• 제목/요약/키워드: Te nanoparticles

검색결과 26건 처리시간 0.035초

Electrochemical Characterization of Multilayered CdTe/PSS Films Prepared by Electrostatic Self-assembly Method

  • Rabbani, Mohammad Mahbub;Yeum, Jeong Hyun;Kim, Jungsoo;Nam, Dae-Geun;Oh, Weontae
    • Transactions on Electrical and Electronic Materials
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    • 제15권5호
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    • pp.257-261
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    • 2014
  • Multilayered CdTe/PSS films were prepared by the electrostatic self-assembly method in an aqueous medium. Positively-charged cadmium telluride (CdTe) nanoparticles and anionic polyelectrolyte, poly (sodium 4-styrene sulfonate) (PSS) were assembled alternately in order to build up a multilayered film structure. A linear proportion of absorbance to the number of bilayers suggests that an equal amount of CdTe was adsorbed after each dipping cycle, which resulted in the buildup of a homogenous film. The binding energies of elements (Cd and Te) in multilayered CdTe/PSS film shifted from those of the CdTe nanoparticles in the pure state. This result indicates that the interfacial electron densities were redistributed by the strong electrostatic interaction between the oppositely-charged CdTe and PSS. Electrochemical properties of the multilayered CdTe/PSS films were studied in detail by cyclic voltammetry (CV).

ZnO 나노선과 CdTe 나노입자를 이용한 NFGM 소자의 전기적 특성 (Electrical characteristics of ZnO nanowire - CdTe nanoparticle nano floating gate memory device)

  • 윤창준;염동혁;강정민;정동영;김미현;고의관;구상모;김상식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.136-137
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    • 2007
  • In this study, a single ZnO nanowire - CdTe nanoparticle nano floating gate memory (NFGM) device is successfully fabricated and characterized their memory effects by comparison of electrical characteristics of ZnO nanowire-based field effect transistor (FET) devices with CdTe nanoparticles embedded in the $Al_2O_3$ gate materials and without the CdTe nanoparticles.

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전기방사법을 이용한 CdTe-Polymer의 합성과 전기 광학적 특성 (Optoelectronic characteristics of CdTe nanoparticles embedded in electrospun polymer nanofibers)

  • 김미현;조경아;김상식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1323-1324
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    • 2007
  • 전기방사법을 이용하여 PVK-CdTe 용액으로 하이브리드 나노파이버를 제조하였다. 하이브리드 나노파이버 형상은 광학현미경과 Scanning Electron Microscope으로 관찰되었으며, 직경은 $300nm\;{\sim}\;30{\mu}m$이고, 길이는 $500\;{\mu}m$이상 이였다. PVK-CdTe 하이브리드 나노파이버의 Photoluminescence 측정을 통하여 하이브리드 나노파이버내에 나노입자특성을 유지한 CdTe 나노입자의 존재를 확인하였으며, 대기와 진공 중에서의 I-V 측정을 통해 진공 상태에서보다 대기상태에서 약 2배 정도 전류가 증가한다는 것을 알았다.

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체온 이용이 가능한 나노입자 박막 열전소자의 플랫폼 개발연구 (Design of the Platform for a Nanoparticle thin Film Thermoelectric Device transforming Body Heat into Electricity)

  • 양승건;조경아;최진용;김상식
    • 전기전자학회논문지
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    • 제20권2호
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    • pp.174-176
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    • 2016
  • 본 연구에서는 HgTe 나노입자 박막 수평열전 플랫폼에 via를 형성하여 나노입자 박막 양단의 온도 차이를 극대화하였다. HgTe 나노입자 박막은 p-type의 열전 특성을 보였으며, HgTe 나노입자 박막 수평열전소자에서 제백계수는 $290{\mu}V/K$이였다. 또한 피부 위의 via 열전 플랫폼을 통해서 향후 차세대 웨어러블 전자 소자의 구현 가능성을 확인하였다.

나노 분말을 Spark Plasma 소결해 제조한 PbTe의 열전 특성 (Thermoelectric Properties of PbTe Prepared by Spark Plasma Sintering of Nano Powders)

  • 전은영;김호영;김참;오경식;정태주
    • 한국분말재료학회지
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    • 제25권5호
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    • pp.384-389
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    • 2018
  • Nanoparticles of PbTe are prepared via chemical reaction of the equimolar aqueous solutions of $Pb(CH_3COO)_2$ and Te at $120^{\circ}C$. The size of the obtained particles is 100 nm after calcination in a hydrogen atmosphere. Dense specimens for the thermoelectric characterization are produced by spark plasma sintering of prepared powders at $400^{\circ}C$ to $500^{\circ}C$ under 80 MPa for 5 min. The relative densities of the prepared specimens reach approximately 97% and are identified as cubic based on X-ray diffraction analyses. The thermoelectric properties are evaluated between $100^{\circ}C$ and $300^{\circ}C$ via electrical conductivity, Seebeck coefficient, and thermal conductivity. Compared with PbTe ingot, the reduction of the thermal conductivities by more than 30% is verified via phonon scattering at the grain boundaries, which thus contributes to the increase in the figure of merit.

