• Title/Summary/Keyword: TDI

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Study on Improvement Measure for Ecosystem Health of Samcheonpo Stream (삼천포천의 수생태계 건강성 향상 방안 연구)

  • Gilsang Jeong;Hansu Choi
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.414-419
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    • 2023
  • Aquatic ecosystem is composed of various organic and inorganic matters. Its health is essential for sustaining its members such as vegetations, mammals, birds, fishes and invertebrates. Samcheonpo stream is one of candidate streams in Sacheon area of ecological restoration. For this reason, this study conducted to build up a data base for future comparison. The results shows that biodiversity of Epilithic Diatoms and Invertebrates is below average which means that human impacts such as artificial structures and activities have been negatively related to stream health. Consequently, we suggest several key factors when ecological restoration is performed in the stream.

Investigation on Polychlorinated Dibenzo-p-dioxins, Polychlorinated Dibenzofurans and Dioxin-like Polychlorinated Biphenyls of Grains and Estimation of Dietary Intake for Korean (국내생산 주곡작물의 Polychlorinated Dibenzo-p-dioxins, Polychlorinated Dibenzofurans와 Dioxin-like Polychlorinated Biphenyls 잔류량 및 섭취노출량 평가)

  • Choi, Geun-Hyoung;Choi, Dal-Soon;Hong, Su-Myeong;Kwon, Oh-Kyoung;Eun, Hee Soo;Kim, Jung Han;Kim, Jin Hyo
    • Journal of Applied Biological Chemistry
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    • v.55 no.4
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    • pp.253-261
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    • 2012
  • Dioxin contamination on agroproducts is one of the most important issue in food safety. Herein, we measured concentration of 17 dioxins polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) and 14 dioxin like-polychlorinated biphenyls (DL-PCBs) in the main grain (rice and barley) that were produced in Korea. The 36 rice samples were collected from rice processing complex at eight provinces, and the average concentrations of each province were ranged from 2.98 pg/g wet weight (w.w) to 4.98 pg/g w.w. as total PCDD/Fs and DL-PCBs. The seven barley samples were collected from Jeon-nam and Jeon-buk provinces, and their average total concentrations of PCDD/Fs and DL-PCBs were 3.00 pg/g w.w. and 3.24 pg/g w.w. respectively. The residual amounts and toxic equivalent (TEQ) of DL-PCBs in rice and barley were higher than PCDD/Fs. The average total TEQ of rice and barley were 0.0056 pg-TEQ/g and 0.0092 pg-TEQ/g on lower bound estimation respectively. Estimated daily intake of dioxins from rice and barley were calculated 1.03 pg-TEQ/day/person and 0.0534 pg-TEQ/day/person respectively. These were estimated 0.46% and 0.03% of Korean TDI based on 55 kg body weight.

Evaluation of short-term cardiac function by tissue Doppler imaging in pre and postoperative period of congenital heart disease (조직 도플러 영상을 이용한 선천성 심장병 수술 전후의 단기 심기능 평가)

  • Lee, Jun-Hwa;Kim, Yeo-Hyang;Hyun, Myung-Chul;Lee, Sang-Bum
    • Clinical and Experimental Pediatrics
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    • v.50 no.5
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    • pp.476-483
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    • 2007
  • Purpose : The objective of this study was to assess ventricular function by tissue Doppler imaging (TDI) in children with congenital heart disease (CHD) who have been undergoing open heart surgery (OHS) using cardiopulmonary bypass. We tried to compare the parameters of tissue Doppler imaging before and after OHS in patients with congenital heart disease. Methods : This study was conducted on 32 patients with CHD after OHS from January 2005 to December 2005 at Kyungpook National University hospital. Patients who underwent 2-D echocardiography before and after their OHS. All patients were divided into three groups, left ventricular volume overloading group (group 1), and right ventricular volume overloading group (group 2), and right ventricular pressure overloading group (group 3). The TDIs were examined before and 1 to 3 months after OHS. Peak early diastolic (E), and peak late diastolic (A) velocity of transmitral flow were measured by pulsed wave Doppler examination. Peak systolic (Sm), peak early diastolic (Em), and peak late diastolic (Am) velocity in apical 4-chamber and 2-chamber views were measured by TDI. The author calculated E/Em ratio. Results : The patients were 14 boys and 18 girls and the average age of patients was 2 years and 3 months. The congenital heart diseases which have to get OHS were ventricular septal defect (13 cases), atrial septal defect (7), atrioventricular septal defect (3), isolated pulmonary stenosis (2) and tetralogy of Fallot (7). There were significant decrease of Sm, Em, Am measured on tricuspid annulus and E/Em measured on mitral annulus in apical 4 chamber view (P<0.05). Conclusion : This study showed significant decrease of Sm, Em, Am measured on tricuspid annulus and E/Em measured on mitral annulus in apical 4 chamber view after OHS. These changes might be due to the effects of cardiopulmonary bypass in OHS and/or hemodynamic changes after correction of congenital heart disease. To clarify these changes, further study on more patients is needed.

