• Journal of Environmental Science International
• /
• v.22 no.11
• /
• pp.1415-1419
• /
• 2013

This study was conducted to investigate the seasonal variation characteristics of phytoncide in trail of Ulsan Metropolitan. Air samples were collected from May to December 2011. They were collected using Tenax Ta tube and phytoncides were detected and quantified using a Gas Chromatograph Mass Spectrometer (GC/MSD). This study are summarized as follows; The seasonal concentrations of phytoncide are Munsu Mt. 272.3 ${\mu}g/m^3$, Samho Mt. 192.4 ${\mu}g/m^3$, Shinbul Mt. 50.9 ${\mu}g/m^3$, Sibli Bamboo forest 22.4 ${\mu}g/m^3$ and Joongbu Fire Station 24.4 ${\mu}g/m^3$. In Munsu Mt., Samho Mt. and Shinbul Mt. major component ratio is ${\alpha}$-Pinene > ${\beta}$-Pinene+Myrcene >Limonene >Camphene > ${\gamma}$-Terpinene > ${\alpha}$-Terpinene. Bamboo forest and Joongbu fire station major component ratio is ${\alpha}$-Pinene >Limonene > ${\beta}$-Pinene+Myrcene >Camphene > ${\alpha}$-Terpinene. The variation of seasonal concentration is summer >spring >fall >winter. The phytoncide concentration of coniferous forest(Munsu Mt., Samho Mt.) is higher than broadleaf forest(Shinbul Mt.).

• Journal of Soil and Groundwater Environment
• /
• v.24 no.6
• /
• pp.16-25
• /
• 2019

Anthropogenic polycyclic aromatic hydrocarbons (PAHs) are formed by the incomplete combustion of fuels and industrial waste. PAHs can be widely exposed to the environment (water, soil and groundwater). PAHs are potentially toxic, mutagenic and/or carcinogenic. Fundamental studies such as biota uptake (e.g., earthworm and plant) of PAHs are highly needed. It is necessary to develop alternative ways to evaluate bioavailability of PAHs instead of using living organisms because it is time-consuming, difficult to apply in the field, and also exaction method is tedious and time-consuming. In this study, sorption behaviors of phenanthrene were evaluated to predict the fate of PAHs in soils. Moreover, bioaccumulation of PAHs in an artificially contaminated soil was evaluated using pea plant (Pisum sativum) as a bioindicator. A novel passive sampler, organic-diffusive gradient in thin-film (o-DGT) for PAHs was newly synthesized, tested as a biomimic surrogate and compared with plant accumulation. Sorption partitioning coefficient (K_P) and sorption capacity (K_F) were in the order of natural soil > loess corresponding to the increase in organic carbon content (f_oc). Biota-to-soil accumulation factor (BSAF) and DGT-to-soil accumulation factor (DSAF) were evaluated. o-DGT uptake was linearly correlated with pea plant uptake of phenanthrene in contaminated soil (R²=0.863). The Tenax TA based o-DGT as a biomimic surrogate can be used for the prediction of pea plant uptake of phenanthrene in contaminated soil.

• Journal of Environmental Health Sciences
• /
• v.44 no.3
• /
• pp.205-216
• /
• 2018

Objectives: Scientific verification for health effects has been constantly demanded through the forest healing factors. In this study, phytoncide concentration which is one of the forest healing factors, was investigated according to stand density, season and visiting time, and analyzed correlation with micrometeorology factors. Methods: Total volatile organic compounds (TVOCs) and Natural volatile organic compounds (NVOCs) were collected using a measuring instrument which is connected to an air pump with the Tenax TA tube. The 32NVOCs were selected through the detailed criteria of adequacy assessment for recreational forest. The statistical analysis (correlation and stepwise regression analysis) was conducted between phytoncide concentration and micrometeorology factors. Results: NVOCs concentration linearly increased according to stand density. The high level showed in the summer (p<0.05), and there is no significant difference according to visiting hours of the Healing forest. NVOCs is a negative correlation with solar radiation, PAR and wind direction, and a positive correlation with relative humidity and temperature (p<0.01). NVOCs increased following the increase of humidity and temperature ($R^2=0.55$). Conclusions: Phytoncide linearly increased according to stand density, and showed the correlation significantly with microclimate factors. In future, these results will be utilized as a basic material to promote the generation of phytoncide, which positively influences human health promotion and manage the forest welfare space.

