• Title/Summary/Keyword: THM

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Constitutive Model for Unsaturated Soils Based on the Effective Stress (유효응력에 근거한 불포화토의 역학적 구성모델)

  • Shin, Ho-Sung
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.55-69
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    • 2011
  • The importance of unsaturated state in various geo-engineering problems has led to the advance of mechanical constitutive model emulating behavior of unsaturated soils in response to thermo-hydro-mechanical loading. Elasto-plastic mechanical constitutive model for unsaturated soil is formulated based on Bishop's effective stress. Effective stress and temperature are main variables in constitutive equation, and incremental formulation of constitutive relationship is derived to compute stress update and stiffness tensor. Numerical simulations involving coupled THM processes are conducted to discuss numerical stability and applicability of developed constitutive model: one-dimensional test, tri-axial compression test, and clay-buffering at high level radioactive waste disposal. Numerical results demonstrated that developed model can predict very complex behavior of coupled THM phenomena and is applicable to geo-engineering problems under various environmental conditions, as well as interpret typical behavior of unsaturated soils.

A study on the concentration and health risk of trihalomethanes in drinking water (음용수중 Trihalomethane의 오염과 그 위해성에 관한 조사연구 - 주요 14개도시를 대상으로 (1988. 9-1989. 2) -)

  • Chung, Yong;Shin, Dong-Chun;Lee, Bo-Young;Yu, Sung-Han;Chung, Sang-Hyuk
    • Journal of Preventive Medicine and Public Health
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    • v.22 no.4 s.28
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    • pp.495-505
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    • 1989
  • This study was conducted as a nationwide survey In Korea to determine the THM (trihalomethane) concentration levels in the drinking water of 14 selected cities. The survey was underdtaken in one city (Kwangju) during September and October of 1988 and 14 cities in January through February of 1989. The results were as follows : 1. The $KMnO_4$ consumption was 10.6mg/l-11.6mg/l in Pusan and Ulsan, exceeding the drinking water standard of 10mg/l. Pusan, Inchon, Kwangju, Ulsan, Mokpo and Junju areas also exceeded the ammonia nitrate standard of 0.5mg/l. Other tap waters surveyed were detected below the drinking water standards. 2. The THM concentrations of tap water measured in January and February of 1989 were detected in the range $1.20{\mu}g/l-150.8{\mu}g/l$. 3. In the comparative study of the THM concentration of tap water measured in the Kwangju area during September and October of 1998, the average THM concentation of $145.63{\pm}70.72{\mu}g/l$ showed a sixfold increase compared to that of $23.8{\pm}8.31{\mu}g/l$ surveyed in January and February 1989. 4. The proportion of the four THM compounds found in tap water was bromoform, 47% ; chloroform, 30% ; chlorodibromomethane, 13% ; and dichlorobromomethane, 10%. 5. Since the results indicate that the concentration of bromoform was 2-10 times higher than that of chloroform measured in the seaside district of Pusan, Ulsan and Cheju Island, it is reasonable to assume that the raw water was somehow Influenced by seawater. 6. The average lifetime cancer rate of the population exposed to chloroform measured in the surveyed areas was 17 cancer incidences per 1 million population. From the above results, the existence of THM in the distribution systems seems to be inevitable, since chlorine disinfection is performed in water treatment plants In our country. There seems to be a trend of increasing. THM cncentrations due to the contamination of raw water. In order to establish my form of regulations, health risk assessment is an imminent subject.

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Evaluation of mechanical properties of KURT granite under simulated coupled condition of a geological repository (복합 처분환경 모사조건에서의 KURT 화강암의 역학적 물성 변화 평가)

  • Park, Seunghun;Kim, Jin-Seop;Kim, Geon Young;Kwon, Sangki
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.4
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    • pp.501-518
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    • 2019
  • The rock properties measured under in-situ geological condition can be used to increase the reliability in numerical simulations with regard to the long-term performance of a high-level waste repository. In this study, the change in mechanical properties of KURT (Korea atomic energy research institute Underground Research Tunnel) granite was evaluated under the simulated THM (Thermo-Hydro-Mechanical) coupled condition due to a deep geological formation in the disposal repository. The rock properties such as uniaxial compression strength, indirect tensile strength, elastic modulus and Poisson's ratio were measured under the coupled test conditions (M, HM, TM, THM). It was found that the mechanical properties of KURT granite is more susceptible to the change in saturation rather than temperature within the test condition of this study. The changes in uniaxial compression strength and indirect tensile strength from the rock samples of dried or saturated conditions showed the maximum relative error of about 20% and 13% respectively under the constant temperature condition. Therefore, it is necessary to use the material properties of rock measured under the coupled THM condition as input parameters for the numerical simulation of long-term performance assessment of a disposal repository

