• Title/Summary/Keyword: TEM cell.

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Study on microstructure of sensitized Alloy 600 rapidly solidified by a $CO_2$ laser beam ($CO_2$ 레이저빔을 이용한 예민화된 Alloy 600의 급속응고 미세구조 연구)

  • 임연수;서정훈;국일현;김정수
    • Laser Solutions
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    • v.1 no.1
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    • pp.18-23
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    • 1998
  • A Study on microstructural changes of sensitized Alloy 600 which was rapidly solidified by a $CO_2$ laser beam was conducted using microscopic equipments such as SEM and TEM. Dissolution of Cr-rich carbides and resultant Cr recovery on the grain boundaries occurred in the heat affected zone (HZA). The microstructure of the laser melted zone (LMZ) having epitaxially solidified from the HAZ was mainly celluar-dendritic with the 〈100〉 crystallographic direction of growth. The Cr concentration was observed to increase along the cell bondaries, and tiny particles were distributed along the cell walls with tangled dislocations around them. Cr-rich carbides had been completely melted by the high density of a laser beam, and were not re-precipitated during the matrix solidification due to a fast cooling rate in the LMZ.

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Non-Pt transition metal electrode catalyst for Oxygen Reuction Reaction of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지의 산소환원반응을 위한 비백금계 전이금속 전극 촉매)

  • Kim, Jy-Yeon;Lee, Sang-Beom;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.383-385
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    • 2009
  • 비백금계 코발트 전이금속 촉매를 탄소지지체에 담지한 뒤, 암모니아 분위기에서 $500^{\circ}C$에서 3시간 동안 열처리하는 과정을 통해 코발트 질화물 촉매를 제조했다. 제조된 촉매들의 구조와 형태를 각각 XRD, HE-TEM등을 통해 분석하였고, 전위 측정기를 이용한 CV, LSV 결과로부터 촉매의 전기화학적 산소 환원특성을 분석하여, 기존의 연료전지 양극 촉매로 사용되는 고가의 백금촉매를 대체하기 위한 비백금계로서의 가능성을 확인하였다.

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Development of methanol resistance catalysts for DMFC cathodes (Methanol에 저항성을 가진 DMFC용 cathode catalyst의 개발)

  • Oh, Jong-Gil;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.204-207
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    • 2007
  • DMFC(direct methanol fuel cell)는 액체연료의 이동과 저장의 용이성 때문에 이동용 장치를 위한 전원공급 장치로서 오랫동안 관심을 받아왔다. 하지만 methanol crossover는 DMFC의 상용화 이전에 해결해야 할 문제이다. 이를 위해 많은 분야에서 연구가 진행되고 있고, 그중에서 methanol에 저항성을 가진 촉매의 개발에 활발히 연구가 진행되고 있다. 본 연구에서는, 표연개질 된 PtCo/C 촉매를 사용하여 메탄올에 저항성을 가진 촉매를 합성하였다. 합성된 촉매의 size와 morphology를 알아보기 위해 transmission electron microscopy (TEM)를 사용하였다. 또한 methanol 존재 하에 산소환원반응의 activity를 알아보기 위해 Rotating ring disk electrode(RRDE) test를 하였고, MEA를 제작하여 full cell test도 병행하였다.

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Time-Domain Response of Transmission-Line Structures Excited by an External Electromagnetic Pulse (외부 전자파 펄스에 의해 여기된 전송선로 구조의 시간 영역 응답)

  • 김태현;정연춘;김세윤;박동철;배범열;박종한
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.7 no.3
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    • pp.239-245
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    • 1996
  • The time-domain response of a two-conductor-structure transmission line excited by an incident electromagnetic pulse is numerically analyzed using the Finite-Difference Time-Domain (FDTD) method. The external electromagnetic pulse is generated by ultilizing a TEM cell. The simulated time-domain response is compared with the time-domain response which is obtained by the Inverse Fast Fourier Transform(IFFT) of the frequency domain measurement data.

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Optimization of Heating Conditions for Bacteria Associated with Food Hygiene (식품위생관련 세균에 대한 가열처리 조건의 최적화)

  • 이보순
    • The Korean Journal of Food And Nutrition
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    • v.12 no.6
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    • pp.569-574
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    • 1999
  • Response surface methodology(RSM) was applied to determine the optimum heating conditions(tem-perature and time) for the inactivation of bacteria associated with food hygiene. Coefficients of determinations(R2) for the cell growth were 0.9155(P<0.05) in Pseudomonas aeruginosa 0.8997(P<0.05) in Escherichia coli 0.9690(P<0.01) in Salmonella typhimurium 0.9393(P<0.05) in Enterobacter aerogenes and 0.7905 in Vibrio parahaemolyticus. The growth of strains was significantly affected by the temperature and time and reaction to temperature was most closely correlated to the inhibition of growth. On the basis of superimposed contour maps of cell growth the optimum range of heating conditions were 55.62-6$0^{\circ}C$ and 19.25-30 min.

