• Title/Summary/Keyword: Temperature coefficient of resonant frequency

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Dielectric Properties of Sr$(Mg_{1/3}Mb_{2/3})$$O_3$-Ba$(Mg_{{1/3}Nb_{2/3})$$O_3$ Solid Solution ($Sr(Mg_{1/3}Mb_{2/3})$$O_3$-$Ba(Mg_{{1/3}Nb_{2/3})$$O_3$ 고용체의 유전성)

  • 윤기현;정범준;김응수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.105-107
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    • 1988
  • The dielectric properties of complex perovskite compound Sr$(Mg_{1/3}Mb_{2/3})$$O_3$-Ba$(Mg_{{1/3}Nb_{2/3})$$O_3$(BMN) system were investigated as a function of composition and sintering time. In the case of the specimens sintered at $1650^{\circ}C$ for same time, dielectric constant and dielectric loss were increased with increasing the mole ratio of BMN. The maximum temperature coefficient of resonant frequency was found in composition Ba$(Mg_{{1/3}Nb_{2/3})$$O_3$. In the case of the specimens with same composition, dielectric constant and dielectric loss were slightly increased with increasing the sintering time. As the sintering time was increased, the temperature coefficient of resonant frequency for SMN was slightly increased, however, that of BMN and ($Sr_{1/2}Ba_{1/2}$) ($Mg_{1/3}Ta_{2/3}$)$O_3$ was largely depended on sintering time.

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Microwave Dielectric Characteristics of $Ba(Mg_{1/3}Nb_{2/3})O_3$ - $La(Mg_{2/3}Nb_{1/3})O_3$ Solid Solutions with Crystal Structure (결정구조에 의한 $Ba(Mg_{1/3}Nb_{2/3})O_3$ - $La(Mg_{2/3}Nb_{1/3})O_3$고용체의 마이크로파 유전 특성)

  • Paik, Jong-Hoo;Lim, Eun-Kyeong;Lee, Mi-Jae;Choi, Byung-Hyun;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.738-743
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    • 2004
  • The microwave dielectric properties and their related structural characteristics in solid solutions of (1-x) $Ba(Mg_{1/3}Nb_{2/3})O_3$ -x $La(Mg_{2/3}Nb_{1/3})O_3$ (BLMN) have been investigated by measuring the dielectric constant${\varepsilon}r)$, Q value and temperature coefficient of resonant frequency$({\tau}f)$ and by observing the crystal structure using high resolution transmission electron microscopy (HRTEM). Microwave dielectric properties showed characteristic features for specific composition. Dielectric constant$({\varepsilon}r)$ showed maximum value at the composition which corresponds to the phase boundary between 1:2 ordered and 1:1 ordered structure. The increase in ${\varepsilon}_r$ may be caused by the rattling of ions by incorporating smaller ions and the disordered structure. The variation of temperature coefficient of resonant frequency${{\tau}_f)$ was investigated in terms of oxygen octahedra tilting.

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Low sintering and dielectric properties of $BiNbO_4$ microwave dielectrics ($BiNbO_4$ 마이크로파 유전체의 저온 소결 및 유전 특성)

  • Yoon, Sang-Ok;Kwon, Hyeok-Jung;Kim, Kwan-Soo;Lee, Hyun-Sik;Shim, Sang-Heung;Park, Jong-Guk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.313-314
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    • 2006
  • $BiNbO_4$ ceramics were sintered under the presence of zinc-borosilicate(ZBS) glass and resultant microwave dielectric properties were investigated with a view to applying the composition to LTCC technology. The addition of 5~20 wt% ZBS glass ensured successful sintering below $900^{\circ}C$. In general, increased addition of ZBS glass increased sinterability and temperature coefficient of resonant frequency(${\tau}_f$), but it decreased the dielectric constant(${\varepsilon}_r$) and quality factor($Q{\times}f_0$) significantly due to the formation of an excessive liquid. The sintered $BiNbO_4$ ceramics at $900^{\circ}C$ with 15 wt% ZBS glass demonstrated 25 in dielectric constant(${\varepsilon}_r$), 3,700 in quality factor($Q{\times}f_0$), and -32 $ppm/{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_f$).

