• 제목/요약/키워드: TSP (total suspended particles)

검색결과 47건 처리시간 0.019초

大氣浮遊粉塵中 多環芳香族炭火水素 및 重金屬의 濃度 (Atmospheric Concentration of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Suspended Particulate)

  • 손동헌;권창호;정원태;허문영
    • 한국대기환경학회지
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    • 제7권1호
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    • pp.17-22
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    • 1991
  • Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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대기 부유 분진 중 미량유해물질들의 통계적 오염 해석 (Statistical Analysis on Pollutants of Total Suspended Particulates in the Ambient Air)

  • 허문영;유기선;김경호;손동헌
    • 한국대기환경학회지
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    • 제6권2호
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    • pp.155-160
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    • 1990
  • During the period from Mar. 1985 to Feb. 1988, airborne particulate matters were collected and size fractionated by the ANdersen high volume air sampler in Seoul. The concentrations of several heavy metals (Pb, Cu, Zn, Fe, Mn) and benzo(a)pyrene were determined to investigate the size distributions and seasonal variations. And with respect to seven components in the total suspended particulate (TSP), the factor analysis was performed for three groups such as the coarse particles (> 2 $\mu$m), fine particles (< $\mu$m) and TSP. As a result of factor analysis by using the varimax method, the chemical components in the TSP were able to characterize with two principal factors. The first factor, F1 was considered to be a factor indicating the contribution of natural sources and the second factor, F2 was a factor indicating the degree of artificial sources. Each components in the TSP was divided into two main groups of components originated from soil and/or road dust and pollutants originated from automobiles and/or human work.

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육용계사내 부유먼지의 입도 분포에 관한 연구 (A Study on the Size Distribution of Suspended Particulate in Broiler Houses)

  • 김종오;용준환
    • 한국가금학회지
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    • 제20권1호
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    • pp.11-15
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    • 1993
  • Environmental measurements were made in 10 broiler confinement houses in order to characterize dust contaminants. Particles were collected by filters on nine stages Anderson Air Sampler, The obtained results were summarized as follows ; 1. The concentrations of the total suspended particles(TSP) were 7.584 mg/$m_3$~11.589mg/$m_3$ in 10 day old broiler houses and 15.836 mg/$m_3$~22.471 mg/$m_3$ in 30 day old broiler houses. 2. The concentrations of the coarse particles were 4.974 mg/$m_3$~18.981 mg/$m_3$ in 10 broiler confinement houses. Therefore, it was found that the coarse particles contributed to TSP between 65.6% and 85.0%. 3. The dust levels were higher in 30 day old broiler houses with TSP averaging about 19.341 mg/$m_3$ than 9.491 mg/$m_3$ in 10 day old broiler houses. In view of the above results , It was concluded that domestic broiler houses need artificial ventilation system.

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도시대기부유분진중 다환방향족 탄화수소의 농도 및 입경분포 특성 (Characteristics of Concentration and Size Distribution of PAHs of Total Suspended Particulates in urban air)

  • 조기철;이승일;김달호;허귀석;김희강
    • 한국대기환경학회지
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    • 제10권1호
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    • pp.57-63
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    • 1994
  • In order to comprehension of the behaviour of PAHs in air which is known as carcinogens and/or mutagens suspended Particulates in ambient air were collected by Anderson air sampler from 1992. 6 to 1993. 5 in Seoul. Ten species of PAHs( Phen, An, Fl, R, Py, BaAn, BaP, Chry, BeP, DiB(a, h)An, I123p) were analyzed to understand monthly variations of PAHs distribution of PAHs concentration according to particle size, and correlation between PAHs and independent charactierstics of PAHs The highest concentration of TSP was 155.58$\mu\textrm{g}$/㎥ in May and the lowest was 60$\mu\textrm{g}$/㎥ in August. Concentration of TSP was more affected by coarse particles in spring, otherwise which was more affected by fine particles in winter. According to results of anaylsis of samples that were collected by Anderson air sampler, concentration of PAHs was more high in winter than that in summer. In almost samples collected by Anderson air sampler, concentration of PAHs was more high in coarse particles than in fine particles, but BaP well known as carcinogenic matter had more high concentration in fine particles(56-97.5%) than that in coarse particles(2.5-46%). Correlation between concentrations of TSP and PAHs was more high in fine Particles than in coarse Particles. Both fine particles and coarse particles have negative correaltion with radiation.

