• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.83-93
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• 2015

This study investigated genetic, mineralogical and spectral characteristics of oil shale and coal samples in Dundgobi area, Mongolia. Based the Rock/Eval and Total organic carbon (TOC) analysis, kerogen type, hydrogen quantity, thermal maturity and depositional environment were confirmed. Moreover, the mineral composition of oil shale and coal samples were analyzed by XRD and spectroscopy. The result of Rock Eval/TOC analysis revealed that the samples of Eedemt deposit are immature to mature source rocks with sufficient hydrocarbon potential, and the kerogen types were classified as Type I, Type II and Type III kerogen. On the other hand, the samples from Shine Us Khudag deposit were mature with good to very good hydrocarbon potential rocks where kengen types are defined as Type I, Type II/III and Type III kerogen. According to the carbon and sulfur contents, the depositional environment of the both sites were defined as a freshwater depositional environment. The XRD analysis revealed that the mineral composition of oil shale and coal samples were quartz, calcite, dolomite, illite, kaolinite, montmorillonite, anorthoclase, albite, microcline, orthoclase and analcime. The absorption features of oil shale samples were at 1412 nm and 1907 nm by clay minerals and water, 2206 nm by clay minerals of kaolinite and montmorillonite and 2306 nm by dolomite. It is considered that spectral characteristics on organic matter content test must be tested for oil shale exploration using remote sensing techniques.

• Journal of Korean Society on Water Environment
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• v.31 no.3
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• pp.313-318
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• 2015

To study the influence of changes in river discharge on water quality of the main stem of the Geum River, we investigated variation of inflow load from tributaries with river discharge. We also studied the mixing behavior of pollutants during mixing of waters of the main stem and Gap Stream. For this study, we collected water quality data such as suspended solids (SS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) representing pre-monsoon, monsoon, and post-monsoon events of 2013 from a website of Water Information System. Based on inflow load, the Gap and Miho streams may be ones of tributaries which may largely influence water quality of main stem in upper river region. The Suksung and Nonsan Streams seemed to further affect water quality downstream. Results of modified EMMA indicated SS and TP may have another source(besides Gap Stream) at pre-monsoon, monsoon, and post-monsoon period. In contrast, TN and organic matter (BOD, COD, TOC) were conservative at pre-monsoon and post-monsoon. However, when river discharge increased, these pollutants may also came from unspecified non-point sources. Therefore, we need to attempt to find non-point sources for the pollutants in the main channel of upper Geum River region.

• Journal of Korean Society on Water Environment
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• v.28 no.4
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• pp.538-550
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• 2012

This study suggests a general methodology which is designed for assessing RDOC behavior at the catchment scale by coupling properly a series of steam flow and water quality simulation models and actual monitoring data set. The modified TANK model in which a river routing function is incorporated to the conventional one is applied to simulate the long-term daily stream flow data, and the simulated stream flow data is combined with the 7-parameter log-linear model coupled to the minimum variance unbiased estimator to simulate the long-term daily water quality (BOD, COD and TOC) loads. Finally, the regression analysis between the usually monitored water quality data (BOD, COD and TOC) and RDOC is combined with the simulated water quality data to manifest the spatio-temporal variability of RDOC flux behavior at the Korean TMDL catchment scale.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.3
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• pp.151-155
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• 2004

The bioremediation of water system contaminated with phenolic compounds having endocrine-disrupting activity, i.e. 2,4-dichlorophenol, 2,4-dichlorophenoxy acetic acid (2,4-D), and 2,4,5-trichlorophenoxy acetic acid (2,4,5-T), was investigated by using ozone oxidation and activated sludge treatment. Ozone oxidation (ozonation time: 30 min) followed by activated sludge treatment (incubation time: 5 days) was an efficient treatment method for the conversion of phenolic compounds in water into carbon dioxide and decreased the value of total organic carbon (TOC) up to about 10% of initial value. Furthermore, 2,4-D was dissolved in water containing salt, i.e. artificial seawater (ASW), and this water was used as model coastal water contaminated with phenolic compounds. The activated sludge treatment (incubation time: 5 days) could consume significantly organic acids produced from 2,4-D in the model costal water by the ozone oxidation (ozonation time: 30min) and decrease the value of TOC up to about 35% of initial value.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.3
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• pp.83-90
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• 1999

This study was carried out to investigate the characteristics of trihalomethane (THM) formation from chlorination of groundwater in the northeastern area of Cheju Island. Effects of total organic carbon (TOC) and bromide in groundwater on the THM formation were studied. Samples were taken from two regions withe altitude. The concentrations of TOC and bromide in groundwater were higher at the regions of lower altitude, especially at the altitude below 50m. Generally the THM formation in GA region containing a high TOC was higher than that in GB region containing a relatively high bromide. At the altitude below 100m, the formation of total and brominated THM was highest at GB region. The most part of THM formation was brominated THM at GB region. The formation ratio of chloroform and brominated THM was similar to the others. Among the brominated THM, dibromochloromethane and bromoform in GB region were containing high bromide. Bromodichloromethane and dibromochloromethane in GA region were containing low bromide. At the altitude above 200m, chloroform was formed mainly. Comparing the ratio of brominated THM of total THM in Cheju Island with that in other areas, Seoul and Pusan, it can be konwn that the former showing 51.3% was much higher than the latter showing 6.7% and 28.8%, respectively.

