• Title/Summary/Keyword: Temperature inflection point

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pH-Temperature Dependence of the Ca-ATPase Activity in Actomyosin Systems of Rabbit and Frog Skeletal muscle (Actomyosin $Ca^{++}$ Activated Adenosinetriphosphatase 활성도에 대한 pH 및 온도의 영향)

  • Kim, Hee-Joong;Hwang, Ae-Ran;Park, Yang-Saeng;Kang, Doo-Hee
    • The Korean Journal of Physiology
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    • v.11 no.2
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    • pp.1-7
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    • 1977
  • The activity of the $Ca^{++}$ activated adenosinetriphosphatase (Ca-ATPase) of actomyosin systeme of rabbit and frog skeletal muscle has been studied at varying pH and temperature. The PH optima of the Ca-ATPase activity of the rabbit actomyosin was rather broad. Over the temperature range of $16-36^{\circ}C$ activity of the enzyme was not appreciably changed between pH 6.4-8.5; below and above which it rapidly reduced. The pH at the inflection point of the enzyme activity increased as temperature decreased, showing the ${\bigtriangleup}pH\;inflection/{\bigtriangleup}T$ of approximately $-0.018\;unit/^{\circ}C$. Consequently, $(OH^-)/(H^+)$ ratio at the inflection point was constant regardless of assay temperature. In the frog actomyosin systems the Ca-ATPase activity was not apparently altered between PH 6.4-7.0 when the incubation temperature was $15{\sim}30^{\circ}C$. Outside of this range of pH, however, the enzyme activity was dramatically decreased. The pH of the inflection point changed inversely with temperature. ${\bigtriangleup}pH\;inflection/{\bigtriangleup}T$ at the acidic side was approximately $-0.018\;unit/^{\circ}C$, whereas that at the alkaline side it was about $-0.037\;unit/^{\circ}C$. The Arrhenius Plot on the Ca-ATPase activity at constant $(OH^-)/(H^+)$ ratio of 1.0 was not linear, but showed break at arround $20^{\circ}C$ for both rabbit and frog actomyosin Preparations. From these results it was speculated that pH dependence of Ca-ATPase activity of rabbit actomyosin systems might reflect titrations of histidine-imidazole and -SH groups, and that of the frog actomyosin represents titrations of histidine-imidazole and lysyllysine ${\alpha}-NH_2$ groups.

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Effect of Ni and Mn on Strain Induced Martensite Behavior of 22Cr Micro-Duplex Stainless steel (22Cr 마이크로 듀플렉스 스테인리스강의 변형유기마르텐사이트에 미치는 Ni과 Mn의 영향)

  • Park, Jun-Young;Kim, Gi-Yeob;Ahn, Yong-Sik
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.122-129
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    • 2013
  • The microstructure and deformation behavior in 22Cr-0.2N micro-duplex stainless steels with various Ni and Mn contents were compared using by OM, TEM, and XRD. The 22Cr-0.2N duplex stainless steel plates were fabricated and hot rolled, followed by annealing treatment at the temperature range of $1,000-1,100^{\circ}C$. All the samples showed the common strain hardening behaviour during the tensile test at a room temperature. The steels tested at the temperatures of $-30^{\circ}C$ or $-50^{\circ}C$ showed a distinct inflection point in the stress-strain curves, which should be resulted from the formation of strain-induced martensite(SIM) of austenite phase. This was confirmed by TEM observations. The onset strain of a inflection point in a stress-strain curve should be depended up the value of $M_d30$. With the decrease of the tensile test temperature, the inflection point appeared earlier, and the strength and fracture strain were higher. The tensile behaviour was discussed from the point of austenite stability of the micro-duplex stainless steels with the different Ni and Mn content.

A study on the change of characteristics and frequency correction method of OCXO by temperature sensor position (온도 센서 위치에 의한 OCXO의 특성 변화와 주파수 보정 방법 연구)

  • Cho, Gyu-Pil;Lee, Young-Soon
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.6
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    • pp.129-135
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    • 2020
  • This study relates to a characteristic change and frequency correction method according to the temperature sensor position of an oven-controlled crystal oscillator (OCXO) using a 10 MHz SC-CUT crystal. Although there are several methods of manufacturing the previous high-precision 10MHz OCXO, the present study shows that the frequency stability characteristics against external temperature changes can be improved simply by adjusting the position of the temperature sensor. Factors that affect the frequency characteristics of the OCXO include the temperature transmitted to the crystal, the voltage applied to the crystal, and the capacitance constituting the oscillation circuit. The amount of change in frequency due to these factors was measured, and the change in the correction value of the OCXO output frequency was investigated by measuring the temperature inflection point and changing the capacitor value.