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도시대기중 호흡성 먼지의 이온성분 거동 특성 (Characteristics of Ion Compositions of the Respirable Particles in Seoul)

  • 신은상;강병욱
    • 환경위생공학
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    • 제9권2호
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    • pp.24-31
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    • 1994
  • Aerosol size distribution were determined in Seoul by Anderson sampler from October 1989 to September 1991 for the major ionic species(SO$_{4}$$^{2-}$, NO$_{3}$$^{-}$, Cl$^{-}$, Na$^{+}$, Na$^{+}$, K$^{+}$, Ca$^{2+}$ and Mg$^{2+}$) and TSP( Total Suspended Particles ). The seasonal variations in concentrations and size distribution have been investigated. The size distributions of TSP and each of ionic species were bimodal throughout the year. The size distribution of these ions were divided as follows; (1) fine- mode dominant for SO$_{4}$$^{2-}$ and N%'. (2) coarse- mode dominant for NO$_{3}$$^{-}$, Cl$^{-}$, Ca$^{2+}$ and Mg$^{2+}$. (3) both- mode dominant for TSP.

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대기(大氣) 중 Benzopyrene 및 중금속(重金屬)의 농도(濃度)와 입경분포(粒徑分布) (Atmospheric Concentration and Size Distribution of Airborne Particulates, Benzopyrene and Heavy Metals)

  • 허문영;권창호;유기선;최성규;권창호;김경호;손동헌
    • 약학회지
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    • 제34권1호
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    • pp.1-10
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    • 1990
  • Total suspended particulate (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for the past two years (Mar. 1987-Feb. 1989) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulate was $229.48\;{\mu}g/m^3$. The concentrations of heavy metals were $2971.94\;ng/m^3$ for Fe, $767.75\;ng/m^3$ for Zn, $765.80\;ng/m^3$ for Pb, $218.40\;ng/m^3$ for Cu, $129.91\;ng/m^3$ for Mn, respectively. And the concentration of PAHs were $3.23\;ng/m^3$ for benzo(a)pyrene, $2.71\;ng/m^3$ for benzo(k)fluoranthene, $4.53\;ng/m^3$ for benzo(ghi)perylene, respectively. The mass-size distribution of TSP was lowest in the particle size range $1.1-3.3\;{\mu}m$ increased as the particle size increased or decreased. But PAHs, Pb and Zn abounded in particles below $2.0\;{\mu}m$, while Fe and Mn abouned in particles above $2.0\;{\mu}m$. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic origin like TSP, PAH and heavy metals in the fine particles were highest in winter and lowest in summer. PAH and Ph analyzed showed significant correlations with each other and with TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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익산시의 부유먼지에 관한 연구 (Studies on the Total Suspended Particulates in Iksan City.)

  • 전병영
    • 환경위생공학
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    • 제14권4호
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    • pp.158-164
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    • 1999
  • This study was carried out to investigate total suspended particulates (TSP) in Iksan area collected by nine stages Anderson air sampler and High volume air sampler from Jul. 1996 to Jul. 1998.The results are as follows1. The average of TSP concentration to be collected by Anderson air sampler and High volume air sampler in Iksan city are $59{\mu}g/m^3$, $67{\mu}g/m^3$. It was below the level of environmental standard. 2. The average of TSP concentration by measured method are HVAS > AS > Gov. 3. The average of TSP concentration on seasonal change are higher spring than winter. It were $65.5{\mu}g/m^3$ of Spring, $57{\mu}g/m^3$ of Summer, $52.5{\mu}g/m^3$ of Fall, $61{\mu}g/m^3$ of Winter. 4. Particle size 3istribution of atmospheric particulate was divided into two groups, coarse group was made by particles larger than $1.1-2.1{\mu}m$ in diameter and fine groups smaller than $1.1-2.1{\mu}m$ in diameter. about 50% of total suspended particle measured by Anderson air sampler during the sampling period was coarse particle.

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도시 대기 부유분진 중 음이온의 농도 (Concentrations of Anions in Airbone Particulate Matters in Metropolitan Area)

