• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.18-18
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• 2010

Methods of the characteristics evaluation of turbo-molecular pumps (TMP) are well-defined in the international measurement standards such as ISO, PNEUROP, DIN, JIS, and AVS. The Vacuum Center in the Korea Research Institute of Standards and Science has recently designed, constructed, and established the integrated characteristics evaluation system of TMPs based on the international documents by continuously pursuing and acquiring the reliable international credibility through measurement perfection. The measurement of TMP pumping speed is normally performed with the throughput and orifice methods dependent on the mass flow regions. However, in the UHV range of the molecular flow region, the high uncertainties of the gauges, mass flow rates, and conductance are too critical to precisely accumulate reliable data. With UHV gauges of uncertainties less than 15% and a calculated conductance of the orifice, about 35% of pumping speed uncertainties are experimentally derived in the pressure range of less than $10^{-6}$ mbar. In order to solve the uncertainty problems of pumping speeds in the UHV range, we introduced an SRG with 1% accuracy and a constant volume flow meter (CVFM) to measure the finite mass flow rates down to $10^{-3}$ mbar-L/s with 3% uncertainty for the throughput method. In this way we have performed the measurement of pumping speed down to less than $10^{-6}$ mbar with an uncertainty of 6% for a 1000 L/s TMP. In this article we suggest that the CVFM has an ability to measure the conductance of the orifice experimentally with flowing the known mass through the orifice chambers, so that we may overcome the discontinuity problem encountering during introducing two measurement methods in one pumping speed evaluation sequence.

• 상하수도학회지
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• 제30권1호
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• pp.1-8
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• 2016

Temperature correction trans-membrane pressure (TC-TMP) is frequently used as a fouling index in membrane water treatment plants. TC-TMP equation is derived based on an assumption that the total membrane resistance (i.e. the sum of the intrinsic membrane resistance and fouling resistance) is not affected by temperature. This work verified the validity of this assumption using microfiltration (MF) and ultrafiltration (UF) membranes with and without fouling. The foulants used in the work were kaolin (inorganic) and humic acid (organic). The intrinsic resistances of MF and UF membranes remains at constant values regardless of temperature change. When the same amount of foulants were accumulated on the membrane, inorganic fouling resistance with kaolin was constant regardless of temperature change while organic fouling resistance with humic acid decreased at higher temperatures, which means that TC-TMP cannot be used as a fouling index when organic fouling occurs in a real field application. Since TC-TMP underestimates the amount of fouling at higher temperatures, more attention should be necessary in the operation of membrane water treatment plant in a hotter season like summer.

• 대한화학회지
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• 제39권11호
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• pp.837-841
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• 1995

사염화탄소 속에서 티오프로피온아미드(TPA)와 triethylphosphine oxide(TEPO), triethylphosphine oxide(TPPO), trimethylphosphate(TMP), 그리고 tributyl phosphate(TBP)간의 수소 결합에 대한 열역학적 상수들을 근적외선 분광법을 이용하여 구하였다. TPA의 .nu./.alpha./+amide 2 조합띠는 TPA 단위체 및 수소 결합을 이룬 TPA의 띠로 이루어져 있음이 확인되어 이 띠를 두 개의 Lorentzian-Gaussian 곱함수의 띠로 분해하였다. 온도 및 농도의 변화에 따른 이 조합띠의 변화기로부터 TPA와 TEPO, TPPO, TMP, TBP의 수소 결합 엔탈피는 각각 -21.4, -16.8, -12.8, -12.9kJ/mol이었다. 이 결과는 치환기의 inductive effect 및 steric effect로 설명할 수 있다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.335-335
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• 2010

