• Journal of the Korean Chemical Society
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• 제31권5호
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• pp.375-381
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• 1987

Rates for the aquation of trans-[Cr(tn)$_2Cl_2]^+$ and trans-[Cr(en)(tn)Cl$_2$]^+$ ions in aqueous acidic solution have been measured by spectrophotometric method at various temperatures and pressures. Activation volumes are negative and lie in the limited range -1.7 ∼ -2.9cm$^3$mol$^{-1}$ or the complex ions. Activation entropies and activation compressibility coefficients are small negative values. From the results of thermodynamic parameters, it can be inferred that the aquation of the complex ions proceed through an associative interchange(Ia) mechanism. Furthermore, the information on possible transition state structure and reaction paths can be obtained by considering total stabilization energy of the hypothetical intermediates within the framework of angular overlap model. It is found that the theoretically predicted mechanism is consistent with the experimentally observed results.

• Journal of Korean Society on Water Environment
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• 제26권1호
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• pp.71-80
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• 2010

We studied the nitrogen behavior and budget of Lake Paldang from March to December 2008. The particulate nitrogen (PN) concentrations ranged from 7 to 13% of the total nitrogen concentration (TN) in the stream inflows, the downstream outflow, and the lake water. The nitrate nitrogen ($NO_3-N$) concentration ranged from 67 to 78% of the TN. In the three rivers of Lake Paldang, Gyeongan River (In3 site) had the highest average of the TN, 5.037 mgN/L, but North Han River (In2 site) had the lowest average TN, 1.683 mgN/L. South Han River (In1 site) had the average TN of 2.399 mgN/L. In the dam discharge, TN showed the average 2.063 mgN/L. In the lake water, L4 site (Gyeongan River area) had the highest average TN, 3.781 mgN/L, but L3 site (North Han River) had the lowest average TN, 1.587 mgN/L. Total input of nitrogen loads to Lake Paldang was about 30,875 ton/year in 2008. Inflow rivers contributed 30,643 ton/year (South Han River: 18,111 ton/year (59%), North Han River: 11,333 ton/year (37%), and Gyeongan River: 1,199 ton/year (4%)). The atmospheric deposition had 135 ton/year, the nitrogen release from the bottom sediments had 88 ton/year, and macrophytes had 9 ton/year. Total output of nitrogen loads from Lake Paldang was about 31,256 ton/year. The downstream from dam contributed 29,877 ton/year, and the sediment deposition was 1,379 ton/year.

• Journal of Ecology and Environment
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• 제42권4호
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• pp.163-173
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• 2018

Background: Deforestation and degradation are currently affecting the ecosystem services of forests. Among the ecosystem services affected by deforestation and degradation are the amount of soil organic carbon (SOC) and total nitrogen (TN) stored in forest soils which have greater impacts in global climate change. This study aimed at examining the amount of SOC and TN in the forest fragments which were separated from the continuous tracts of forests of Jibat and Chillimo through fragmentation processes over four decades. Methods: We have sampled soils from 15 forest fragments of Chillimo and Jibat in the central highlands of Ethiopia. The soil samples obtained in two separate soil depths (0-30 and 30-60 cm) were bulked, dried, and sieved for analysis. Results: Our results have shown that the two sites (Jibat and Chillimo forest fragments) differed in their SOC and TN contents. While the values for Jibat were found to be 29.89 Mg/ha of SOC and 2.84 Mg/ha for TN, it was 14. 06 Mg/ha of SOC and 1.40 Mg/ha for TN for Chillimo. When all forest fragment soil samples were bulked together, Jibat site had twice the value of SOC and TN than Chillimo. When disaggregated on the basis of each fragments, there existed differences in SOC (1.86 Mg/ha and 42.15 Mg/ha) and TN (0.24 Mg/ha and 4.23 Mg/ha) values. Among the forest fragments, fragment four ($F_4$) had the highest Relative Soil Improvement Index (RSII) value of 3826.82% and fragment fifteen ($F_{15}$) had the lowest RSII value (726.87%) which indicated that the former had a better quality of soil properties than the latter. Conclusion: SOC and TN differed across sampled fragments and sites. Variations in soil properties are the reflections of inherent soil parent material, aboveground vegetation, human interferences, and other physical factors. Such differences could be very important for identifying intervention measures for restoration and enhancing ecosystem services of those fragments.

• Korean Journal of Veterinary Research
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• 제58권4호
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• pp.211-217
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• 2018

Mesenchymal stem cells (MSCs) are useful candidates for tissue engineering and cell therapy. Physiological cell environment not only connects cells to each other, but also connects cells to the extracellular matrix that provide mechanical support, thus exposing the entire cell surface and activating signaling pathways. Hydrogel is a polymeric material that swells in water and maintains a distinct 3-dimensional (3D) network structure by cross linking. In this study, we investigated the optimized cellular function for canine adipose tissue-derived MSCs (cAD-MSCs) using hydrogel. We observed that the expression levels of Ki67 and proliferating cell nuclear antigen, which are involved in cell proliferation and stemness, were increased in transwell-hydrogel (3D-TN) compared to the transwell-normal (TN). Also, transforming growth factor-${\beta}1$ and SOX9, which are typical bone morphogenesis-inducing factors, were increased in 3D-TN compared to the TN. Collagen type II alpha 1, which is a chondrocyte-specific marker, was increased in 3D-TN compared to the TN. Osteocalcin, which is a osteocyte-specific marker, was increased in 3D-TN compared to the TN. Collectively, preconditioning cAD-MSCs via 3D culture systems can enhance inherent secretory properties that may improve the potency and efficacy of MSCs-based therapies for bone regeneration process.

