• Textile Coloration and Finishing
• /
• v.26 no.3
• /
• pp.165-172
• /
• 2014

Novel super hydrophobic orange dyes having maximum absorption band at 450-500nm were synthesized to dye polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers, using 4-alkylanilines and ${\beta}$-naphthol. Their absorption spectra at visible range showed almost the same, which meant that the alkyl substituents introduced to chromophore did not affect on color appearance of the dyes. Considering both color strength and wash fastness, the decyl-substituted dye was determined as the optimum one practically. From the dyeing results at various conditions, the optimum dyeing was $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was also acceptable giving rating 3-4 for polypropylene fibers and rating 3 for ultra high molecular weight polyethylene fibers.

• Textile Coloration and Finishing
• /
• v.28 no.3
• /
• pp.156-163
• /
• 2016

The 6 novel super hydrophobic bluish-green dyes, showing the maximum absorption at 600~650nm, were synthesized to dye polyolefin fibers such as polypropylene and high strength polyethylene fibers. Their absorption spectra appeared almost the same at visible range, which meant the length of alkyl substituents did not affect on color appearance of the dyes. The optimum length of alkyl group was determined as hexyl substituents from the practical point of view. From the dyeing results, the optimum dyeing condition was $130^{\circ}C$ for 1 hour. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was obtained also good rating 4 for both fibers.

• Proceedings of the IEEK Conference
• /
• 2002.06a
• /
• pp.423-426
• /
• 2002

Undoped-GaN thin film is deposited on Sapphire substrate by MOCVD. SAW velocity is measured with tile center frequency by HP8753C. Center frequency is 266.52 MHz and SAW velocity is 5330㎧ when wavelength was 20 Um. insertion loss, Q factor and side love attenuation is 41.265 dB, 257.41 and over 23 dB. k'i is calculated from tile measured data. k2'is from 1 % to 4 %. TCF is -61.817pp/m/$^{\circ}C$.

• Textile Coloration and Finishing
• /
• v.25 no.3
• /
• pp.159-164
• /
• 2013

Pyrene based molecule has been synthesized through the reaction of pyrene-1-carboxaldehyde and 4- phenylthiosemicarbazide in this research. The pyrene based molecule showed specific optical properties such as absorption and emission changes after mixing with fluoride in DMSO. The phenomenon is induced by the interaction of the molecule and fluoride. This interaction may affect to electron distributions and potential energy levels. In this regard, synthesized pyrene based molecule has been investigated for its electron distributions and HOMO/LUMO energy levels depending on interaction with fluoride. The absorption measurement, cyclicvoltammograms and computational method were investigated to calculate and compare energy potential levels.

• Textile Coloration and Finishing
• /
• v.25 no.3
• /
• pp.215-222
• /
• 2013

The purpose of this study is to minimize fading fabrics of surgical gown by repeated severe laundering and sterilization condition. The study showed that the best conditions were reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions. In these conditions, color difference values(dE) were below 1.0 that means unrecognizable color change by repeated laundering and sterilization. If it treated with only laundering, reduction cleaning conditions may adjust over $80^{\circ}C$ alkaline solution. In conclusion, it is needed to select the high-washing fastness dye and reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions for removal unfixed dyes.

• Textile Coloration and Finishing
• /
• v.25 no.3
• /
• pp.165-171
• /
• 2013

A new monoazo violet dye optimized for polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers was synthesized and its dyeability was investigated. Two hexyl groups were introduced to coupler, 2,5-dimethoxyaniline, in order to increase hydrophobicity of the dye. The maximum absorption wavelength was appeared at 580nm, which meant that the dye showed violet color. From the dyeing results at various conditions, the optimum dyeing was determined as $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing at least 4 for both fibers. Light fastness was acceptable for polypropylene fibers giving ratings 3~4. However, relatively poor light fastness was obtained in case of ultra high molecular weight polyethylene fibers showing ratings 2.