Electrical Conduction Characteristics of Ultra High Voltage Cable for Prevention of Electrical Fires (전기 방재를 위한 초고압케이블의 전기 전도 특성)

  • Park, Hee-Doo;Park, Ha-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.216-217
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    • 2007
  • In this paper we investigated the volume resistivity and AC conduction current according to the temperature and voltage. As a result, the volume resistivity comes to be small according to the measurement temperature and voltage. AC conduction current of the heat treatment specimen is increased because of the decrease of insulation.

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Computation of Ionic Conductivity at NASICON Solid Electrolytes (II) Effects of mid-Na Sites on Na1-Na2 Conduction Paths (NASICON 고체 전해질의 이온 전도도 계산 (II) Na1-Na2 전도 경로에 미치는 mid-Na의 영향)

  • 최진삼;서양곤;강은태
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1292-1300
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    • 1995
  • The ionic conductivity of NASICON solid electrolytes was simulated by using Monte Carlo Method (MCM). There were included two conduction paths: (1) Na1-Na2 and (2) Na1-Na2 including Na2-Na2. We assumed that mid-Na ions provde an additional driving force for Na mobile ions due to the interionic repulsion between Na1 and Na2 ions. The inflection point of vacancy availability factor, V has been shown at nearby x=2, the maximum mid-Na ions. The inflection point of vacancy availability factor, V has been shown at nearby x=2, the maximum mid-Na sites are occupied. The effective jump frequency factor, V has been shown at nearby x=2, the maximum mid-Na sites are occupied. The effective jump frequency factor, W increased rapidly with the composition at low temperature, but decreased at high temperature region. On Na1-Na2 conduction path, the minimum of charge correlation factor, fc and the maximum of $\sigma$T were appeared at x=2.0. this indicated that mid-Na ions affect on the high ionic conductivity behavior. At the whole range of NASICON composition, 1n $\sigma$T vs. 1/T* plots have been shown Arrhenius behavior but 1n (VWFc) vs. 1/T* have been shown the Arrhenius type tendency at x=2, which mid-Na is being the maximum. The results of MCM agreed with the experimental one when the chosen saddle point value was 6$\varepsilon$ : 3$\varepsilon$. Here the calculated characteristic parameter of materials, K and the phase transition temperature were -4.001$\times$103 and 178$^{\circ}C$ (1/T*=1.92, 1000/T=2.22), respectively.

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A Study on Thermal Stratification Phenomenon due to In-Leakage in the Safety Injection Piping of Nuclear Power Plant (원전 안전주입 배관에서의 In-Leakage 에 의한 열성층 현상에 관한 연구)

  • Kim, K.C.;Park, M.H.;Youm, H.K.;Kim, T.Y.;Lee, S.K.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1633-1638
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    • 2003
  • In case that in-leakage through the valve disk occurs, a numerical study is performed to estimate on thermal stratification phenomenon in the Safety Injection piping connected with the Reactor Coolant System piping of Nuclear Power Plant. As the leakage flow rate increases, the temperature difference between top and bottom of horizontal piping has the inflection point. In the connection point of valve and piping, the maximum temperature difference between top and bottom was 185K and occurred in the condition of 10 times of standard leakage flow rate. In the connection point of elbow and horizontal piping, the maximum temperature difference was 145K and occurred in the condition of 15 times of standard leakage flow rate. In the vertical piping of Safety Injection piping, the near of connection point between elbow and vertical piping showed the outstanding thermal stratification phenomenon in comparison with another region because of turbulent penetration from Reactor Coolant System piping. In order to prevent damage of piping due to the thermal stratification when in-leakage through the valve disk occurs, the connection points between valve and piping, and the connection points between elbow and piping need to be inspected continually.