• Journal of Environmental Science International
• /
• v.22 no.1
• /
• pp.91-98
• /
• 2013

In order to study the seasonal patterns and possible origins of air concentrations of volatile organic compounds(VOC), measurements were taken with GC-MS at 3 sampling sites in Jinju for 12 months from Mar. 2010 to Feb. 2011. Atmospheric VOC are sampled on tubes containing solid adsorbents(Tenax TA) with a time resolution of 2hrs. Composition and concentration of VOC are analysed with a GC system equipped with thermal desorption apparatus(ATD). The most abundant compound appeared to be Toluene, Ethylbenzene and m,p-Xylene. The mean concentrations of Benzene were 0.20 ppb at GN site, 0.18 ppb at DA site, and 0.25 ppb at SP site, respectively. VOC concentration showed a strong seasonal variation, with higher concentrations during the spring and lower concentrations during the summer. The results showed that monthly fluctuations in measured VOC concentrations depended on variations in the strength of sources, as well as on photochemical activity and meteorological conditions. In Jinju, the total VOC emissions for 2009 were estimated to be 4,407 ton/year by Clean Air Policy Support System(CAPSS). It is shown that solvent use 57.5%(2,534 ton/yr), waste treatment and disposal 23.3%(1,025 ton/yr), and mobil source-road traffic 12.2%(537 ton/yr) are the most significant anthropogenic source.

• Environmental Engineering Research
• /
• v.18 no.3
• /
• pp.169-176
• /
• 2013

The present study was designed to examine the concentrations, emission rates, and source characteristics of a variety of volatile organic compounds (VOCs) in 30 newly-constructed apartment buildings by measuring indoor and outdoor VOC concentrations over a 2-year period. For comparison, seven villa-type houses were also surveyed for indoor and outdoor VOC concentrations over a 3-month period. Indoor and outdoor air samples were collected on Tenax-TA adsorbent and analyzed using a gas chromatograph (GC)/mass spectrometer system or a GC/flame ionization detector system coupled to a thermal desorption system. The long-term change in indoor VOC concentrations depended on the type of VOCs. Generally, aromatic (except for naphthalene), aliphatic, and terpene compounds exhibited a gradual deceasing trend over the 2-year follow-up period. However, the indoor concentrations of the six halogenated VOCs did not significantly vary with time changes. Similar to these halogenated VOCs, the indoor naphthalene concentrations did not vary significantly with time changes over the 2-year period. Unlike the halogenated VOCs, the indoor naphthalene concentrations were much higher than the outdoor concentrations. The indoor concentrations of aliphatic and aromatic compounds were higher for the villa-type houses when compared to those of apartment buildings. In addition, four source groups (floor coverings and interior painting, household products, wood paneling and furniture, moth repellents) and three source groups (floor coverings and interior painting, household products, and moth repellents) were considered as potential VOC sources inside apartment buildings for the first- and second-year post-occupancy stages, respectively.

• Journal of Korean Society for Atmospheric Environment
• /
• v.25 no.1
• /
• pp.38-45
• /
• 2009

Since the seventies and the oil crisis, energy-saving measures have led to a reduction in the ventilation of room. The use of synthetic materials which emit various chemical substances had led to an increase in the concentration of indoor pollutants. "Sick building syndrome (SBS)" and "Sick house syndrome (SHS)" are worldwide problems. Also, the number of complaints about indoor air pollution caused by VOCs (Volatile organic compound) and HCHO (Formaldehyde) has increased. It is important that evaluating and understanding emission of indoor air pollutant from building materials. The object of this study was to evaluate emission test method for flooring such as wood based flooring, carpet tile, rubber tile, PVC sheet and tile, and to determine emission of TVOC and form-aldehyde. The quantity of TVOC and carbonyl compounds emission were sampled and measured by Tenax TA and gas chromatography/mass spectrometry (GC/MSD), 2,4-DNPH cartrige with ozone scrubber and high performance liquid from flooring. The TVOC concentration emitted from carpet tile was ($7.419\;mg/m^2 h$) the highest among 5 groups of test materials. In wood based flooring and PVC tile, the emitted concentration of toluene was high. And the dodecane emission was highest in carpet. The concentration of TVOC decreased by an increase in emission test period. After 7 days, the concentration of TVOC from floorings were about 50% below of the concentration at the first day. TVOC emission from wood based flooring, carpet tile, rubber tile, PVC sheet and tile were decreased in 28 days and remained steady after about 15 days. The concentration of formaldehyde emission from floorings showed extremely low.

