• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2874-2879
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• 2008

The Selective catalytic reduction(SCR) system is a highly-effective device of $NO_x$ reduction for diesel engines. Generally, the ammonia($NH_3$) generated from a liquid urea-water solution is used for the reductant. The ideal ratio of $NH_3$ molecules to $NO_x$ molecules is 1:1 based on $NH_3$ consumption and having $NH_3$ available for reaction of all of the exhaust $NO_x$. However, under the too low and too high temperature condition, the $NO_x$ reduction efficiency becomes lower, due to temperature window. And space velocity also affects to $NO_x$ conversion efficiency. This paper reviews a laboratory study to evaluate the effects of $NO_x$ and $NH_3$ concentrations, gas temperature and space velocity on the $NO_x$ conversion efficiency of the SCR system. The maximum conversion efficiency of $NO_x$ was indicated when the $NH_3$ to $NO_x$ ratio was 1.2 and the space velocity was $60,000\;h^{-1}$. The results of this paper contribute to improve overall $NO_x$ reduction efficiency and $NH_3$ slip.

• 한국컴퓨터정보학회논문지
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• 제22권1호
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• pp.63-69
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• 2017

In this paper, we propose a method to optimize the geometry and installation position of the mixer in the selective catalytic reduction (SCR) system by computational fluid dynamic(CFD). Using the commercial CFD software of CFD-ACE+, the flow dynamics of the flue gas was numerically analyzed for improving the injection uniformity of the reduction agent. Numerical analysis of the mixed gas heat flow into the upstream side of the primary SCR catalyst layer was performed when the denitrification facility was operated. The characteristics such as the flow rate, temperature, pressure loss and ammonia concentration of the mixed gas consisting of the flue gas and the ammonia reducing gas were examined at the upstream of the catalyst layer of SCR. The temperature difference on the surface of the catalyst layer is very small compared to the flow rate of the exhaust gas, and the temperature difference caused by the reducing gas hardly occurs because the flow rate of the reducing gas is very small. When the mixed gas is introduced into the SCR reactor, there is a slight tendency toward one wall. When the gas passes through the catalyst layer having a large pressure loss, the flow angle of the exhaust gas changes because the direction of the exhaust gas changes toward a smaller flow. Based on the uniformity of the flow rate of the mixed gas calculated at the SCR, it is judged that the position of the test port reflected in the design is proper.

• Bulletin of the Korean Chemical Society
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• 제19권6호
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• pp.661-666
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• 1998

Active reaction sites and electrochemical O2 reduction kinetics on La_{1-x}Sr_xMnO_{3+{\delta}} (x=0.1-0.4)/YSZ (yttria-stabilized zirconia) electrodes are investigated in the temperature range of 700-900 ℃ at $Po_2=10^{-3}$-0.21 atm. Results of the steady-state polarization measurements, which are formulated into the Butler-Volmer formalism to extract transfer coefficient values, lead us to conclude that the two-electron charge transfer step to atomically adsorbed oxygen is rate-limiting. The same conclusion is drawn from the $Po_2$-dependent ac impedance measurements, where the exponent m in the relationship of $I_o$ (exchange current density) ∝ $P_{o_{2}}^m$ is analyzed. Chemical analysis is performed on the quenched Mn perovskites to estimate their oxygen stoichiometry factors (δ) at the operating temperature (700-900 ℃). Here, the observed δ turns out to become smaller as both the Sr-doping contents (x) and the measured temperature increase. A comparison between the 8 values and cathodic activity of Mn perovskites reveals that the cathodic transfer coefficients $({\alpha}_c)$ for oxygen reduction reaction are inversely proportional to δ whereas the anodic ones $({\alpha}_a)$ show the opposite trend, reflecting that the surface oxygen vacancies on Mn perovskites actively participate in the $O_2$ reduction reaction. Among the samples of x= 0.1-0.4, the manganite with x=0.4 exhibits the smallest 8 value (even negative), and consistently this electrode shows the highest ${\alpha}_c$ and the best cathodic activity for the oxygen reduction reaction.

• Nuclear Engineering and Technology
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• 제54권1호
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• pp.220-225
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• 2022

Perlite is one of the major constituents of the radioactive thermal insulation waste (RTIW) originating from nuclear power plants and, for proper waste management, a significant reduction in its volume is required prior to disposal. In this work, the volume reduction of perlite is studied by high-temperature treatment method with using K₂CO₃ as a flux. The perlite is ground with 0-30 wt% K₂CO₃, and differential thermal analysis/thermogravimetric analysis is used to monitor the glass transition temperature (T_g) and weight loss. The Tg varied between ~772.2 and 837.1 ℃ with the minima at ~643.5 ℃ with the addition of ~10 wt% K₂CO₃. It is observed that compared to the pure perlite the volume reduction ratio (VRR) increases with the addition of K₂CO₃. The VRR of 11.20 is observed with 5 wt% K₂CO₃ at 700 ℃, as compared to VRR of 5.56 without K₂CO₃ at 700 ℃. The X-ray photoelectron spectroscopy and scanning electron microscopy are used to characterize perlite samples heat-treated without/with 5 wt% K₂CO₃ at 700 ℃. Moreover, the atomic absorption spectroscopy indicates that the proposed heat-treatment procedure is able to completely retain the radionuclides present in the perlite RTIW.

