• Title/Summary/Keyword: TOC(total organic carbon)

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Determination of Total Organic Carbon in Water by Flame Ionization Detector (FID를 이용한 수중의 TOC 분석법)

  • 박만기;한대석;임병연
    • YAKHAK HOEJI
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    • v.22 no.3
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    • pp.157-162
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    • 1978
  • Total organic carbon(TOC) can be determined by means of combustion and flame ionization detector. The principle of string method is that a sample acidified to pH2 and transferred into combustion tube by string is oxidized with air. Another combustion tube method is that organic compounds are oxidized in the combustion tube charged with CuO and cobalt asbestos after the acidified sample is injected directly by microsyringe. Carbon dioxide evolved was reduced under specially treated nickel catalyst and hydrogen, the methane produced was detected by flame ionization detector. Linear relationship was found between concentration and the peak height by the string method. The peak area in the case of combustion tube method is in the range of 1-200ppm. The coefficient of variation by string method was 2.3% and that by combustion tube method was 1.8%. The lower detectable limit was about 10mol. Advantages of the latter are simplicity, sensitivity and reproducibility. TOC in contineous stream can also be determined automatically by means of the string method.

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Correlation analysis between TOC and organic matter indices in influent and effluent of public sewage treatment facilities (공공하수처리시설 유입수 및 방류수에서 TOC와 유기물질 관리지표간의 상관성 분석)

  • Son, Dong-Jin;Jeong, Dong-Hwan;Park, Kyoo-Hong
    • Journal of Convergence for Information Technology
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    • v.11 no.4
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    • pp.122-129
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    • 2021
  • As the total organic carbon (TOC) becomes a new water quality standard as an organic matter (OM) index for public sewage treatment facilities (PSTFs) in Korea from 2021, a comparison study needs to be conducted by examining the correlation between TOC and the existing OM indices (DOC, BOD5, CODMn, CODCr). 500 PSTFs were categorized by process configuration and capacity, and correlation between OM indices in influent and effluent was analyzed. The CODMn/TOC showed higher correlation than other OM indices. This results can be used to basic data for various research associated with TOC.

Application of Discrete Wavelet Transform for Detection of Long- and Short-Term Components in Real-Time TOC Data (실시간 TOC 자료의 장.단기 성분의 검출을 위한 이산형 웨이블렛 변환의 적용)

  • Jin, Young-Hoon;Park, Sung-Chun
    • Journal of Environmental Science International
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    • v.15 no.9
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    • pp.865-870
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    • 2006
  • Recently, Total Organic Carbon (TOC) which can be measured instantly can be used as an organic pollutant index instead of BOD or COD due to the diversity of pollutants and non-degradable problem. The primary purpose of the present study is to reveal the properties of time series data for TOC which have been measured by real-time monitoring in Juam Lake and, in particularly, to understand the long- and short-term characteristics with the extraction of the respective components based on the different return periods. For the purpose, we proposed Discrete Wavelet Transform (DWT) as the methodology. The results from the DWT showed that the different components according to the respective periodicities could be extracted from the time series data for TOC and the variation of each component with respect to time could emerge from the return periods and the respective energy ratios of the decomposed components against the raw data.

Holocene Variations of Organic Carbon Contents in Lake Langer of King George Island, South Shetland Islands, West Antarctica

  • Khim, Boo-Keun;Yoon, Ho-Il;Kang, Cheon-Yun;Zhao, Junlin
    • Ocean and Polar Research
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    • v.26 no.3
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    • pp.507-514
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    • 2004
  • A sediment core drilled from Lake langer on King George Island was analyzed for a variety of textural md geochemical properties along with $^{14}C$ age dates. These data were combined with published records of other cores to provide a detailed history of Holocene variation of total organic carbon (TOC) contents with respect to terrestrial paleoclimate change. The lithologic contrast of the lower diamicton and upper fine-grained sediments shows the glacier activity and subsequent lake formation. Low TOC contents fluctuated during the diamicton deposition whereas the increase of TOC began with the lake formation during the postglacial period that started about 5,000 yr B.p More notable are the distinct TOC peaks that may imply enhanced primary productivity during the warm period. The uniform and low TOC contents may reflect the limited productivity during the evolution of the lake. However, the recent TOC readvance clearly indicates gradual warming on King George Island. However, the paleoclimatic signature in the terrestrial lake environment during the Holocene seems to be subtle and less distinct, compared to the marine environment.

Effect of the Total Organic Carbon(TOC) on phosphorus removal by Stapylococcus auricularis (Stapylococcus auricularis에 의한 인 제거에서 총유기탄소의 영향)

  • 최석순
    • Journal of environmental and Sanitary engineering
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    • v.15 no.3
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    • pp.57-61
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    • 2000
  • Stapylococcus auricularis was used for the simultaneous removal of phosphorus and Total Organic Carbon(TOC) in the wastewater from sewage and various industries. In this study, the characteristics of phosphorus removal was investigated with initial ratio of TOC phosphorus in the synthetic wastewater. When the synthetic wastewater containing 15mg/L of phosphorus was treated under anaerobic and conditions, phosphorus was removed completely within 6 hours of operation. And when the initial ratio of TOC to phosphorus was 30, as high as 10 times the removal rate of phosphorus by Acinetobacter calcoaceticus was achieved. These results implied that a long adaptation time, one of the chief problems in biological phosphorus removal process was overcome.