• Journal of Chest Surgery
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• 제31권1호
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• pp.20-27
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• 1998

It is well known that troponin T(below TnT) is present in the myocardial cells and released during myocardial damage, so it`s very specific enzyme to myocardium. Availability of cardiac specific TnT in assessing perioperatively myocardial damage was evaluated from 34 open heart surgery patients. They consisted of 11 ischemic heart, 13 acquired valvular heart and 10 congenital heart cases. Patients were divided into two groups, group A(patients with myocardial damage) and group B(patients without myocardial damage), according to the symptom of chest pain suspecting angina and the ECG findings of ST segment and T wave changes which show myocardial ischemia and injury. Serum TnT levels were measured by enzyme immunoassay method preoperatively, immediately postoperatively, postoperative day 1, day 2, day 3, and day 7. We observed and analyzed the changes of serum TnT levels in two groups and compared the serum TnT levels with CK-MB levels measured at the same time. In group A, serum TnT levels showed 1.37$\pm$0.26$\mu$g/L, 3.16$\pm$0.66$\mu$g/L, 2.39$\pm$0.74$\mu$g/L, 2.49$\pm$0.76$\mu$g/L, and 1.23$\pm$0.60$\mu$g/L, immediate postoperatively, postoperatively day1, day2, day3, and day7, respectively. It was observed there were significant differences compared with those of group B(0.38$\pm$0.04$\mu$g/L, 0.34$\pm$0.05$\mu$g/L, 0.25$\pm$0.03$\mu$g/L, 0.24$\pm$0.04$\mu$g/L, and 0.11$\pm$0.03$\mu$g/L) during identical periods(P<0.01). Serum CK-MB level in group A significantly elevated to 145.04$\pm$35.08 IU/L on the postoperative day 1 compared to group B(31.28$\pm$5.87 IU/L, P<0.05), However, it stiffly decreased from day 2 and returned to preoperative level at day 3. When serum TnT level more than 1.0$\mu$g/L is thought to reflect myocardial damage, serum TnT had 100% of sensitivity and 87% of specificity in diagnosing the postoperative myocardial damage(p<0.01). I conclusion, serum TnT levels increased significantly at very early stage of myocardial damage and persisted much longer period than CK-MB. This suggests that serum TnT has more advantage and availability in assessing the perioperatively myocardial damage than any other tests.

• Proceedings of the KIEE Conference
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• 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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• pp.178-181
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• 2001

The electro-optical (EO) characteristics for the twisted-nematic (TN)-liquid crystal display (LCD) photo-aligned with polarized UV exposure on various blending photopolymer surfaces were investigated. Excellent LC alignment and voltage-transmittance (V-T) characteristics for TN-LCD photo-aligned with polarized UV exposure of normal incidence on the blending Photopolymer (polyimide (PI) + PM4Ch (poly(4-methacryloyloxy chalcone))) surface containing chalcone group can be achieved. The EO performances of the TN-LCD photo-aligned on the blending photopolymer can be improved due to the photosensitivity by long side chain of the photopolymer.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 한국조명전기설비학회 2009년도 추계학술대회 논문집
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• pp.315-318
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• 2009

Electric shock is the accident caused by the current through a person or animal's body. That is characterized by the physiological effects. In this paper, we evaluate performance of protection against electric shocks for TT and TN grounding systems which are used by a low voltage consumer nowadays. The performance of protection against electric shocks for TT grounding system is very excellent in equipotential area of the third class grounding, but the performance is poor outside the equipotential area. The performance of protection against electric shocks for TN grounding system is excellent because the potential difference is less than 50V. Accordingly, the performance of protection for TN grounding system is good as compared with that for TT grounding System.

• Annals of Clinical Neurophysiology
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• 제19권2호
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• pp.145-147
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• 2017

Trigeminal neuralgia (TN) is generally characterized by lancinating, unilateral, paroxysmal pain occurring in the distribution of the fifth cranial nerve. TN is diagnosed clinically based on the typical patient history, negative findings in a neurologic examination, and the response to medication. Idiopathic TN is the most common type, but TN can result from vascular malformation, compression, trauma, neoplasm, multiple sclerosis, or inflammation. We report a TN case diagnosed as recurrent trigeminal neuritis of the maxillary branch confirmed by magnetic resonance imaging.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• 제18권10호
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• pp.924-928
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• 2005

We synthesized the two types of photoalignment material of high thermal resistance with hydroxyl aromatic polyimide, and studied the liquid crystal (LC) aligning capabilities on the photopolymer layers. Also, electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photoaligned with linearly polarized UV exposure were investigated. A good LC alignment with UV exposure on the two types of photopolymer surface can be obtained. The Voltage-transmittance (V-T) curve in the photoaligned TN cell with UV exposure was different from two type. The response time of photoaligned TN cell was measured about 21 ms in two alkyl chain and about 15 ms in four alkyl chain.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.53-54
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• 2006

We have studied the viewing angle control of a twist nematic liquid crystal display (TN-LCD). The TN-LCD exhibits a bad image quality along vertical direction, due to characteristics such as low contrast ratio and grey scale inversion. The proposed new TN-LCD has the function of switching between the wide viewing mode and narrow viewing angle mode using two tilted LC layers at both sides of a TN-cell Tilt angles of the two LC layers, $14^{\circ}$ and $60^{\circ}$ were required in both wide viewing angle and narrow viewing angle modes, respectively.