• 제목/요약/키워드: Temperature transition

검색결과 2,897건 처리시간 0.03초

Effect of phenothiazine derivatives on the thermotropic phase transition of liposomal phospholipid membrane

  • Han, Suk-Kyu;Kim, Nam-Hong;Lee, Yong-Soo
    • Archives of Pharmacal Research
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    • 제9권2호
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    • pp.75-79
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    • 1986
  • The effect of phenothiazine derivatives on the thermotropic transition of liposomal lipid bilayer made of dipalmitoyl phosphatidylchline and dipalmitoyl phosphatidic acid was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayer incorporated with levomepromazine, chlopromazine, prochloperazine, perphenazine and fluphenazine were obtained and the size of cooperative unit of the transition were calculated from the ratio of the van't Hoff enthalpy change to the calculated enthalpy change of the transition. The results showed that incorporation of phenothiazine derivatives into the liposomal bilayer reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. Phenothiazine derivatives also significantly reduced the size of cooperative unit of the transition. The effect of the drugs was proportional to the concentration of the drug in the bilayer. This means that phenothiazine derivatives might have significant fluidizing effects on the biomembrane. The sizes of cooperative unit were successfully corrlated with phar-macological activities of the drugs and the surface pressure increases of lipid monolayer by these drugs. These correlations might be ascribed to a possible hydrophobic nature of interaction between the biomembrane and the drugs involved in their pharmacology.

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추이대(推移帶)를 중심으로 한 경상북도 3개 도시의 열섬 평가 (Evaluation of the heat island in transition zone of three cities in Kyungpook, Korea)

  • 박인환;장갑수;김종용
    • 환경영향평가
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    • 제8권2호
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    • pp.73-82
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    • 1999
  • This study analyzed the relationship between NDVI(Normalized Difference Vegetation Index) and urban heat island in three cities: Daegu, Kyungju, and Pohang for understanding the degree of nature conservation concentrating in the transition zone of them. Daegu city is the third city in Korea which has a dense population. Kyungju is a traditional city which has good nature. Pohang is an industrial city which has those of characters of Daegu and Kyungju. Landsat 1M data in May 17, 1997 were used for the analysis of heat island. There were about four theoretical models to estimate the surface temperature from TM data: Two-point linear model, Linear regression model, Quadratic regression model, and Cubic regression model. In this study, Linear regression model had been utilized to analyze the urban heat island. On the resultant images, the transition zone of Daegu was urbanized more extremely than those of other two cities. It is thought that the analysis of relationship between NDVI and surface temperature, used in this study, is regarded as one of effective methodologies for urban-environmental detection from satellite imageries.

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Consideration of NDVI and Surface Temperature Calculation from Satellite Imagery in Urban Areas: A Case Study for Gumi, Korea

  • Bhang, Kon Joon;Lee, Jin-Duk
    • 한국측량학회지
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    • 제35권1호
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    • pp.23-30
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    • 2017
  • NDVI (Normalized Difference Vegetation Index) plays an important role in surface land cover classification and LST (Land Surface Temperature Extraction). Its characteristics do not full carry the information of the surface cover typically in urban areas even though it is widely used in analyses in urban areas as well as in vegetation. However, abnormal NDVI values are frequently found in urban areas. We, therefore, examined NDVI values on whether NDVI is appropriate for LST and whether there are considerations in NDVI analysis typically in urban areas because NDVI is strongly related to the surface emissivity calculation. For the study, we observed the influence of the surface settings (i.e., geometric shape and color) on NDVI values in urban area and transition features between three land cover types, vegetation, urban materials, and water. Interestingly, there were many abnormal NDVI values systematically derived by the surface settings and they might influence on NDVI and eventually LST. Also, there were distinguishable transitions based on the mixture of three surface materials. A transition scenario was described that there are three transition types of mixture (urban material-vegetation, urban material-water, and vegetation-water) based on the relationship of NDVI and LST even though they are widely distributed.

합금응고시 주상정으로부터 등축정 수지상으로의 천이에 관한 해석 (The analysis of columnar to equiaxed dendritic transition during alloy solidification)

  • 김신우
    • 한국결정성장학회지
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    • 제8권1호
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    • pp.187-192
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    • 1998
  • 일반적으로 재료의 응고조직은 주상정과 등축정 수지상 영역으로 이루어지는데 이것은 제품의 기계적, 물리적 성질과 밀접한 관계를 가지기 때문에 주상정-등축정 천이에 관한 많은 이론적 연구가 행하여지고 있다. 본 연구에서는 J.D. Hunt에 의하여 일방향응고시 주상정앞에서의 핵생성과 결정성장조건을 이용하여 구하여진 해석학적 주상정-등축정 조건식을 바탕으로 응고속도에 따라 변하는 분배계수와 액상선기울기를 적용하여 수정된 조건식을 구하였다. 그리고 Al-Cu합금에 대하여 응고변수인 핵생성수, 핵생성온도, 합금의 조성, 응고속도 온도기울기에 따른 천이현상의 변화를 조사하였다.