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A Study on the Appropriateness as Organic Matters Indicator and the Distribution of Chemical Oxygen Demand and Total Organic Carbon in Masan Bay, Korea (마산만 해수 중 화학적산소요구량과 총유기탄소 분포 특성 및 유기물 지표로서의 적절성 검토)

  • PARK, MI-OK;LEE, YONG-WOO;CHO, SEONG-AH;KIM, HYE-MI;PARK, JUN-KUN;KIM, SUNG-GIL;KIM, SEONG-SOO;LEE, SUK MO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.2
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    • pp.82-95
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    • 2021
  • We investigated the temporal and spatial distribution characteristics of chemical oxygen demand (COD) and total organic carbon (TOC) in all 13 locations of Masan Bay from February to November in 2015. The COD and TOC contents were high during the June-August period when the pollution load increased. In particular, the concentrations of COD and TOC were about twice as high in the surface water as in the bottom water. In spatial distribution, the COD and TOC concentrations at the inner bay were about twice as high as those of the outer bay in Masan Bay. As a result of estimating the oxidation efficiency of COD from the surface layer of Masan Bay in 2015 based on the theoretical oxygen demand (TOD), it was at the level of about 23%. Due to the low oxidation efficiency of COD, there is a risk that the organic matter in Masan Bay will be somewhat underestimated. Therefore, for quantitative analysis of organic matter, COD and TOC analyses need to be combined.

Comparison of Real Time Water Soluble Organic Carbon Measurements by Two PILS-TOC Analyzers (PILS-TOC를 이용한 실시간 대기 중 수용성 유기탄소 비교 측정)

  • Park, Da-Jeong;Kang, Seokwon;Lee, Taehyoung;Shin, Hye-Jung;Shon, Zang-Ho;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.633-641
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    • 2016
  • Two identical Particle Into Liquid Samplers-Total Organic Carbon (PILS-TOC) were operated to measure fine particle Water Soluble Organic Carbon (WSOC) for one week on Feb. in 2016. The dual instrument operations provided validated WSOC concentrations to have a continuous WSOC measurement during the sample analysis period. Both PILS-TOC instruments were operated downstream of an carbon denuder to remove positive adsorption artifacts associated with semi-volatile organic compounds. Comparison of WSOC showed good agreement each other. The linear regression had a coefficient of determination ($r^2$) of 0.92 and a regression slope of 1.01 for the first period. The lower collection efficiency due to lower steam temperature is discussed. In addition, the potential primary source related to WSOC based on the comparison of black carbon (BC) concentrations is explained. The results of good agreement between two PILS-TOC measurements can provide the validation of WSOC cooperations and knowledge regarding the origins of WSOC and their behaviors.

A Study on the Treatment of Secondary Effluent by ${\gamma}-ray$ Irradiation ($\gamma$-선의 조사를 이용한 하수처리장 방류수 처리에 관한 연구)

  • 이면주;정영도;박순달
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.106-114
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    • 1998
  • This study was carried out for the purpose of industrial reuse of effluent released from activated sludge unit by $\gamma $-ray irradiation technique. The dissolved organic carbon in the effluent of an activated sludge unit is mostly refractory or inert material which are difficult to be degraded by micro organism. The effluent generated from activated sludge unit was irradiated with Co$^{60}$ $\gamma $-ray under condition of air bubbling. The effects of irradiation on the pH, COD, TOC, color, molecular weight distribution were investigated by membrane filtration and u.v.-spectrum analysis. With increasing dose, the TOC was decreased smoothly. The COD was increased at lower dose, while the COD was decreased at higher dose. The TOC and COD, however, were decreased smoothly when TiO$_{2}$ was added to the solution. It was thought that the differential decreasing trend of COD and TOC in according to the absence or presence of TiO$_{2}$ was due to the molecular weight distribution shifted from group of higher molecular weight to group of lower one which are more easy to be decomposed. The removal efficiency of color was 71.5% and it was increased to 85.7% when TiO$_{2}$ was added to the solution. The $\gamma $-ray irradiation was effective on the production of chlorine.

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Estimation of Production Unit Loads of Livestock Manure Based on TOC (TOC 기반 가축분뇨 발생 원단위 산정)

  • Lee, Yunhee;Kim, Yongseok;Park, Jihyung;Oa, Seong-Wook
    • Journal of Wetlands Research
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    • v.16 no.3
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    • pp.403-409
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    • 2014
  • Assessment of pollutant loads for livestock manure based on total organic carbon (TOC) is being required to apply TOC as an indicator in management of total maximum daily loads. In this study, TOC based unit loads of pig manure known as highly contributing to water pollution assessed. The concentration of pig manure, amount of manure production including cleaning water, and unit loads were investigated targeting 52 farms according to 4 major river basins, rearing form, farm scale, and piggery form. The manure production was highly generated in scraper type of piggery, in small scaled farm rearing sow, and in Han River basin and Nakdong River basin. The averaged manure production was 7.4 L/head/d in total river basins. Averaged concentrations were investigated as TOC 16,037 mg/L, BOD 10,559 mg/L, TN 4,145 mg/L, and TP 503 mg/L. Corresponding unit loads were assessed as TOC 117.1 g/head/d, BOD 77.1 g/head/d, TN 34.7 g/head/d, and TP 3.67 g/head/d.