CdTe/CdHgTe 코어쉘 나노입자를 이용한 P채널 전계효과박막트렌지스터의 전기적특성 (Electrical characteristics of Field Effect Thin Film Transistors with p-channels of CdTe/CdHgTe Core-Shell Nanocrystals)

  • 김동원;조경아;김현석;김상식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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    • pp.1341-1342
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    • 2006
  • Electrical characteristics of field-effect thin film transistors (TFTs) with p-channels of CdTe/CdHgTe core-shell nanocrystals are investigated in this paper. For the fabrication of bottom- and top-gate TFTs, CdTe/CrHgTe nanocrystals synthesized by colloidal method are first dispersed on oxidized p+ Si substrates by spin-coating, the dispersed nanoparticles are sintered at $150^{\circ}C$ to form the channels for the TFTs, and $Al_{2}O_{3}$ layers are deposited on the channels. A representative bottom-gate field-effect TFT with a bottom-gate $SiO_2$ layer exhibits a mobility of $0.21cm^2$/ Vs and an Ion/Ioff ratio of $1.5{\times}10^2$ and a representative top-gate field-effect TFT with a top-gate $Al_{2}O_{3}$ layer provides a field-effect mobility of $0.026cm^2$/ Vs and an Ion/Ioff ratio of $2.5{\times}10^2$. $Al_{2}O_{3}$ was deposited for passivation of CdTe/CdHgTe core-shell nanocrystal layer, resulting in enhanced hole mobility, Ior/Ioff ratio by 0.25, $3{\times}10^3$, respectively. The CdTe/CdHgTe nanocrystal-based TFTs with bottom- and top gate geometries are compared in this paper.

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콜로이드 합성법에 의한 HgTe 양자점의 제조와 특성 분석 (Colloidal synthesis of IR-Iuminescent HgTe quantum dots)

  • 송현우;조경아;김현석;김상식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.31-34
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    • 2002
  • HgTe quantum dots were synthesized in aqueous solution at room temperature by colloidal method. The synthesized materials were identified to be zincblende cubic structured HgTe quantum dots by X-ray diffraction and transmission electron microscopy image revealed that these quantum dots are agglomerate of a individual particle. The colloidally prepared HgTe quantum dots have the sphere-like shape with a diameter of approximately 4 nm. The optical properties of the HgTe quantum dots were investigated with photoluminescence(PL). The PL appears in the near-infrared region, which represent a dramatic shift from bulk HgTe behavior. The analytic results revealed that HgTe quantum dots have the broad size distribution, as PL emission spectrum covers the spectral region from 900 to 1400 nm. In this study, the factors affecting PL of HgTe quantum dots and particle size distributiont are described.會Ā᐀䁇?⨀젲岒Ā㰀會Ā㰀顇?⨀끩Ā㈀會Ā㈀?⨀䡪ఀĀ᐀會Ā᐀䡈?⨀Ā᐀會Ā᐀ꁈ?⨀硫ᜀĀ저會Ā저?⨀샟ගऀĀ저會Ā저偉?⨀栰岒ఀĀ저會Ā저ꡉ?⨀1岒Ā저會Ā저J?⨀惝ග؀Ā؀會Ā؀塊?⨀ග嘀Ā切會Ā切끊?⨀⣟ගĀ搀會Ā搀ࡋ?⨀큭킢Ā저會Ā저恋?⨀桮킢Ā저會Ā저롋?⨀⣅沥ࠀĀࠀ會Āࠀ၌?⨀샅沥Ā저會Ā저桌?⨀壆沥ሀĀ저會Ā저쁌?⨀o킢瀀ꀏ會Āᡍ?⨀棤좗ĀĀĀ會ĀĀ灍?⨀å좗ĀĀĀ會ĀĀ졍?⨀飥좗ĀĀĀ會ĀĀ⁎?⨀?ꆟᤀ

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칼코제나이드 나노입자와 유리섬유를 이용하여 제작된 열전모듈의 발전 특성 (Thermoelectric Characteristics of a Thermoelectric Module Consisting of Chalcogenide Nanoparticles and Glass Fibers)

  • 류호현;조경아;최진용;김상식
    • 한국전기전자재료학회논문지
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    • 제28권4호
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    • pp.257-261
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    • 2015
  • In this study, we fabricated a thermoelectric module made of nanoparticles (NPs) and glass fibers investigated its thermoelectric characteristics. P-type HgTe and n-type HgSe NPs synthesized by colloidal method were used as thermoelectric materials and glass fibers were used as spacers between the hot and cold electrodes of the thermoelectric module. In the module, the average Seebeck coefficients of the HgTe and HgSe NPs were 1260 and $-628{\mu}V/K$, respectively. The p-n module generated about a voltage of 11.9 mV and showed a power density of $1.6{\times}10^{-5}{\mu}W/cm^2$ at a temperature difference of 7.5 K.

CdTe QDs 용액 안정성의 장시간 유지지속을 위한 TGA(thioglycolic acid)의 첨가효과 (Influence of Raito of TGA(thioglycolic acid) on CdTe QDs Solution Stability for a Period of Time)

  • 김종환;김태희;구동건;기경범;최원규;한경석;류봉기
    • 한국재료학회지
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    • 제22권9호
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    • pp.465-469
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    • 2012
  • This paper focuses on the after synthesis of CdTe quantum dots(QDs) in aqueous solution. CdTe nanoparticles were prepared in aqueous solution using mercaptocarboxylic acid or thioglycolic acid(TGA) as stabilizing agents. QDs emit light smaller than the nano size. The contents of the mercaptocarboxylic acid, and a kind of raw material, were revealed for a period of time. We succeeded in synthesizing a very high quality QDs solution; we discussed how to make QDs better and to keep them stabilized. TGA is known as one of the best stabilizing agents. Many papers have mentioned that TGA is a good stabilizing agent. We dramatically confirmed the state of QDs after the experiments. The QDs solution can be influenced by several factors. Different content of TGA can influence the stability of the CdTe solution. Most papers deal with the synthesis of CdTe, so we decided to discuss the after synthesis process for the stability of the CdTe solution.