한국표준과학연구원 진공센터에서는 국제규격에 바탕을 둔 저진공펌프 종합특성평가시스템을 구축하여 $1100mbar\;{\sim}\;10^{-3}mbar$ 압력 영역에서의 저진공펌프(roots, dry 등)류의 종합특성평가를 시행하고 있다. 저진공펌프 종합특성평가시스템은 국제적 절차에 따른 신뢰성을 바탕으로 구축하고 있으나, 한국표준과학연구원 진공센터 뿐만 아니라, 국내에서도 고진공 종합특성평가 시스템을 구축 하고 있지 않다. 이에 반도체/디스플레이 등 첨단 공정에서 진공 환경을 조성하는 핵심장비인 고진공펌프의 종합특성평가시스템을 개발하고자 터보펌프(TMP) 1000L/s 급의 database를 구축 하였다. 터보펌프(TMP)는 throughput method와 orifice method 두 가지 방법을 병행하여 pumping speed 측정한다. orifice method는 일종의 미세유량 측정 장치이며, 실험값과 계산값 유량의 오차 범위가 작고 신뢰성을 확보하면 throughput method 만으로 측정할 수 있다. Througput method는 $10^{-6}mbar$ 압력 이상의 영역을 측정하며, ultimate pressure 및 $150^{\circ}C$의 bake-out 을 진행하여 base pressure을 측정 할 수 있으며, $10^{-6}mbar$ 압력 이상의 pumping speed를 측정 할 수 있다. 이에 따른 정압형 유량시스템을 개발 중에 있으며, inlet pressure와 outlet pressure를 이용한 compression ratio를 측정 한다. Orifice method는 ultimate pressure와 base pressure을 측정하며, leak valve를 이용한 컨덕턴스(C)로 pressure ratio을 이용하여 유량값을 계산하며, $10^{-6}mbar$ 압력 이하의 pumping speed를 측정할 수 있다. 또한 throughput method와 orifice method의 pumping speed 뿐만 아니라 소비전력 및 소음, 진동, 온도 등 특성평가 관련 사항들의 전반적인 사항을 평가하여 터보펌프(TMP) 1000L/s 급의 database를 구축한다. 향후 예비 실험을 통한 고진공펌프의 종합특성평가시스템을 완비해 나가며, 고진공펌프 종합 특성평가시스템을 통하여 국제적으로 공인받을 수 있는 평가기준을 확립하고 그 기준에 의한 진공/기계적 성능의 전방위적인 종합특성진단과 공정대응성 평가 등 국제적 기술 신뢰성을 확보하고자 한다.

• 펄프종이기술
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• 제35권5호
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• pp.17-25
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• 2003

The influence of base paper properties and fiber type on coating penetration was studied in terms of characterization of coating holdout using two types of hand sheets as the base paper which were prepared from thermomechanical pulp (TMP) and hardwood bleached kraft pulp(KP) sized internally with alkyl ketene dimmer (AKD). Laboratory rod draw down coater was used for surface sizing and coating application. Characterization of coating penetration was done by measuring the roughness of the backside of coating layer. The backside of the coating was exposed by dissolving the fibers in a solution of cupriethylenedimine (CEO). Data show that internal sizing of base paper is effective and surface sizing is more effective to prevent coating penetration. Comparing between the two types of base papers, backside roughness of coating layer of TMP sheet is much larger and sizing is more effective to reduce coating penetration than those of KP sheet. From the result of water absorption and sizing degree after surface sizing, it seems that internal sizing slows down molecular diffusion much more than capillary penetration, but surface sizing reduces the capillary penetration. Furthermore, predominant mechanism of water into paper of TMP sheet seems to be capillary penetration, but it is molecular diffusion in the case of KP sheet.

• Environmental Engineering Research
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• 제23권2호
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• pp.159-163
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• 2018

The feasibility of applying coagulation-integrated microfiltration (MF) as a pretreatment for an ultrafiltration (UF) feed in oily wastewater treatment was investigated. The effects of different coagulants on oil removal rates from wastewater were studied. The maximum oil removal rate of 82% was obtained after coagulation with 130 mg/L of polyaluminium chloride (PAC). UF flux reached $95L/(m^2{\cdot}h)$ with coagulation-integrated MF as pretreatment. This value was 2.5 times higher than that flux obtained without pretreatment. The value of UF flux increased as the transmembrane pressure (TMP) and cross-flow velocity (CFV) of the UF module increased. UF flux gradually increased when TMP and CFV exceeded 0.4 MPa and 3 m/s, respectively, because of concentration polarization and membrane fouling stabilization. Chemical oxygen demand reduction and oil removal rate reached 95.2% and 98.5%, respectively, during integrated membrane processing with a PAC concentration of 130 mg/L, TMP of 0.4 MPa, and CFV of 3 m/s for UF. In addition, sequentially cleaning the fouling membrane with NaOH and $HNO_3$ aqueous solutions caused UF flux to recover to 90%. These encouraging results suggested that the hybrid integrated membrane process-based coagulation and MF + UF are effective approaches for oily wastewater treatment.