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Microwave Dielectric Properties of the $MgTiO_3$ Ceramics with $SrTiO_3$ ($SrTiO_3$ 첨가에 따른 $MgTiO_3$ 세라믹스의 마이크로파 유전특성)

  • Bae, Koung-In;Park, In-Gil;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.473-475
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    • 2000
  • The (1-x)$MgTiO_3-xSrTiO_3$$(x=0.03{\sim}0.04)$ ceramics were fabricated by conventional mixed oxide method. The structural properties and microwave dielectric properties were investigated by XRD, SEM and HP8757D network analyzer. In the $0.96MgTiO_3-0.04SrTiO_3$ ceramics, the perovskite structure $SrTiO_3$ and ilmenite structure $MgTiO_3$ phases were coexisted. The dielectric constant(${\varepsilon}_r$ and temperature coefficient of resonant frequency(${\tau}_f$) was increased with addition of $SrTiO_3$. In the case of $0.96MgTiO_3-0.04SrTiO_3$ ceramics sintered at $1325^{\circ}C$, the dielectric constant, quality factor and temperature coefficient of resonant frequency were 20.13, 7956(at 7.27GHz), +1.7568ppm/$^{\circ}C$, respectively.

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The Performance Investigation of 1/4 Wavelength Thermoacoustic Refrigerator with Helium Refrigerant (헬륨을 냉매로 사용한 1/4파장 열음향 냉동기의 성능 평가)

  • 송규조;박종호;이성노
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.2
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    • pp.52-57
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    • 2002
  • In this study, a thermoacoustic refrigerator, using a resonant standing acoustic wave. has been built. The refrigerant is helium gas. The description of thermoacoustic refrigerator was Presented. The temperature ratio (cold part temperature over hot part temperature) and the COP (Coefficient of Performance) that normalized by carnot's COP are plotted versus the thermal load applied to the cold end, for- various speaker power.

Piezoelectric Properties of PSN-PMN-PT-PZ System (TSN-PMN-PT-PZ계 압전특성)

  • 성연우;장창섭;오봉인;강원호
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.21-26
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    • 1988
  • The piezoelectric properties and temperatureproperties of resonant frequency of the pseudoquaternary soild solution 0.075 Pb(Sb$\frac{1}{2}$Nb$\frac{1}{2}$)O3-0.025 Pb(Mn1/3Nb2/3)O3-xPbTiO3-(0.9-x) PbZrO3 were investigated. The composition range examined are 0.32 x 0.57. Specimens were prepared by the conventional mixed oxide technique, calcined at 850$^{\circ}C$ for 1 hour and sintered at 1270$^{\circ}C$ for 2 hours under PbO atmosphere. From the results of XRD, dielectric and piezoelectric properties, it is supposed that the MPB composition between tetragonal and rhombohedral ferroelectric perovskite exists in 0.42$^{\circ}C$ was considered at the nearby MPB.

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Microwave Dielectric Properties of ZST Ceramics for Mobile Telecommunication System (기지국용 ZST세라믹스의 소결조건에 따른 고주파 유전 특성)

  • 서정철;이희영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.636-639
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    • 2000
  • Effects of sintering temperature and time on relative permittivity $\varepsilon$$\_$r/, unloaded quality factor Q$.$f and temperature coefficient of resonant frequency $\tau$$\_$f/ of dielectric resonator materials produced from commercial ZST powder were investigated in some detail. Q$.$f values, as determined from cavity perturbation method at 1.6 GHz, gradually increased with sintering temperature reaching the maximum at 1420$^{\circ}C$. However, bulk density and relative permittivity values, which increased with temperature, started to decrease above 1380$^{\circ}C$. In addition, Q$.$f values slightly increased with sintering time at the sintering temperature of 1300$^{\circ}C$∼1380$^{\circ}C$, while bulk density and relative permittivity values were approximately constant. It was also found that $\tau$$\_$f/ values were not affected by sintering temperature and time within the experimental conditions used.

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Structural and Microwave Dielectric Properties of the $0.9MgTiO_3-0.1SrTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 $0.9MgTiO_3-0.1SrTiO_3$ 세라믹스의 구조 및 마이크로파 유전특성)

  • Choe, Ui-Seon;Lee, Mun-Gi;Ryu, Gi-Won;Bae, Seon-Gi;Lee, Yeong-Hui
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.5
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    • pp.294-298
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    • 2000
  • The $MgTiO_3\; and \;$0.9MgTiO_3-0.1SrTiO_3$ ceramics were fabricated by the conventional mixed-oxide method. The sintering temperature and time were $1300^{\circ}C~1600^{\circ}C$, 2hr., respectively. The structural and microwave dielectric properties were investigated with sintering temperature and the application for the satellite communication microwave dielectric resonator was investigated. The coexistence of cubic $SrTiO_3$ and hexagonal TEX>$MgTiO_3$ structures in $0.9MgTiO_3-0.1SrTiO_3$ ceramics were found from X-ray diffraction patterns. In the case of $MgTiO_3$ ceramics, sphere phase and needle-like phase were coexisted. The $0.9MgTiO_3-0.1SrTiO_3$ ceramics observed sphere phase. The dielectric constants and temperature coefficient of resonant $frequency(\tauf)$ were increased with addition of $SrTiO_3$ but the quality factor was decreased. The dielectric constant, quality factor and $\tau$f of the;$0.9MgTiO_3-0.1SrTiO_3$ ceramics were 22.61, 10.928(at 1GHz) and $+50.26ppm/^{\circ}C$, respectively.