• 청정기술
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• 제21권2호
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• pp.96-101
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• 2015

수소를 환원제로 사용한 산화철의 유동 환원에서, 환원율에 대한 다양한 공정 변수를 통해 산화철의 하나인 적철광의 환원 거동을 면밀히 관찰하였다. 본 연구를 위해 특별히 설계된 실험실 규모의 유동층 장치에서 목적으로 하는 환원 특성에 대한 가스 속도, 환원 시간 및 온도의 최적 값을 평가 하였다. 최적의 환원율을 나타낸 온도는 750 ℃, 환원 시간은 30분이며 이들을 다음의 시험을 위한 시작점으로 매개 변수 값을 설정 하였다. 가장 높은 관심을 갖는 변수들 중 하나는 가스의 소비 원단 위로, 이는 최적의 조건에서 산화철 1톤을 기준하여 90% 이상의 환원율을 달성하기 위해 요구되는 가스의 양을 말한다. 이 매개 변수는 실험실 수준 장치의 스케일 엎에 있어서 중요한 인자이며, 본 연구를 통해 1,500 Nm³/ton-ore가 산화철이 가장 높은 환원율을 갖기 위한 최적의 가스 소비 원단위 임을 확인하였다.

• 자원리싸이클링
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• 제20권4호
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• pp.71-77
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• 2011

$MoO_3$ 분말을 723 K ~ 873 K에서 Ar+$H_2$ 혼합기체를 이용히여 수평관상로에서 $MoO_2$로 훤원하였으며, 반용속도를 배가스 중의 상대습도를 측정하여 계산하였다. 반응속도는 수소가스 분압과 반응속도에 따라 현저하게 증가하였다. 환원 반응초기에 $H_2O$의 발생속도가 급격하게 증가하였으며, 시간의 경과에 따라 배가스 중의 $H_2O$ 분압은 급격하게 감소하였다. 이 시기에 환원 반응율은 직선적으로 증가하였다. 환원반응 초기의 $MoO_3$에서 $MoO_2$로의 환원반응의 활성화 에너지는 73.56 kJ/mol로 계산되었다.

• 원예과학기술지
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• 제31권5호
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• pp.538-543
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• 2013

여름철 절화 장미 재배 시 고온으로 인한 품질저하를 방지할 목적으로 분무기를 설치하여 기온의 변화와 절화 장미의 품질 및 병충해 발생 정도를 조사하였다. 그 결과, 분무처리 횟수가 증가할수록 일일 최고 온도가 떨어지는 효과가 있었으며, 5분 간격으로 10초간 처리했을 때 최고온도를 $6^{\circ}C$ 정도까지 떨어뜨리는 효과가 인정되었다. 그러나 이러한 온도저하 효과는 일일 최고온도가 $40^{\circ}C$ 이상이 되었을 때만 나타났다. 또한 분무처리는 장미의 초장과 생체중을 10-20%정도 촉진시키는 효과가 인정되었다. 다만, 분무처리에 의해 기형화 발생이 많아지고 절화수명이 대조구에 비해 오히려 짧아지는 등, 절화품질에는 부정적으로 작용하였다. 또한 파밤나방유충이나 깍지벌레와 같은 해충의 발생이 많아지는 부작용도 있었다. 따라서 여름 고온 시 온도저하 목적으로 분무를 사용하고자 할 때에는 $40^{\circ}C$ 이상의 고온 시에만 사용하는 것이 좋고, 해충의 발생이 심해질 수 있으므로 예방을 철저히 할 필요가 있다고 사료되었다.

• 한국분말재료학회지
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• 제13권4호
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• pp.278-284
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• 2006

Spherical Ag powder was prepared in the system of $AgNO_3\;and\;NaBH_4$ by wet chemical reduction method. The size of Ag powder was increased as the reaction temperature and the concentration of reducing agent was decreased in the constant concentration of dispersion agent. Optimum conditions of producing Ag powder having $1.39{\mu}m$ of D50 was 1M of $AgNO_3$, 0.5M of $NaBH_4$, 1.5g of Gelatine in the room temperature.

• 한국염색가공학회지
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• 제3권3호
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• pp.6-14
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• 1991

To develop an one-bath process for weight-reduction and mercerization of polyester/cotton fabric, concentrated NaOH solution was padded and steam-treated at high temperature. Following results which can be used commercially are obtained. (1) Steaming temperature of 110-12$0^{\circ}C$ is most efficient. (2) Optimum concentration of NaOH solution is 15-20%. (3) Most favorable weight-reduction is 20% in the aspect of fabric handle, and under this treating condition, dye exhaustion onto the mercerized cotton fiber is also increased to 40% or more. From above results, we believe that the economical and concurrent weight-reduction and mercerzation of polyester/cotton fabric can be realized. Moreover, with continuous treatment by pad-steam procedure, it is expected that this is, also, advantageous for the improvement of fabric quality and productivity.

• Journal of Mechanical Science and Technology
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• 제18권12호
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• pp.2303-2309
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• 2004

Flue gas recirculation (FGR) is a method widely adopted to control NOx in combustion system. The recirculated flue gas decreases flame temperature and reaction rate, resulting in the decrease in thermal NO production. Recently, it has been demonstrated that the recirculated flue gas in fuel stream, that is, the fuel induced recirculation (FIR), could enhance a much improved reduction in NOx per unit mass of recirculated gas, as compared to the conventional FGR in air. In the present study, the effect of FGR/FIR methods on NOx reduction in turbulent swirl flames by using N$_2$ and CO$_2$ as diluent gases to simulate flue gases. Results show that CO$_2$ dilution is more effective in NO reduction because of large temperature drop due to the larger specific heat of CO$_2$ compared to N$_2$ and FIR is more effective to reduce NO emission than FGR when the same recirculation ratio of dilution gas is used.