• Journal of Environmental Health Sciences
• /
• v.44 no.4
• /
• pp.330-339
• /
• 2018

Objectives: The occurrence characteristics of BTEXS and phytoncides were investigated by type of urban forest. Methods: Four types of urban green space (Hongneung Forest, Mt. Chunjang, residential park, and traffic island) and Gwangneung Forest were selected. Monitoring of phytoncides and BTEXS was conducted considering the activity times of urban residents (five times per day) using a Tenax TA tube and suction pump in June 2017 (one day). Results: Phytoncide concentrations were ranked as Gwangneung Forest>Hongneung Forest>Mt. Cheonjang>traffic island>residential park. Relatively high concentrations of phytoncides were also identified in the urban forest. There was no significant difference between Gwangneung Forest and the urban forest. BTEXS concentrations were ranked as traffic island>residential park>Hongneung Forest>Gwangneung Forest>Mt. Cheonjang. Traffic island and residential park showed high levels of BTEXS depending on the inflow of vehicles. The difference in concentration by time was significant for the traffic island in particular. Pollutant levels in Hongneung Forest were as low as in Gwangneung Forest. Conclusion: The concentrations of phytoncides and BTEXS were different by types of urban green space, and the potential for health and hygiene of urban forests were able to be investigated. This study is expected to provide as basic data for the creation of urban forest spaces in the future.

• Journal of Environmental Health Sciences
• /
• v.43 no.2
• /
• pp.95-102
• /
• 2017

Objectives: This study was conducted to evaluate the emission of VOCs from clothing that had been dry cleaned. Methods: In order to ensure the same conditions, f100% wool scarves were selected as the fabric type. Four identical tests were conducted on the option of either removing the plastic bags which came from the dry cleaning shop or not. The scarf was located inside a closet or room for one or two days. Small chamber tests were conducted to determine the VOC emission characteristics under the same conditions such as temperature, humidity, loading factor, and air exchange rates. Air from the chamber for VOCs was sampled by Tenax TA tube and analyzed by thermal desorption and GC/MSD. Results: Assuming that test represented dry cleaning and consumer's conditions well enough, we can conclude that immediate emissions after the dry cleaning of the scarfs caused elevated levels of TVOC, five VOCs (benzene, toluene, ethylbenzene, xylene, stylene), and decane group compounds. Conclusions: By removing the plastic bags which came from the dry cleaning shop or not, the storage conditions of dry cleaned scarfs by consumers during the storage time periods (one to three days) would be significant for reducing VOC emissions.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.6
• /
• pp.616-623
• /
• 2010

Recently, interests in indoor air quality (IAQ) have been increased; however, a number of researchers have mainly focused on anthropogenic volatile organic compounds (AVOC) emitted from building materials. Therefore, the properties of natural VOC (NVOC) and anthropogenic VOC (AVOC) emitted from wood-based panels was investigated in this work. VOCs emitted from these panels were sampled through Tenax TA/Cabotrap and analyzed by GC-MS and GC-FID. Comparisons were made concerning TVOC, NVOC, and composition ratios of NVOC. It was revealed that TVOC emission rates of midium density fiber (MDF) were the highest. Besides, it was found that emissions of NVOC from wood-based panels were much higher than those of anthropogenic AVOC except for plywood of Oceania timber. It was also observed that the composition ratio of NVOC emitted from plywood of Pinus radiata was the highest as 65% of TVOC. Major NVOC components were monoterpene compounds such as $\alpha$-pinene, $\beta$-pinene, d-limonene, camphene and $\alpha$-terpinene. It was concluded that the composition rates of VOCs emitted from building materials were clearly different according to the raw materials and manufacturing methods.

• Analytical Science and Technology
• /
• v.26 no.3
• /
• pp.165-173
• /
• 2013

To establishment of PT Program for Indoor air quality field that manufacture of confidential development PTMs (proficiency testing materials) and examined of proficiency testing evaluation included sampling process whether or not that is valid. Confirmation of homogeneity and stability of PTMs prepared. PTMs were confirmed to be homogeneous enough to be used as proficiency testing materials since withinbottle homogeneities of the RMs were lower than 0.3 times of targeted standard deviation of proficiency testing. The result of this study showed that the Robust RSD of proficiency testing for VOCs (volatile organic compounds) appeared 23~43% in concentration of 50~320 ${\mu}g/m^3$ for Method A(Distribution by adsorption in Tenax-tube of VOCs), but less 13~42% in concentration of 200~1200 ${\mu}g/m^3$, 16~31% in concentration of 100~450 ${\mu}g/m^3$ for Method B (distribution by VOCs of gas phase in 10L Tedalr bag), C (directly sampling of cylinder with high pressure) respectively. The result of this study showed that method C with sampling is most adequate to the proficiency testing for VOCs in indoor air.