• Title/Summary/Keyword: Tannery waste water

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Speciation of Cr(III)/Cr(VI) in Tannery Waste Waters by Using Ion-Exchange Resins

  • Kartal, S.;Tokalloglu, S.;Ozkan, B.
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.694-698
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    • 2006
  • A method has been described for the chemical speciation, preconcentration and determination of Cr(III) and Cr(VI) species in filtered tannery waste waters by flame atomic absorption spectrometry using ion-exchange resins. Amberlite IR-120($H^+$) strongly acidic cation exchanger and Amberlite IRA-410($CI ^-$) strongly basic anion exchanger resins were used for the separation and preconcentration of Cr(III) and Cr(VI) species, respectively. Optimum condition for preconcentration and speciation was obtained by testing pH of sample and eluent, flow rates of sample and eluent, amount of resins, volume of sample and eluents, and effect of foreign ions. The recommended method has been successfully applied for the preconcentration and determination of chromium species in the dissolved phase of waste water samples collected from a tannery waste water treatment plant in Kayseri, Turkey. The detection limits achieved were 0.73 $\mu$g/L for Cr(III) and 0.81 $\mu$g/L for Cr(VI). Recovery studies showed 99% for Cr(III) and 98% for Cr(VI), for samples spiked with single species.

The Effect of Cement Admixtures on Solidification of Tannery Sludge based Cement Method (피혁슬러지 고형화시 시멘트 혼화제의 영향)

  • 주소영;박상찬;전태성;손종렬;김태영
    • Journal of environmental and Sanitary engineering
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    • v.18 no.4
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    • pp.36-44
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    • 2003
  • The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

Effect of Sulfate and Heavy Metals on Methanogenic Activation of in the Anaerobic Digestion of Tannery Wastes (피혁폐수의 혐기성 소화시 황산염과 중금속이 메탄균 활성에 미치는 영향)

  • Shin, Hang Sik;Oh, Sae Eun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.1
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    • pp.13-21
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    • 1996
  • For treating tannery wastewater containing high sulfate and heavy metals, test was performed to assess their performance, competition between SRB (sulfate reducing bacteria) and MPB (methane producing bacteria), and the activity of MPB according to change of chromium concentrations. COD removal efficiency was above 70% at VLR (volumetric loading rate) of 2.0 gCOD/I.day and HRT (hydraulic retention time) of 18hrs at $35^{\circ}C$. In the competition between SRB and MPB, about 15% of the removed COD was utilized by SRB in the begining, but it became 43% at the end. It indicated that MPB was strongly suppressed by the occurrence of significant sulfate reduction since a large electron flow was uptaken by SRB. For the entire experiment, removal efficiencies of chromium concentration were more than 90%. Despite high removal efficiencies of chromium concentration, performance of reactor did not change significantly during the experimental periods. Expecially, chromium (III) is tannery wastewater is less toxic than chromium (VI).

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Removal of chromium from tannery wastewater by electrosorption on carbon prepared from peach stones: effect of applied potential

  • Ziati, Mounir;Khemmari, Fariza;Kecir, Mohamed;Hazourli, Sabir
    • Carbon letters
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    • v.21
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    • pp.81-85
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    • 2017
  • The objective of this study is the removal of chromium from tannery wastewater by electrosorption on carbon prepared from lignocellulosic natural residue "peach stones' thermally treated. The followed steps for obtaining coal in chronological order were: cleaning, drying, crushing and finally its carbonization at $900^{\circ}C$. The characterization of the carbon material resulted in properties comparable to those of many coals industrially manufactured. The study of the dynamic adsorption of chromium on the obtained material resulted in a low removal rate (33.7%) without applied potential. The application of negative potentials of -0.7 V and -1.4 increases the adsorption of chromium up to 90% and 96% respectively. Whereas a positive potential of +1.4V allows desorption of the contaminant of 138%.

A Study on the Biodiesel Production Technology using Lard Oil (동물성 유지를 이용한 Biodiesel 생산기술에 관한 연구)

  • Shin, Soo-Beom;Min, Byung-Wook;Yang, Seung-Hun;Park, Min-Seok;Kim, Hae-Sung;Paek, Doo-Hyeon
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.19-25
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    • 2006
  • Flesh wasters from tannery create major environmental problems. Despite their considerable fat content, these waster do not find important usage. Their disposal is also troublesome and costly. We have investigated the possible use of this fat as the production of biodiesel(fatty acid methyl esters) by transesterification using with fossil fuels. The fat released the waste by boiling water under the optimal condition (i.e., temperature, $120^{\circ}C;$ decompression, 200mbar) and used to dry without refining for the production of fatty acid methyl esters. Under the optimal condition, the experimental value of biodiesel yield was about 96%. The result of the chemical and GC analysis showed fatty acid composition and characteristics of biodiesel. Evaluation of the product indicated that it was suitable for use as a biodiesel fuel. In result of this experiment oil extract from fleshing process can be transformed into an environmentally affination fuel, to provide economical and ecological profits.

Study on The Application Case of Clean Technology of Leather Manufacture through technical transfer of chrome reduced tanning process (청정 피혁 생산을 위한 저크롬 탄닝 공정 기술 보급에 관한 사례 연구)

  • Kim, W.J.;Kim, H.H.;Lee, S.C.;Park, K.S.;Heo, J.S.
    • Clean Technology
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    • v.10 no.1
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    • pp.27-35
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    • 2004
  • Domestic leather company is working hard to solve present environmental problem. Leather industry is realized by representative pollution industry. An advanced nation is trying to develop clean technology by collaborating research institute with the chemical company, and tannery. This research introduced information that is gained through technical transfer in leather processing. This project started to solve environmental problem of leather industry. Specially the environment and economic problem is caused from chrome which exists in the waste water or solid waste. Representative technologies, reduced chrome tanning, non-chrome tanning method, are being introduced through transfer. Also lightweight leather development advances the research which uses non-metal tanning agent.

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A Study on the Utilization of Industrial Solid Organic Wastes (I). The Physical and Chemical Characteristics of Industrial Solid Wastes with Regard to Fertilizer Value and Humus Sources (산업 고형유기폐물의 자원화에 관한 연구 (제1보) 산업 고형유기폐물의 비료와 Humus 원으로서의 물리적 및 화학적 특성에 관하여)

  • Park Nae Joung;Kim, Yong In
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.258-268
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    • 1975
  • The physical and chemical characteristics of solid organic wastes from paper and pulp industries, tanneries, and food processing industries were studied with regard to fertilizer value as well as humus sources as a rational method of waste utilization. The pulp and paper mill wastes containing low mineral nutrients but high lignin may be utilized for soil amendments through humus preparation. Chemical treatment sludges of tannery wast water contained appreciable fertilizer nutrients andiliming materials, but utilization as fertilizers or soil amendments depends on the pollution effect of high chromium content, which has not been well understood. Food processing wastes may be utilized as organic fertilizers or micronutrient sources for plant. Some wastes containing high water-soluble sugars or lower C/N ratio than 20 may be utilized as additives for rapid humus preparation.

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