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Effect of Sintering Additives and Annealing Atmospheres on the Microwave Dielectric and Sintering Characteristics of $(1-x)CaTiO_3-xLaAlO_3$ System (소결조제와 열처리 분위기가 $(1-x)CaTiO_3-xLaAlO_3$ 계의 소결 및 마이크로파 유전특성에 미치는 영향)

  • 이경태;여동훈;문종하
    • Journal of the Korean Ceramic Society
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    • v.34 no.6
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    • pp.629-635
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    • 1997
  • The effects of the annealing atmospheres(O2, N2) and sintering additives that Bi2O3 is a major composition on the microwave dielectric and sintering propertie of (1-x)CaTiO3-xLaAlO3 system were investigated. The annealing atmospheres and the increase of annealing time after sintering did not affect the relative dielectric constant($\varepsilon$r) and temperature coefficient of resonant frequency($\tau$f) of (1-x)CaTiO3-xLaAlO3 system. However, the Q.f0 values of (1-x)CaTiO3-xLaAlO3 were very sensitive to annealing atmospheres. As the annealing time increased under O2 atmosphere the Q.f0 values of (1-x)CaTiO3-xLaAlO3 enhanced untill 10 hrs in 0.3$\leq$x$\leq$0.6 region, but degraded over that time. The increasing rate of Q.f0 value increased wth increasing x. On the other hand, as the annealing time increased under N2 atmosphere the Q.f0 values were constant in x$\leq$0.6 region, increased gradually in x$\geq$0.7 region. When 0.97Bi2O3-0.03Al2O3 and 0.76Bi2O3-0.24NiO of 3wt% as sintering additives were added to (Ca0.5La0.5) (Ti0.5Al0.5)O3 (x=0.5) the sintering temperature of 1$600^{\circ}C$ was lowered to 140$0^{\circ}C$, and the relative dielectric constant($\varepsilon$r) and temperature coefficient of resonant frequency($\tau$f) were not nearly changed. The addition of 0.97Bi2O3-0.03Al2O3 and 0.76Bi2O3-0.24NiO of 3wt% to (Ca0.5La0.5)(Ti0.5Al0.5)O3 made the Q.f0 values to be lower about 15% and 34%, respectively.

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The Structural and Microwave Dielectric Properties of the BMT Ceramics with Sintering Temperature and BCN Composition Ratio (소결온도와 BCN 초성에 따른 BMT 세라믹스의 구조 및 마이크로파 유전특성)

  • Choe, Ui-Seon;Lee, Mun-Gi;Ryu, Gi-Won;Lee, Seong-Gap;Lee, Yeong-Hui
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.7
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    • pp.305-310
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    • 2002
  • The microwave dielectric properties of Ba(Mg$_{1}$3/Ta$_{2}$3/O$_3$-Ba(Co$_{1}$3/Nb$_{2}$3/O$_3$[BMT-BCN] ceramics were investigated. The specimens were prepared by the conventional mixed oxide method with the sintering temperature of 15$25^{\circ}C$~1575$^{\circ}C$. It was found that Ba(Mg$_{1}$3/Ta$_{2}$3/O$_3$[BMT] and BCN formed a solid solution with complex perovskite structure. As increasing the mole fraction of BCN, dielectric constant increased while the temperature coefficient of resonant frequency was changed from positive to negative value. The highest value of quality factor, Q$\times$f$_{0}$=138,205GHz, obtained in the 0.9BMT-0.1BCN ceramics sintered at 1575$^{\circ}C$. In the range of x$\geq$0.4, the dielectric constant was about 30. The 0.55BMT-0.45BCN ceramics sintered at 15$25^{\circ}C$ for 5 hours showed the microwave dielectric properties of $\varepsilon$$_{r}$=30.21, Q$\times$f$_{0}$=85,789GHz and $\tau$$_{f}$=2.9015ppm/$^{\circ}C$.EX>.