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Temperature and Atmosphere Dependence of the Electrical Conduction of the Vacuum Evaporated Thin Metal Films on Glass Substrate (진공증착된 금속박막의 전기전도성에 대한 온도와 분위기 의존성)

  • 김명균;박현수
    • Journal of the Korean Ceramic Society
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    • v.28 no.6
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    • pp.437-442
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    • 1991
  • Temperature and atmosphere dependence of electrical conduction of the metal Cu, Ag, Au films, vaccum evaporated on glass, was investigated. The structural changes of the metal films were examined by SEM and high temperature XRD. The electrical resistance slightly increased with initial temperature increase up to the inflection point and decreased to minimum value, after this rapidly increased with further temperature increased below minimum. These phenomena were caused by the thermally induced film failure as a result of the mass transport. The temperature for the film failure increased in the order of O2, Air, Vacuum, N2, Ar in Cu, Ag films and Air, Vacuum, N2, Ar in Au film. The increase of resistance at the lower temperature range was attributed to the lattice distortion by disordered crystal structure, while the decreasing resistance was attributed to the removal of structural defects and film densification.

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Prediction of High Temperature Plastic Deformation Variables on Al 6061 Alloy (Al 6061 합금의 고온 소성변형 조건의 예측)

  • 김성일;정태성;유연철;오수익
    • Transactions of Materials Processing
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    • v.8 no.6
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    • pp.576-582
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    • 1999
  • The high temperature behavior of Al 6061 alloy was characterized by the hot torsion test in the temperature ranges of 400∼550℃ and the strain rate ranges of 0.05∼5/sec. To decide optimum deformation condition, three types of deformation maps were individually made from the critical strain (εc). deformation resistance(σp) and deformation efficiency (η). The critical strain(εc) for dynamic recrystallization (DRX) which was decided from the inflection point of strain hardening rate(θ) - effective stress (σ) curve was about 0.65 times of peak strain (εp). The relationship among deformation resistance (peak stress, σp), strain rate (ε), and temperature (T) could be expressed by ε=2.9×1013[sinh(0.0256σp]7.3exp (-216,000/RT). The deformation efficiency (η)which was calculated on the basis of the dynamic materials model (DMM) showed high values at the condition of 500∼550℃, 5/sec for 100% strain. The results from three deformation maps were compared with microstructures. The best condition of plastic deformation could be determined as 500℃ and 5/sec.

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Dielectric Characteristics of EVA and LLDPE Films (에틸렌비닐아세테이트와 선형저밀도폴리에틸렌 박막의 유전특성)

  • 성민우;고시현;신종열;이충호;조경순;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.783-786
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    • 2000
  • In this paper, physical properties and dielectric characteristics of LLDPE and EVA which are used as a blending material to improve PE's performance are studied. LLDPE of 0.92[g/cm3] and EVA with the EVA contents of 12.5[%1 were selected as specimens, and X-ray diffraction(XRD) are used to analysis physical properties. We measured dielectric constant with the frequency range from 20[Hz] to 1 [MHz], applied voltage 6[V] and the temperature from 25[$^{\circ}C$] to 110[$^{\circ}C$]. From XRD, LLDPE has a crystallinity of 53[%] and, 46[%] for EVA. LLDPE has as low tan$\delta$ as of 10$^{-3}$ ~10$^{-4}$ and inflection point near 500[Hz]. At frequency region lower than 500[Hz], tan$\delta$ decreases with frequency and increases with temperature and it is considered to be caused by conductive carriers within specimen. Over 500[Hz], it is the reverse and we thought that it was caused by decrease of relaxation time due to Debye theory, EVA has tan$\delta$with the values of 10$^{-2}$ ~10$^{-3}$ , which is higher than that of LLDPE, and it has inflection point at 60[Hz]. It is shown that Dielectric characteristics of EVA are similar to LLDPE's.

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Phase Transition Temperature Shift of a Ferromagenetic Gadelonium Film due to the Finite-Size Effects (Finite-Size Errect에 의한 강바성 Gd박막의 상전이온도 이동)

  • Rhee, Il-Su;Lee, Eui-Wan;Lee, Sang-Yun
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.3-6
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    • 1993
  • Abstract We report the result of measurement for the ferro-to paramagnetic phase transition temperature shift of a gadolinium film. The phase transition temperature has been determined by measuring the resistance changes of film as function of temperature. At the ferro-to paramagnetic transition temperature, we can observe the inflection point of resistance changes. The phase transition temperature of 6600$\AA$ gadolinium film is found to be shifted by 4 $\pm$ 0.$3^{\circ}C$ below the transition temperature of bulk gadolinium. This is the first measurement for the phase transition temperature shift of ferromagnetic gadolinium film. This and further results might give a milestone in resolving the differences between experiments and finite-size scaling theory.

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