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납이 포함되지 않은 압전 특성의 (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x 상전이 거동 연구 (Phase Transition Behaviors of Lead-Free Piezoelectric (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x)

  • 이병완;;김정규
    • 세라미스트
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    • 제23권1호
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    • pp.101-109
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    • 2020
  • In this study, the phase transition behaviors of lead-free (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x (NBT-BT) are investigated by using Brillouin spectroscopy. The elastic properties, sound velocity and absorption coefficient of NBT-BT are characterized as a function of temperature along different crystallographic axes. The temperature dependences of the elastic constants of NBT-BT near the morphotropic phase boundary are determined for the first time. The unpoled NBT-BT single crystals exhibits the typical relaxor behaviors, presenting broad acoustic and dielectric anomalies. The application of electric field induced discontinuous changes in the elastic properties at ~110℃, which indicates field-induced phase transition occurred. The electric field also changes the dielectric constant from more relaxor-like to ferroelectric-like dielectric behavior.

미국 전기도매시장의 전기가격 추정 (Estimating Spot Prices of Restructured Electricity Markets in the United States)

  • 유시용
    • 자원ㆍ환경경제연구
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    • 제13권3호
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    • pp.417-440
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    • 2004
  • 미국의 PJM(Pennsylvania-New Jersey-Maryland) 전기도매시장의 전기 가격을 가변 전환확률 국면전환모형(regime switching model with time-varying transition probability model)을 이용해서 추정해보았다. 전기수요뿐만 아니라 기온을 전환확률 방정식의 설명변수로 포함시킴으로써 전기가격이 낮은 국면에서 높은 국면으로 전환할 확률의 문턱점(threshold) 효과가 뚜렷이 향상되었다. 따라서 도매전기가격의 스파이크(spike) 발생을 예측할 수 있게 되는 것이다. 이는 또한 미국의 도매시장 전기가격의 스파이크는 기온에 의해서도 잘 설명되며, 이를 이용하여 날씨관련 파생상품이나 계약을 통해서 도매전기 구입비용의 위험을 해지할 수 있다는 것을 의미한다.

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Metal-to-Insulator Transitions in La2/3Sr1/3MnO3/LaMnO3 (LSMO/LMO) Superlattices

  • Ryu, Sang-Woo;Jang, Hyun-M.
    • 한국세라믹학회지
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    • 제43권11호
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    • pp.734-737
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    • 2006
  • A series of manganite-based superlattices composed of half-metallic $La_{2/3}Sr_{1/3}MnO_3/LaMnO_3$ and insulating LaMnO$_3$ stacking layers were fabricated by employing pulsed laser deposition method. The dc resistivity increased drastically by simply reducing the stacking periodicity. The resistivity enhancement was accompanied by a gradual decrease in the temperature (T$_c$) of the Metal-to-Insulator Transition (MIT). This observation was interpreted as a small decrease in the effective metallic fraction near the percolation threshold. For the stacking periodicity less than a certain critical value, there appeared another transition to an insulating state at temperatures far below T$_c$. This low-temperature transition seems to be closely related to the AF-type (C-type) orbital ordering in newly formed insulating domains.

A Scanning Calorimetric Study of the Effect of Clover Saponin on Liposomal Phospholipid Membrane

  • Bae, Song-Ja;Han, Suk-Kyu;Im, Kwang-Sik;Kim, Nam-Hong
    • Archives of Pharmacal Research
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    • 제11권3호
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    • pp.181-184
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    • 1988
  • The effect of clover saponin on the phase transition of liposomal lipid bilayers of dimyristoyl phosphatidylcholine was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayers incorporated with the clover saponin were obtained, and the enthalpy changes and the sizes of cooperative unit of the transition were calculated. The results showed that incorporation of the clover saponin into the liposomal bilayers effectively reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. It also reduced the size of cooperative unit of the transition. These results indicate that the clover saponin might have significant effect on the fluidity of biological membranes.

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표면상변이의 강인력 의존성 : 점유통계를 이용한 정성적 고찰 (On the strong attractive force dependence of the surface phase transition : Qualitative consideration from the occupation statistics)

  • 김철호
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.573-577
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    • 1997
  • 표면상변이 현상은 표면 흡착입자들 사이에 강력한 인력포텐셜이 존재할 경우 일어나는 것으로 알려져 있다. 본 논문에서는 표면상변이 현상의 강인력 의존성을 간단한 점유통계를 이용하여 고찰하였다. 압력이 임계점에 도달하였을 때 표면 결정화가 급속히 진행되는 상변이 효과가 나타났으며, 온도가 증가함에 따라서 상변이가 일어나는 임계압력은 증가하였다. 이러한 결과는 표면상변이 현상에 대한 정성적 고찰로 사료된다.

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Kinetic Properties of Plasmas at Earth's Bow Shock

  • Lee, En-sang;Parks, George;Wilber, Mark;Lin, Naiguo
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2011년도 한국우주과학회보 제20권1호
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    • pp.29.2-29.2
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    • 2011
  • Earth's bow shock is a transition layer across which properties of plasmas change irreversibly. Although some features of the bow shock are well described by continuities of fluxes of various macroscopic quantities, particle dynamics across the transition layer is very complicated. Observed phase space distributions show multiple ion beams and partially thermalized ions around the transition layer. In some cases, both hot magnetosheath ions and cold solar wind ions simultaneously exist in the magnetosheath. Electrons around the transition layer usually have flat-top distributions with temperature anisotropy. From the observed properties of the phase space distributions we will discuss thermalization processes that occur across the shock transition.

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