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Photovoltaic characteristics of Si quantum dots solar cells

  • Ko, Won-Bae;Lee, Jun-Seok;Lee, Sang-Hyo;Cha, Seung-Nam;Hong, Jin-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.489-489
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    • 2011
  • The effect of Si quantum dots for solar cell appications was investigated. The 5 ~ 10 nm Si nanoparticle was fabricated on p-type single and poly crystalline wafer by magnetron sputtering and laser irradiation process. Scanning electron microscopy (SEM), atomic force measurement (AFM) and transmission electron microscopy (TEM) images showed that the Si QDs array were clearly embedded in insulating layer ($SiO_2$). Photoluminesence (PL) measurements reliably exhibited bandgap transitions with every size of Si QDs. The photo-current measurements were showed different result with size of QD and number of superlattice.

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Effect of Polyphosphates on the Growthof Listeria monocytogenes Scott A (인산염이 Listeria monocytogenes Scott A 성장에 미치는 영향)

  • 장덕화;송재영;김일환
    • Journal of Food Hygiene and Safety
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    • v.10 no.4
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    • pp.205-211
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    • 1995
  • To investigate the antimicrobial effect of polyphosphates as a food additive, the growth and structural change of Listeria monocytogentes Scott A were examined in relation to polyphosphates concentration and incubation temperature. Up to 10,000 ppm of polyphosphates, the growth rate of strain was gradually inhibited with increasing polyphosphates concentration and decreasting the incubation temperature. Minimal inhibitory concentration of polyphosphates to the growth of strain was about 12,000 ppm. It was observed , using both scanning electron microscopy(SEM) and transmission electron microscopy(TEM), that 0.9% polyphosphates treatment was resulted in the destruction of cell wall and outflow of cell ingredients. The antimicrobial effects of polyphosphates were more effective than those of dehydroacetate and potassium sorbate at 13$^{\circ}C$ and 4$^{\circ}C$. The growth rate the strain in beef was significantly inhibited by the treatment of 0.9% polyphosphates and storaged at cooling temperature.

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One-pot Synthesis of Nickel and Tungsten Carbide Nanoparticles Supported Mesoporous Carbon Electrocatalyst for Oxygen Reduction Reaction (산소환원반응을 위한 니켈-텅스텐 카바이드 나노입자 담지 메조포러스 카본 촉매의 단일 합성 및 그 특성 평가)

  • Kim, Hyemin
    • Journal of the Korean institute of surface engineering
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    • v.51 no.3
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    • pp.179-184
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    • 2018
  • In this study, Ni and tungsten carbide (WC) nanoparticles are simultaneously synthesized with the mesoporous carbon nanoparticles (CNP) using a solution plasma processing (SPP) in the benzene. The Ni and WC nanoparticles were formed through the sputtering effect of electrodes during discharge, and mean time CNP were formed through reduction reaction. TEM observation showed that loaded Ni and WC nanoparticles were evenly dispersed on the CNP. The results of electrochemical analysis demonstrated that an introduction of Ni nanoparticles promoted to improve catalytic activity for oxygen reduction reaction (ORR). Moreover, Ni-WC/CNP lead to fast electron transfer process compared to that of WC/CNP. Therefore, the inexpensive Ni-WC/CNP might be a promising as catalytic material for cathodes in fuel cell applications.

Antimicrobial Activities of Chopi(Zanthoxylum piperitum DC.) Extract (초피추출물의 항균특성)

  • 정순경;정재두;조성환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.2
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    • pp.371-377
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    • 1999
  • In order to evaluate the antimicrobial function of natural herb extracts as antimicrobial agent or packaging material for the preservation of foods and greenhouse produce, the water extract of chopi (Zanthoxylum piperitum DC.) was prepared and its antimicobial activity was determined. In the paper disk test its antimicrobial activity was increased in proportion to its concentraion. The growth of microorganisms was completely inhibited above 500ppm of its concentration. It showed wide spectrum of thermal(40 to 180oC) and pH(4 to 10) stabilities. In the electronic microscopic observation(TEM and SEM) of microbial morphological change it showed to decrease the activation of physiological enzymes and to lose the function of cell membranes. Even in the activation test of galactosidase, it seemed to weaken the osmotic function of cell membranes remarkably in comparison with chloroform and its activation corresponded to 40~50% of toluene. Zanthoxylum piperitum DC. extract seemed to be an excellent antimicrobial for the inhibition of food borne microorganisms as well as the pre servation of greenhouse produces.

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Antimicrobial Resistance Patterns of Vancomycin-Resistant Streptococcus equinus Isolated from Animal Foods and Epidemiological Typing of Resistant S. equinus by Microbial Uniprimer Kit

  • Choi, Sung-Sook;Lee, Jin-Woo;Kang, Byoung-Yong;Ha, Nam-Joo
    • Archives of Pharmacal Research
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    • v.26 no.8
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    • pp.638-643
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    • 2003
  • Raw milk samples, and cow and chicken intestines were tested to isolate vancomycin-resistant, gram-positive bacteria. From these samples, we isolated seven vancomycin-resistant Streptococcus equinus, two vancomycin-resistant viridans Streptococcus and two vancomycin-resistant Enterococcus faecium. The MICs of several antibiotics, including vancomycin, against these strains were tested. Seven isolates of S. equinus showed high level resistance to vancomycin and teicoplanin (>100 $\mu$ g/mL). The cell wall thickness of these strains was compared with that of the sensitive strain by TEM and no differences were obserbed between these strains. We compared the strains of vancomycin-resistant Streptococcus equinus using PCR with Microbial Uniprimer Kit. We concluded that it is necessary to combine other methods in order to cluster and identify all isolates of S. equinus.