• 한국환경보건학회지
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• 제24권1호
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• pp.70-79
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• 1998

본 실험의 목적은 다양한 펄프제조 조건과 여러 형태의 리그노 셀루로우스 성분이 펄프폐수의 혐기성 생분해에 미치는 영향을 규명하는 것이다. 실험에 사용된 폐수는 일반적으로 펄프 제조시에 발생되는 폐수를 대상으로 하였으며, 펄프제조 조건은 TMP공정과 소다 펄프공정을 적용하였다. 혐기성 생분해 가능성 시험 및 독성실험은 $35\pm 2\circ$C의 중온상태에서 입상슬러지를 식종물질로 사용한 회분식 반응조를 이용하였다. TMP공정의 배출되는 폐수는 산으로의 전환율이 총 COD기준으로 68-87%로 매우 높은 혐기성 생분해 가능성을 보였다. 그리고 TMP공정폐수는 일반적으로 제지폐수 처리시 독성농도라고 알려진 농도에서도 메탄생성균에 독성을 주지 않았고, 또한 COD 10g/l의 농도에서도 처리에 저해가 일어나지 않았다. 반면에, 알카리성 상태에서 준비된 펄프폐수의 경우는 생분해성이 매우 낮아서 대략 50%정도의 산전환율을 보였으며, 메탄생성균에 상당한 저해를 주었다. 메턴생성균의 활성도에 50%저해를 주는 농도는 2.1~5.4 gCOD/l였다. 알카리성 펄프폐수의 독성에 대한 추가 실험결과 펄프내 wood resin이 산이나 중성 pH부근에서는 잘 용해가 되지 않고 알카리성 상태에서 쉽게 용해되어 메탄생성균에 저해를 나타내는 것으로 밝혀졌다. 따라서 펄프제조시 나무성분이 알카리성분과 접촉할 경우 후속하는 혐기성 처리공정의 메탄생성균에 심각한 저해를 줄 수 있다.

• 상하수도학회지
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• 제22권4호
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• pp.445-448
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• 2008

The application of the membrane filtration process has been increased for the drinking water treatment system because of excellent quality of treated water compared with the sand filtration process. The selection of suitable pre-treatment processes and optimum flux according to the characteristics of raw water are important factors for the design of membrane processes. In this study, the most efficient pre-treatment processes for drinking water was selected by investigating the effects of pre-treatment processes on the operational stability of the membrane filtration process. Both lab-scale and pilot-scale experiments were conducted. In the lab-scale test, the effect of pre-treatment processes on the stability of the membrane filtration process was investigated indirectly by comparing the performance of membrane flux for raw water, pre-treated water, and membrane permeated water. In the pilot-scale test, the usefulness of prefiltration processes was assessed by comparing the performance of single membrane process and hybrid coagulation-membrane process. The results indicated that the coagulation process contributed to the stabilization of trans-membrane pressure (TMP) by removing contaminants on membranes, though the pre-filtration process had little effect on the TMP.

• Journal of the Korean Wood Science and Technology
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• 제25권2호
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• pp.75-80
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• 1997

This research has been examined to measure the degree of the fiber damage of ozonenation high yield pulp in the beating process. Ozone treated the TMP(Thermomechanical Pulp) and CTMP(Chemithermomechanical Pulp) of spruce and the CTMP of birch has been beaten to be reached 200ml(freeness) of its content. It had been studied the forming of fiber distribution by treatment for long fiber, short fiber, fine with the above method. As ozone treatment time gets longer, the pulp has showed the tendency of increasing the fiber content of 28, 48mesh. Ozone treated fiber has been increased long fiber content by being added softness. By given longer ozone treatment time, the TMP and CTMP of spruce has showed the decreasing of fiber content. On the contrary, CTMP of birch has showed the increasing its fiber content. It had proved that the results of difference are rather closer to the species of tree than closer to the kinds of pulp. The fiber content of over 200mesh which has created in beating process demonstrates the decreasing of its fiber content by getting longer ozone treatment time. The softness of fiber can be extracted by the lignin of fiber surface that had been formed by ozone treatment. Thus we assume that the fiber in the process of beating obtains less physical damage.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.1
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• pp.51-59
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• 2006

The surface of various mechanical pulp fibres including thermomechanical pulp (TMP), chemithermomechanical pulp (CTMP), and alkaline peroxide mechanical pulp (APMP) fibres, were characterized using SEM, AFM, and XPS. With SEM and AFM, middle lamella material was observed to be non-fibrillar, patch-like, while fibre secondary wall was observed to have a microfibrillar structure. It was found that after the first-stage refiner, lignin-rich middle lamella remainders are present on the fibre surface of all three pulps, although most of the fibre surfaces expose microfibrillar structure. After the final-stage refining, large amounts of granules are present on the TMP fibre surface. In contrast, most middle lamella remainders remain on the surface of CTMP fibres after final stage refining and even after peroxide bleaching. XPS results have confirmed that the non-fibrillar surface material is the lignin-rich middle lamella remainder., and the remainders of middle lamella contribute to the high surface lignin concentration.