• Title/Summary/Keyword: Temporarily solubilized disperse dyes

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Dispersant-free Dyeing of Polyester with Temporarily Solubilized Azo Disperse Dyes from Indole Derivatives

  • Lee, Jung-Jin;Lee, Won-Jae;Kim, Jae-Pil
    • Fibers and Polymers
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    • v.4 no.2
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    • pp.66-70
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    • 2003
  • Temporarily solubilized azo disperse dyes based on 1,2-substituted indoles were synthesized and characterized. Dispersant-free dyeing of polyester by using the synthesized dyes has been investigated. The colour yields of the dyes on the polyester fabric were found to be highly dependent on the dyeing pH, optimum results being obtained at pH 5. The dyes exhibited good to excellent fastness properties on polyester while lightfastness was moderate.

Dispersant-free dyeing of acetate with temporarily solubilized azo disperse dyes

  • Lee, Jung-Jin
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.15-21
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    • 2006
  • Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsufonyl group were applied to acetate fabric and the feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on acetate fabric were found to be dependent on dye bath pH as well as dyeing temperature. The optimum results were obtained at pH 6 and $80^{\circ}C$. The dyes showed good exhaustion and levelling properties. Vinylsulfone derivatives of the dyes were prepared and applied to acetate with dispersant. Dyeing properties of the temporarily solubilized disperse dyes were similar to or better than those of the vinylsulfone dyes. The dyes showed moderate to good fastness properties on acetate.

Dyeing of meta-Aramid Fabric with Temporarily Solubilized Reactive Disperse Dyes (일시적 수용성 반응성 분산염료를 이용한 메타 아라미드 섬유의 염색성 연구)

  • Lee, Yeon Ju;Lee, Jung Jin
    • Textile Coloration and Finishing
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    • v.25 no.4
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    • pp.262-270
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    • 2013
  • Temporarily solubilized reactive disperse dyes containing ${\beta}$-sulfatoethylsulfonyl group were applied to 100% meta-aramid knitted fabric and their dyeing properties were investigated. Reactive disperse dyes showed relatively high K/S values on meta-aramid fabric when compared with conventional disperse dye or reactive dye, which showed very low K/S values. Color yields of reactive disperse dyes were highly dependent on dyeing pH and optimum results were obtained at pH 6. Percent exhaustion of reactive disperse dye on meta-aramid fabric was over 80% at 2% o.w.f of dye concentration. Wash fastness of pyridone-based reactive disperse dyes was very good to excellent while that of aminoazobenzene reactive disperse dyes was medium to good. Light fastness of all the reactive disperse dyes was very poor which seems to be due to the low photostability of meta-aramid fiber itself.

Synthesis of Temporarily Solubilized Reactive Disperse Dyes and Their Application to the Polyester/Cotton Blend Fabric

  • Lee, Jung-Jin;Han, Nam-Keun;Lee, Won-Jae;Park, Jae-Hong;Kim, Jae-Pil
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.85-90
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    • 2002
  • Five temporarily solubilized reactive disperse dyes were synthesized and characterized. They were applied to polyester/cotton blend fabric using one-bath dyeing method without dispersing agent. The dye that has azonaphthalene chro-mophore seemed to not only be exhausted on polyester but also react with cotton. But other dyes were selectively dyed on polyester and showed limited uptake on cotton. Good levelling as well as moderate to good colour fastness was obtained with the dyes on P/C blend fabric.

One-bath Dyeing of Acetate/nylon Blend Fabric with Temporarily Solubilized Reactive Disperse Dyes (일시적 수용성 반응성 분산염료를 이용한 아세테이트/나일론 혼방직물의 일욕염색)

  • 이정진;김정훈;윤양수;김재필
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.202-205
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    • 2003
  • $\beta$-Sulfatoethylsulfone기를 갖는 일시적 수용성 반응성 분산염료는 분산제를 첨가하지 않고도 염욕내에서 단분자 상태를 유지할 수 있으며 염색 공정 중 온도와 pH조건의 변화에 따라 Scheme 1과 같이 비수용성 vinylsulfone form으로 변환된다[1]. 이 때 vinylsulfone기는 섬유와 화학결합을 할 수 있는 대표적인 반응기이므로 이 염료는 일시적 수용성 분사염료와 반응성 염료의 두 성질을 동시에 지닌다[2]. (중략)

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