Change of Molecular Weight of Organic Matters through Unit Water Treatment Process and Associated Chlorination Byproducts Formation

  • Sohn, Jin-Sik;Kang, Hyo-Soon;Han, Ji-Hee;Yoon, Yeo-Min
    • Environmental Engineering Research
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    • v.12 no.5
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    • pp.224-230
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    • 2007
  • The objectives of this study were to evaluate the change of molecular weight (MW) profiles in natural organic matter (NOM) through various treatment processes (coagulation, granular activated carbon (GAC), and ozonation) using high performance size exclusion chromatography based on ultraviolet absorbance and dissolved organic detection (HPSEC-UVA-DOC). In addition, relationships between MW profiles and disinfection by-production (DBP) formation were evaluated. Each treatment process results in significant different effects on NOM profiles. Coagulation is effective to remove high molecular weight NOM, while GAC is effective to remove low molecular weight NOM. Ozonation removes only a small portion of NOM, while it induces a significant reduction of UV absorbance due to breakdown of the aromatic groups. All treated waters are chlorinated, and chlorination DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) are measured under formation potential conditions. Both THM and HAA formation potentials were significantly reduced through the coagulation process. GAC was more effective to reduce THM formation compared to HAA formation reduction, while ozonation showed significant HAA reduction compared to THM reduction.

ARTIFICIAL NEURAL NETWORK FOR PREDICTION OF WATER QUALITY IN PIPELINE SYSTEMS

  • Kim, Ju-Hwan;Yoon, Jae-Heung
    • Water Engineering Research
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    • v.4 no.2
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    • pp.59-68
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    • 2003
  • The applicabilities and validities of two methodologies fur the prediction of THM (trihalomethane) formation in a water pipeline system were proposed and discussed. One is the multiple regression technique and the other is an artificial neural network technique. There are many factors which influence water quality, especially THMs formations in water pipeline systems. In this study, the prediction models of THM formation in water pipeline systems are developed based on the independent variables proposed by American Water Works Association(AWWA). Multiple linear/nonlinear regression models are estimated and three layer feed-forward artificial neural networks have been used to predict the THM formation in a water pipeline system. Input parameters of the models consist of organic compounds measured in water pipeline systems such as TOC, DOC and UV254. Also, the reaction time to each measuring site along pipeline is used as input parameter calculated by a hydraulic analysis. Using these variables as model parameters, four models are developed. And the predicted results from the four developed models are compared statistically to the measured THMs data set. It is shown that the artificial neural network approaches are much superior to the conventional regression approaches and that the developed models by neural network can be used more efficiently and reproduce more accurately the THMs formation in water pipeline systems, than the conventional regression methods proposed by AWWA.

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An Effcient Two-Level Hybrid Signature File Method for Large Text Databases (대용량 텍스트 데이터베이스를 위한 효율적인 2단계 합성 요약 화일 방법)

  • Yoo, Jae-Soo;Gang, Hyeong-Il
    • The Transactions of the Korea Information Processing Society
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    • v.4 no.4
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    • pp.923-932
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    • 1997
  • In this paper, we propose a two-level hybrid signature file method(THM) to dffciently deal with large txt databases that use a term discrimination concept.In addition, we apply Yoo's clustering scheme to the two-level hybeid signature file method. The clustering schme groups similar signatures together according to the similarity of the highly discriminatiory tems so that we may achive better performance on retrival. The space-time ana-lyhtical model of the proposed two-level hybrid method is provided. Based on the analytical model and experiments, we compare it with the exsting methods, i.e. the bit-sliced method(BM), the-level method(TM), and the hybrid method(HM). As a result, we show that THM achives the best retrival performance in a large database with 100,000 records when the mumber fo matching records is less than 160.

