP) composites, the property change with the addition of a coupling agent, maleic anhydride polypropylene(MAPP) was examined experimentally. The maleated coupler acts as an intermediate to chemically connect the polar nature of the fiber and non-polar nature of the polyolefin polymer resin. Furthermore, the decrease in viscosity of the resin which results from the melting point reduction by the MAPP, leads to an increase of contact area with the fiber interface. We discussed the improvement of the PP composite blend of the maleated coupler with the 80mm jute long fiber mat in conjunction with the change of physical parameters in the thermoplastic resin. We confirmed the extent of contribution to the mechanical physical enhancement by using the following parameters: melting flow index(MI) and viscosity, contact angle, thickness of the composite, interfacial shear strength and morphology observation etc. Especially it was observed that the MI and viscosity, MAPP mixture had a very strong relationship with the tensile and flexural strength and modulus, and interfacial shear strength(IFSS).

A Study on the Physical Properties of a Compound Using the Crosslinking of Vinylized-mesoporous Silica and Regenerated Polyethylene (비닐화 실란이 도입된 메조포러스 실리카와 재생 폴리에틸렌의 가교결합을 이용한 컴파운드의 물성 연구)

  • Tae-Yoon Kim;Hyun-Ho Park;Chang-Seop Lee
    • Journal of the Korean Chemical Society
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    • v.67 no.6
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    • pp.420-428
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    • 2023
  • Crosslinking was introduced into vinylized-mesoporous silica and recycled polyethylene. By introducing a vinyl group into the mesoporous silica, it becomes a material capable of inducing cross-linking with non-polar polyethylene. By synthesizing vinylized-mesoporous silica and inducing crosslinking with recycled polyethylene, a recycled polyethylene composite with improved physical properties than existing recycled polyethylene was synthesized. In addition, even when a small amount is added according to the grade of recycled polyethylene using vinylized-mesoporous silica, the crosslinking reaction proceeds and all physical properties are improved. Four types of vinylized-mesoporous silica were synthesized, and the shape, microstructure, and functional groups were analyzed by TEM, BET, FT-IR, and XRD. Using vinylized-mesoporous silica, three types of compounds were blended by crosslinking reaction with recycled polyethylene. In order to confirm the presence or absence of crosslinking, analysis was performed using XPS and FT-IR, and physical properties such as tensile strength, elongation, flexural strength, and flexural modulus were confirmed using a universal testing machine. As a result, by applying vinylized-mesoporous silica to recycled polyethylene in various grades, the weak physical properties of existing recycled polyethylene were overcome. By applying the vinylized-mesoporous silica, recycled polyethylene composite material that overcomes the weak physical properties to the normal polyethylene, it shows the optimal physical property index that can be used commercially. Therefore, it is expected that it can potentially increase the use of recycled polyethylene and recycle resources.

The Physical and Thermal Properties Analysis of the VOC Free Composites Comprised of Epoxy Resin, and Dicyandiamide (VOC Free Epoxy Resin/Dicyandiamide 경화물의 배합비 변화에 따른 물리적 특성 및 열적특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young IL;Kim, Young Chul;Lim, Choong-Sun
    • Clean Technology
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    • v.21 no.1
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    • pp.76-82
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    • 2015
  • Volatile organic compounds (VOC) free adhesives have been interested by many scientists and engineers due to environmental regulations and the safety of industrial workers. In this work, a series of composites composed with bisphenol A epoxy resin used as solvent, dicyandiamide, and promoter were prepared to investigate the most appropriate molar ratio for steel-steel adhesion. The cured test specimen of each composite were measured with universal testing machine (UTM) to figure out mechanical properties such as tensile strength, Young’s modulus, and elongation. Furthermore, the lap shear strength of the specimen was tested with UTM while impact resistance was measured with Izod impact tester. The composite whose molar ratio of epoxy resin to curing agent is 1 : 0.9 (sample 3), showed better tensile strength, coefficient of elastic modulus, elongation, and impact strength than other composites did. The highest tanδ from dynamic mechanical analysis (DMA) was observed from sample 2 (epoxy resin: dicy = 1 : 0.7) while sample 3 showed slightly lower tanδ than that of 2. The morphology of the fracture surface of the cured composites from SEM showed that the number of subtle lines on the surface caused by impact increase as the contents of amine curing agent accrete. Furthermore, the viscosity change of sample 5 (epoxy resin: dicy = 1 : 1.3) was observed to confirm its storage stability.

A New Attempt to Establish the Extrinsic Aging Hair Model to Evaluate The Response to Aging in Physical Property (모발 노화에 따른 물성변화와 외인성 노화모델의 개발)

  • Song, Sang-Hun;Choi, Wonkyung;Park, Hyunsub;Lim, Byung Tack;Park, Kyoung Ran;Kim, Younghyun;Park, Sujin;Son, Seong Kil;Lee, Sang-Min;Kang, Nae-Gyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.2
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    • pp.185-198
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    • 2019
  • Human tissue undergoes aging by the oxidant damage via structural change and its physical properties. The skin aging process is well known and many evaluations have been conducted. However, studies on hair aging were relatively few and thus care for aging hair is difficult. This study aims to fabricate an aging hair and identify anti-aging effect with known ingredient in anti-aging. First of all, physical properties of aging hair of age 60s by physiologically intrinsic factors were compared to those of the hair made by various extrinsic factors such as several chemical reactions and iteration numbers of the treatments. The extrinsic aging hair of this study relates to the less amount of lipid and to the hair of perm treated once accordingly, wherein several physical properties, preferably comprise roughness and tensile strength, present a novel concept of the intrinsic aging hair. The penetration of peptide into the aging hair was leading the extrinsic hair towards more structurally directed a younger hair. In addition to the structural change, the penetration of the peptide enhanced texture and tensile strength of the aging hair. These patterns have been also found in addition of propolis. For the first time, these qualitative studies exhibit that indeed our extrinsic aging hair well describes the anti-aging efficacy as a receptor for a cross-linker and the ingredients of human hair.