• Title/Summary/Keyword: Temperature Inversion

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Formation of Thin $CoSi_2$by Layer Inversion of Co/Nb bi-layer (Co/Nb 이중층 구조의 막역전을 이용한 박막 $CoSi_2$의 형성)

  • Lee, Jong-Mu;Gwon, Yeong-Jae;Lee, Byeong-Uk;Kim, Yeong-Uk;Lee, Su-Cheon
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.779-785
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    • 1996
  • Thin $700^{\circ}C$films were formed through layer inversion of Co/Nb bilayer during rapid thermal annealing(RTA). The Nb interlayer seems to effectively prevent over-consumption of Si and to control the silicidation reaction by forming Co-Nb intermetallic compounds and removing the native oxide formed on Si substrate which interferes the uniform Co-Si interaction. The final layer structure of the Co/Nb bilayer after $700^{\circ}C$ RTA was found to be ${Nb}_{2}{O}_{3}$/${Co}_{2}$Si.CoSi/${NbCo}_{x}$/Nb(O, C)/${CoSi}_{2}$/ Si. The layer inversion and the formation of a stable CoSi, phase occurred above $700^{\circ}C$, and the Nb silicides were not found at any annealing temperature. These may be due to the formation of very stable Co-Nb intermetallic compounds and Nb oxides which limit the moving of Co and Si.

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Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.

A GN-based modified model for size-dependent coupled thermoelasticity analysis in nano scale, considering nonlocality in heat conduction and elasticity: An analytical solution for a nano beam with energy dissipation

  • Hosseini, Seyed Mahmoud
    • Structural Engineering and Mechanics
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    • v.73 no.3
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    • pp.287-302
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    • 2020
  • This investigation deals with a size-dependent coupled thermoelasticity analysis based on Green-Naghdi (GN) theory in nano scale using a new modified nonlocal model of heat conduction, which is based on the GN theory and nonlocal Eringen theory of elasticity. In the analysis based on the proposed model, the nonlocality is taken into account in both heat conduction and elasticity. The governing equations including the equations of motion and the energy balance equation are derived using the proposed model in a nano beam resonator. An analytical solution is proposed for the problem using the Laplace transform technique and Talbot technique for inversion to time domain. It is assumed that the nano beam is subjected to sinusoidal thermal shock loading, which is applied on the one of beam ends. The transient behaviors of fields' quantities such as lateral deflection and temperature are studied in detail. Also, the effects of small scale parameter on the dynamic behaviors of lateral deflection and temperature are obtained and assessed for the problem. The proposed GN-based model, analytical solution and data are verified and also compared with reported data obtained from GN coupled thermoelasticity analysis without considering the nonlocality in heat conduction in a nano beam.

Flexural Properties and Thermal Stability of Bifunctional/Tetrafunctional Epoxy Blends (2 -관능성 에폭시 수지 블렌드의 굴곡 특성과 열 안전성)

  • Yu, Hui-Yeol;Lee, Jae-Rak;Lee, Jong-Mun
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.75-80
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    • 1994
  • Flexural properties and thermal stability have been studied as a function of blend composition in bifunctional DGERA (diglycidyl ether of hisphenol A)/tetrafunctional TGDDM(tetrag1ycidyl diamino diphenyl methane) cured with DDM(4, 4'-diamino diphenyl methane). The flexural modulus and the glass transition temperature increase with an increase of TGDDM and show discontinuous dependence on blend composition around the composition range of 80/20~60/40(L)GEBA/TGDDM). This can be explained with a structural phase inversion (ductile-to-brittle) in crosslinking networks. With increasing TGDDM, the maximum decomposition temperature(Ts) increases, whereas the activation energy during thermal degradation decreases.

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Performance test of Joule-Thomson cryocooler with $H_2$gas (수소 Joule-Thomson냉동기의 성능실험)

  • 백종훈;강병하;홍성제;장호명
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.4
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    • pp.457-463
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    • 1999
  • The Joule-Thomson cryocooler with $H_2$gas has been developed. Cool-down characteristics and the cooling performance of a JT cryocooler have been investigated in detail. The JT cryocooler consists of JT expansion valve, heat exchanger, expansion chamber, compressed $H_2$gas storage tank, $LN_2$precooler, heater and a cryostat. The precooling process using both $GN_2$and $LN_2$was peformed to cool down the inside components of cryocooler under the maximum inversion temperature of $H_2$. The $H_2$expansion experiments have been peformed for 2-5MPa of H$_2$pressure to evaluate steady state temperatures of the cryocooler. It is found that the steady state temperatures are decreased as the H$_2$pressures are increased. The effects of cooling temperatures on the performance have been evaluated for various $H_2$and $N_2$pressures. It is seen that the cooling loads are increased, as the cooling temperature and operating pressure are increased.

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Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.