  • 손동헌;신경순
    • 약학회지
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    • 제34권3호
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    • pp.206-211
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    • 1990
  • Total suspended particles were collected and size-fractionated by an Andersen high-volume air sampler at Chungang University located near the Han River, Seoul, Korea, during the period form March, 1986 to August, 1986 and from March, 1987 to February, 1988. The concentrations and the particle size distributions of anions such as chloride, nitrate and sulfate were determined by ion chromatography. The averages of concentrations were $125.43\;{\mu}g/m^3$ in 1986 and $189.19\;{\mu}g/m^3$ in 1987 for total suspended particles (TSP), $2.12\;{\mu}g/m^3$ in 1986 and $4.14\;{\mu}g/m^3$ in 1987 for chloride, $4.39\;{\mu}g/m^3$ in 1986 and $5.95\;{\mu}g/m^3$ in 1987 for nitrate and $11.98\;{\mu}g/m^3$ in 1986 and $19.29\;{\mu}g/m^3$ in 1987 for sulfate. Size distribution of TSP was found to be generally bimodal. Chloride exhibited a seasonal variation in the distribution; fine particles were predominant in the winter whereas the concentration of coarse ones was almost same through four seasons. Nitrate showed a distribution similar to that of chloride. Such variation was less significant for sulfate. For chloride and nitrate, the relationship between the monthly averaged distribution pattern and air temperature was analyzed in terms of fine fraction (FF). The FF decreased with increasing air temperature.

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토양 성분이 입자 특성에 미치는 영향: 제주도 고산에서의 1994년 측정결과 모사 (Effects of Crustal Species on Characteristics of Aerosols: Simulation of Measurements at Kosan, Cheju Island, 1994)

  • 김용표;문길주
    • 한국대기환경학회지
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    • 제12권3호
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    • pp.289-296
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    • 1996
  • Effects of crustal species on the characteristics of ambient particles were studied by applying a gas-particle equilibrium model, SCAPE, to the measurements at Kosan, Cheju Island during the spring and summer, 1994. Two cases were simulated; the measured composition was used without any modification (case 1), and the metal ion concentrations originated from crust were subtracted from the measured particle composition (case 2). Total suspended particles (TSPs) were collected by an automatic high volume tape sampler during spring period and by high volume samplers during summer period. The fine particles, PM 2.5, and gaseous volatile species were collected using a filter pack smapler during summer period. The water soluble ion concentrations were analyzed from all the particle samples. According to the simulation results, the effect of crustal elements on the chemical composition of particles is negligible for both TSP particles and PM 2.5 particles. Acidity of particles measured at Kosan, however, is affected by the change of the concentrations of crustal species, stronger effects for TSP particles than for PM 2.5 particles during summer, and stronger effects during summer than spring for TSP particle. The average pH decrease due to the absence of crustal species was about 0.10 for PM 2.5 particle during summer and 1.51 and 0.85 for TSP particles during summer spring, respectively. Water contents of PM 2.5 particles for both cases are comparable to each other. Estimated water content of TSP particles for case 2 is higher than that for case 1 by about 4 $\sim 6 \mum/m^3$ because salts of metal ions are not hygroscopic.

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한라산 1100 고지 총부유분진(TSP)의 조성 및 오염 특성 (Compositions and pollution characteristics of total suspended particles (TSP) at 1100 Site of Mt. Halla)

  • 김원형;강창희;정덕상;고희정;이원
    • 분석과학
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    • 제21권4호
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    • pp.304-315
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    • 2008
  • 한라산 1100 고지에서 채취한 대기 부유분진의 조성은 인위적 기원의 성분들이 가장 높고, 다음으로 해양 기원 성분과 토양 기원 성분들이 높은 함량을 나타내었다. 계절별로는 봄철에 토양 성분인 nss-$Ca^{2+}$, Al, Fe, Ca 성분의 농도가 크게 증가하였고, 인위적 기원의 $NH{_4}^+$, $K^+$, nss-$SO{_4}^{2-}$은 6월에 가장 높은 농도를 보였다. 반면에 $NO{_3}^-$은 봄철에 nss-$Ca^{2+}$과 함께 농도가 상승하였고, 이는 중국으로부터 장거리 이동에 의한 영향으로 추정된다. 황사와 비황사 때의 농도를 비교해 본 결과, 황사 때에 nss-$Ca^{2+}$, Al, Ca, Fe 농도가 7.2~9.5배 증가하였고, nss-$SO{_4}^{2-}$$NO{_3}^-$은 각각 1.3, 3.8배 정도 더 증가한 것으로 확인되었다. 요인분석법으로 분진성분의 발생기원을 조사해 본 결과, 한라산 1100 고지 부유분진은 토양의 영향을 가장 많이 받고, 다음으로 인위적 영향과 해염 영향을 많이 받고 있는 것으로 추정된다. 역궤적분석에 의해 분진 성분의 유입경로를 조사한 결과, 공기덩어리가 중국대륙을 거쳐 제주지역으로 이동한 북서풍 계열의 풍향일 때 주요 인위적 기원의 성분과 토양 성분의 농도가 상승하고, 공기가 북태평양을 거쳐 제주지역으로 유입되었을 때 이들 성분들의 농도가 상대적으로 감소하는 경향을 보였다.