• Environmental Engineering Research
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• v.25 no.2
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• pp.186-196
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• 2020

Pillared clays with Zr and Fe/Cu/Zr polycations have been prepared from natural clays found in large deposits of Kazakhstan and assessed as catalysts for the catalytic wet peroxide oxidation (CWPO), using 4-nitrophenol (4-NP) as model compound. The performance of the catalysts was followed by measuring the concentration of 4-NP, H₂O₂ and the total organic carbon (TOC), considering C_4-NP = 5 g L^-1, $C_{H_2O_2}$ = 17.8 g L^-1, C_cat = 2.5 g L^-1, initial pH = 3.0 and T = 50℃. At those selected conditions, the pillared clays showed higher activity than natural clays in the CWPO of 4-NP. The conversion of the model pollutant was complete when Fe/Cu/Zr-PILCs were used, with the TOC removal reaching 78.4% after 24 h with the best Fe/Cu/Zr-PILC. The H₂O₂, 4-NP and TOC time-evolution was well described by a kinetic model based on TOC lumps in three blocks, considering the initial TOC (corresponding to 4-NP), the production of oxidizable intermediates and the formation of refractory products.

• Journal of Korean Society on Water Environment
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• v.23 no.4
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• pp.551-560
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• 2007

The present study analyzed noise reduction and long/short-term components for discharge, TOC concentration, and TOC load data in order to understand the data characteristics better. For the purpose, wavelet transform which can reduce noise from raw data and has flexible resolution in time and frequency domain was applied and the theory of nonlinear dynamics was also used to determine the last decomposition level for wavelet transform. Wavelet function of 'db10' and the 7th level for the last decomposition of wavelet transform were applied for the all data in the present study. Also the results revealed that the energy ratios of approximation components with 187-hour periodicity decomposed from 7th level of wavelet transform were 94.71% (discharge), 99.00% (TOC concentration), and 93.84% (TOC load), respectively. In addition, the energy ratios of detail components showed the range between 1.00% and 6.17%, which were extremely small comparing to the energy ratios of approximation components, therefore, the first and second detail components might be considered as noise components included in the raw data.

• Journal of environmental and Sanitary engineering
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• v.11 no.2
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• pp.1-7
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• 1996

The behavior of total organic carbon (TOC) and phosphate were observed for 15 days with immobilized activated sludge using polyacrylamide (PAA) by sequencing batch reactor (SBR). In the preparation of immobilized sludge by PAA, it was found that suitable acrylamide concentration for actual wastewater treatment was to be 15% through the batch test. When SBR system was operated in the repeated aerobic and anaerobic conditions, TOC removal efficiency was 92%. The uptake rate of phosphate was increased from 1.78 mg-P/g cell/hr on the 5th day of acclimation to 2.5 mg-P/g cell/hr on the 15th day of acclimation. And the total phosphorus content in PAA bead was increased from 40 mg-P/g cell on the 1st day of operation to 55 mg-P/g cell on the 15th day of operation. From this study, lowering the volume of aeration tank was possible when PAA bead was used in wastewater treatment and long operation was also possible without the settler.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.12
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• pp.851-857
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• 2014

Treatability of heavy metals in marine sediments contaminated with mainly organic matter was investigated on the basis of washing technology using oxidizers and surfactants. Sediment samples were collected at N area which expected for remediation project of contaminated marine sediment. For additives, hydrogen peroxide ($H_2O_2$) and Tween-80 were used at oxidizer and nonionic surfactant, respectively. In experiments, sediments was mixed with sea water at the ratio of 1 : 3 than $H_2O_2$ (1 M, 3 M, 4 M, 5 M) and Tween-80 (0.05%) were added. Samples were gathered at following reaction time (10, 20, 30, 40, 50, 60, 70, 80 min and 24 h). Total Organic Carbon (TOC) was 55.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 24 h. Hence total heavy metals were Cu 29.5%, Zn 42.3%, Cd 73.0% and bioavailable heavy metals were Cu 60.0%, Zn 77.7%, Cd 90.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 10 min. The correlations for between bioavailable metals (Cu, Zn, Cd) and TOC were significant (Cu, Zn, Cd; $r^2=0.94$, 0.85, 0.69, respectively).

• Journal of Korean Society of Water and Wastewater
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• v.34 no.6
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• pp.473-480
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• 2020

High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.