Doping-Concentration and Annealing Effects on Photoluminescence Profile of Eu(III)-doped CeO2 nanorods

  • Lee, Juheon;Park, Yohan;Joo, Sang Woo;Sohn, Youngku
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3319-3325
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    • 2014
  • Eu(III)-doped $CeO_2$ nanorods were prepared by a co-precipitation method at room temperature, and their photoluminescence profiles were examined with different Eu(III)-doping concentrations and thermal annealing temperatures. Scanning electron microscopy, X-ray diffraction crystallography and UV-Vis absorption spectroscopy were employed to examine the morphology, crystal structure and photon absorption profiles of the nanorods, respectively. Additionally, their 2D and 3D-photoluminescence profile maps were obtained to fully understand the photoluminescence mechanism. We found that the magnetic dipole $^5D_0{\rightarrow}^7F_1$ and the electric dipole $^5D_0{\rightarrow}^7F_2$ transitions of Eu(III) were highly dependent on the doping concentration, annealing temperature and excitation wavelength, which was explained by the presence of different Eu(III)-doping sites (with and without an inversion center) in the $CeO_2$ host with a cubic crystal structure.

Numerical Prediction on Snowfall Intensity in the Mountainous Coastal Region

  • Choi, Hyo;Lee, Han-Se;Kim, Tae-Kook;Choi, Doo-Sun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.89-94
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    • 2003
  • The formation of a severe snow storm occurred in the mountainous coastal region near Mt. Taegualyang and Kangnung city in the eastern part of Korea was investigate from 0900LST, December 7 through 9, 2002, using MM5 model. As synoptic scale easterly wind induced a great amount of moisture from the East Sea into the inland coastal region and sea-breeze further induced more moisture from the basin toward the top of the mountain side. The lifted moisture toward the mountain top was cooled down along the eastern slope of the mountain and near the mid of the mountain the moisture was much cooled down with relative humidity of 100% under the air temperature below $O^{\circ}C$, resulting in the formation of snow. Relative humidity of 100% generally occurred at the 5km away from the coast toward the inland mountain and the band of 100% RH was parallel to the coastal line. The 100% band coincided with minimum air temperature band and line.

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Application of SP and Pole-pole Array Electrical Resistivity Surveys to the Seawater Leakage Problem of the Embankment (방조제 누수지점 탐지를 위한 SP및 단극배열 전기비저항탐사의 적용)

  • 송성호;이규상;김진호;권병두
    • Economic and Environmental Geology
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    • v.33 no.5
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    • pp.417-424
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    • 2000
  • We applied SP monitoring and resistivity surveys using the pole-pole electrode array to seawater leakage problems in the Youngsan estuary dam and the Eoeun embankment to estimate and detect the zone of seawater leakage. The embankment is generally affected by tidal variation and has low resistivity characteristics due to the high saturation of seawater. For this reason, SP monitoring and the pole-pole array resistivity surveys, which are relatively more effective to the conductive media, were carried out to delineate the leakage zones of sea water through the embankment. We checked out electrical conductivity (EC) and temperature variations along the inner part of Youngsan estuary dam to detect the zone of seawater leakage and found that the measured EC value agreed to that of seawater in the leakage zone and the temperature was lower than that of the vicinity of leakage zone. SP monitoring results were coincided with tidal variations at each embankment. At the leakage zones in the Youngsan estuary dam and the Eoeun embankment, SP anomalies are in the range of -60~-85 mV and -20~-50 mV, respectively, and true resistivity values obtained by 2-D inversion are 3~15 ohm-m and below 0.3 ohm-m, respectively. Both SP monitoring and the pole-pole array resistivity method are found to be quite effective for investigation of seawater leakage zones in the embankment.

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Gravity wave activities in the polar region using FORMOSAT-3 GPS RO observations

  • Liou, Yuei-An;Yan, Shiang-Kun
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.65-68
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    • 2007
  • FORMOSAT-3 was launched in April of 2006. It consists of six low earth orbit (LEO) satellites that will be eventually deployed to an orbit at 800 km height. Its scientific goal is to utilize the radio occultation (RO) signals to measure the bending angles when the GPS signals transect the atmosphere. The bending angle is then used to infer atmospheric parameters, including refractivity, temperature, pressure, and relative humidity fields of global distributions through inversion schemes and auxiliary information. The expected number of RO events is around 2500 per day, of which 200 events or so fall into the polar region. Consequently, the FORMOSAT-3 observations are expected to play a key role to improve our knowledge in the weather forecasting and space physics research in the polar region. In this paper, we use temperature profiles retrieved from FORMOSAT-3 RO observations to study the climatology of gravity wave activity in the polar region. FORMOSAT-3 can provide about 200 RO observations a day in the polar region, much more than previous GPS RO missions, and, hence, more detailed climatology of gravity wave activity can be obtained.

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