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Mechanical Constitutive Model for Frozen Soil (동토지반에 대한 역학적 구성모델)

  • Shin, Ho-Sung;Kim, Ji-Min;Lee, Jang-Guen;Lee, Seung-Rae
    • Journal of the Korean Geotechnical Society
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    • v.28 no.5
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    • pp.85-94
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    • 2012
  • Recently, growing interests in frozen ground have stimulated us to advance fundamental theories and systematic researches on soil behavior under freezing conditions. Unlike the well-established soil mechanics theory, temperature variation and phase change of pore-water cause water migration to cold side, ground heaving, sharp increase in earth pressure, etc., which bring about serious problems in frozen geotechnical structures. Elasto-plastic mechanical constitutive model for frozen/unfrozen soil subjected to fully coupled THM phenomena is formulated based on a new stress variable that is continuous in frozen-unfrozen transitional regions. Numerical simulations are conducted to discuss numerical reliability and applicability of the developed constitutive model: one-dimensional heaving pressure, tri-axial compression test, and one-side freezing tests. The numerical results show that developed model can efficiently describe complex THM phenomena of frozen soil, and they can be utilized to analyze and design the geotechnical structures under freezing conditions, and predict their long-term behavior.

Behavior of THM Formation Pormation Potential for Micro-Pollutants Mixed with SBR Effluent in BAC Treatment (활성오니 처리수중에 함유된 미량유기오염물의 생물학적 활성탄 처리시 THM 생성능의 거동)

  • Han, Myung Ho;Kim, Jeong Mog;Huh, Man Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.84-98
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    • 2000
  • Control of Trihalomethanes(THMs) is a major concern of many water treatment plants. A number of researchers have studied the effectiveness of activated carbon adsorption process in removing THMs or organic halogen compounds. Recently, attention has been paid to the biological activated carbon (BAC) treatment of THM precursors as an alternative to the carbon adsorption treatment because of its effectiveness as well as its low running cost. In this study, changes of THM formation potential(THMFP) and removal of substrates in the SBR effluent were investigated in an attempt to clarify the mechanisms of the decrease/increase of THMFP in the BAC treatment. The increase and decrease of THMFP concentrations were observed in effluents during prolonged operation. When PCP or DBS was feeded as substrate contained in SBR effluent, the THMFPs were easyly removed with TOCs removal. But the case of SBR effluent containing SDS or glycine was introduced, and when microbial growth came to its near steady state, the THMFPs of treated effluents were increased more or less in comparison to those in the influents. Such increases of THMFP coincided with the increase in microbial growth within the activated carbon fiber(ACF) column. In the case of only sucrose was feeded as substrate on ACF colume, THMFP concentrations of effluent were higher than those of influent. The THMFP concentration was significantly increased on inlet part of ACF column, which biomass inhabits abundantly, then they were decreased gradually. These increases mean production of the secondary THM precursors by biological activities, which can be removed by adsorption and biological degradation on ACF column.

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Determination of THM(trihalomethane) in Rain by using Solid Phase Micro-Elctraction(SPME) Fiber Assembly (고상 미량 추출 장치(SPME, solid phase micro-extraction device)를 이용한 물 중의 THM(trihalomethane) 분석)

  • 유광식;박상윤
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.277-283
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    • 1997
  • SPME deuce was applied to determine the THM in an aqueous solution. The 6 kinds of THM was quantitatively detenuned by using GC-ECD which has the sample eutracted on the SPME fiber from an aqueous solution for 10 min. The THM components were well separated from $CHCl_3$ to the last $CHBr_3$ UHh 13 mons at the condition. 6 kinds of the volatile halogenated organic compounds: $CHCl_3$, $CHBrCl_2$, $CHBrtCl_2$, $CHCl_3$, $C_2Cl$. and $CHBr_3$, showed well defirled calibration graph with good llnearlty from a few ppb level up to several tens of pub concentration. $CHBr_2Cl$ and $C_2C1_4$ were detected from a few samples among the 10 of river samples. CHCl3, however, was detected In 4 sea water samples with the highest of 10 ppd among the pouuted 6 positions. Trace level of $CHBr_2Cl$ and few pub level of $CHBr_3$ were also detected at the other two sample stations. Most of the 13 rain water samples collected from 6 sampling stations were contained ppd level of $CHCl_3$, and also $CHBr_2Cl$, and C_2Cl_4$ were only detected at trace level at a few rain samples among them. We could recognize the fact that our Ut and water enoronment has already been contaminated by certain volatile halogenated organic compounds through this study.

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