• Textile Coloration and Finishing
• /
• v.32 no.3
• /
• pp.128-134
• /
• 2020

Heat and flame protecting cloth is usually made of meta aramid fiber because of its own properties. But the high inter molecular hydrogen bonding and high Tg is the reason of the difficulty to dye meta aramid fiber. Recently, it was commercialized that the easily dyeable meta aramid fiber(AMD) for improving dyeability. In this study, the dyeing properties of AMD dyed with cationic dyes were investigated. The K/S values of AMD were 5~10% higher than these of general meta aramid fiber(AM) in the case of 1%owf caused by the lower crystallinity of AMD. The difference between K/S values of AMD and AM was increased as increasing dyeing concentration. The washing and rubbing fastness grade of AM and AMD were similar and good to very good.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.371-371
• /
• 2010

탄소나노튜브(CNT)는 기계적인 특성이 뛰어나며, 화학적으로 안정하고, 전기적으로 도체 및 반도체성을 가지고 있을 뿐만이 아니라 직경이 최소 1nm 수준으로 종횡비 및 비표면적이 매우 큰 특성을 가지고 있다. CNT는 투명전극, 유연성 디스플레이, 전자종이 분야 등 투명 전극 응용 분야에서 ITO 대체 신소재로 각광을 받고 있다. 본 발표에서는 SWCNT 전도막의 특성을 향상시키기 위해 PET 기판에 다양한 전처리 방법을 적용하여 SWCNT의 부착력 및 접착력, 투명전극의 면저항, 투과도 및 균일도 향상을 통해 SWCNT 투명전극 특성향상 연구를 진행했다. 접촉각과 표면에너지 제어를 통한 박막특성과의 상관관계 분석, 전처리 방법에 따른 표면에너지 및 제타포텐셜 변화와 박막특성과의 관계를 규명, Roughness 조절을 통한 기판의 면저항과 투과도 향상, 플라즈마 및 polymer 처리를 통해 물리적, 화학적 기판 전처리에 따른 SWCNT 투명전극 특성 향상을 목적으로 실험을 진행했다. 플라즈마 처리 후 polymer 처리된 박막에서는 친,소수 작용기 양의 변화에 따른 상관관계를 보이지 않았지만, 플리즈마 처리 후 친,소수 작용기 양과 Roughness 변화정도에 대해서는 면저항과 투과도의 변화를 보였다.

• Journal of the Korean institute of surface engineering
• /
• v.49 no.4
• /
• pp.323-330
• /
• 2016

The flexible transparent conducting films (TCFs) are required to realize flexible optoelectronic devices. 1D nanomaterials such as carbon nanotubes (CNTs), metal nanowires are good candidates to replace indium tin oxide that is currently used to fabricate transparent electrode. Particularly, silver nanowires are used to produce flexible TCFs. In this review, we introduce TCF technologies based on silver nanowires/CNTs hybrid structures. CNTs can compromise drawbacks of silver nanowires for applications in high performance TCFs for optoelectronic devices.

• Textile Coloration and Finishing
• /
• v.30 no.4
• /
• pp.264-274
• /
• 2018

Immobilization of lysozyme on chitosan non-woven using glutaraldehyde(GA) was investigated. For this, 100 % chitosan non-woven was prepared as novel support for the enzyme immobilization. In addition, free lysozyme activity was examined depending on various pH and temperature by measuring time. Moreover, the optimum immobilization conditions depending on various pH, temperature, immobilization time and lysozyme concentration was evaluated. In addition, thermal stability and storage stability of immobilized lysozyme were measured. The characteristics of immobilized lysozyme was examined by FT-IR, surface morphology, and MTT assay. The results are follows: the optimal immobilization of lysozyme were pH 7.0, $25^{\circ}C$, lysozyme concentration 1.5 mg/ml, immobilization time 240 min. The immobilized lysozyme showed higher thermal stability than the free trypsin. The immobilized lysozyme activity was retained 80 % of its initial activity at $4^{\circ}C$ over 30 days of storage. The lysozyme was immobilized effectively on chitosan non-woven by observation of surface morphology.