Relation of Stream Shape Complexity to Land Use, Water Quality and Benthic Diatoms in the Seom River Watershed (섬강 수계에서 하천 형태복잡도와 토지이용, 수질 및 부착규조류 군집 분포와의 관계)

  • Min, Han-Na;Kim, Nan-Young;Kim, Mi-Kyung;Lee, Sang-Woo;Hwang, Kil-Soon;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.45 no.1
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    • pp.110-122
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    • 2012
  • This study examined the benthic diatom community distribution, land cover/use and water quality in relation to stream shape complexity (SSC) in the Seom River watershed. SSC showed a significant relation to the riparian land cover/use pattern and also water quality variables of the studied streams. Streams with high stream shape complexity (HSC) appeared to have a high proportion of forest and farmland, while streams having a low stream shape complexity (LSC) appeared to have high proportion of city. Streams with lower SSC showed higher nutrients concentration in the stream waters. Benthic diatom species composition and dominant species appeared to be similar regardless of SSC differences among the studied streams, while the variation of diatom density was manifested with SSC. The relative abundance of dominant benthic diatoms varied with SSC. Saprophilic diatoms were dominant in the streams of LSC, while saproxenic diatoms were dominant in the streams of HSC. During the evaluation of biological water quality using the benthic diatom indices, Trophic Diatom Index (TDI) and Diatom Assemblage Index to organic water pollution (DAIpo), the streams of LSC generally showed poorer water quality than those of MSC (Middle stream shape complexity) and HSC. In particular, BOD, TP, and $PO_4$-P showed significant relationships with DAIpo. In conclusion, shape complexity of streams in the Seom River watershed showed a close relation with benthic diatom distribution. This relation seemed to primarily be resulted from the effect of proximate factors, such as water quality, which might be affected by the land use types determining the degree of SSC.

Safety Evaluation of Hazardous Metals Migrated in Tumbler Samples (유통 텀블러 제품에서 용출되는 유해금속 안전성평가)

  • Jang, Mi-Kyung;Son, Mi-Hui;Park, Sung-Hee;Cho, Yun-Sik;Ku, Eun-Jung;Chae, Sun-Young;Jeon, Jong-Sup;Lee, Myung-Jin
    • Journal of Food Hygiene and Safety
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    • v.37 no.3
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    • pp.166-172
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    • 2022
  • This study evaluated the migrant and residue tests of lead (Pb), cadmium (Cd), nickel (Ni), arsenic (As), and antimony (Sb) in 70 tumbler samples. The migration levels of hazardous metals in all the samples were within the migration limits outlined in the Korean standards and specifications for utensils, containers, and packages. Moreover, in all the tumbler samples, only Ni was detected in 0.5% citric acid solution of a food stimulant. The maximum level of Ni 0.0144 mg/L was 14.4% of the migrant specification (not more than 0.1 mg/L), which was relatively safe. The 0.5% citric acid solution was eluted at 4℃, 70℃, and 100℃ for 30 min, and only Ni was detected while testing for migration levels according to the temperature variations; all temperature conditions conformed to the standards. The level of Ni migration increased significantly with increasing migration temperature. Regarding the residue level outside the paint-coated tumbler samples, the Pb level was found to range from N.D. to 20638.1323 mg/kg. The risk of Ni was further estimated to be at a safe level of 0.00 to 0.01% compared to the %TDI as a result.

Investigation on the Safety of Biodegradable Synthetic Resins for Food (식품용 생분해성 합성수지제의 안전성 조사)

  • Hee-Jeong Yun;Jong-Sup Jeon;Young-Su Kim;Sung-Hee Park;Seo-Hyeon Song;Eun-Jung Ku;Sun-Young Chae;Myung-Jin Lee
    • Journal of Food Hygiene and Safety
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    • v.39 no.2
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    • pp.95-101
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    • 2024
  • In this study, we investigated the migration level of items specified in the Korean Standards and Specifications for Utensils, Containers, and Packages (Ministry of Food and Drug Safety Notification) for 50 utensils and hygiene products made of biodegradable resins. Our results revealed that one Polylactide (PLA) baby tableware contained 20 mg/L in consumption of potassium permanganate, exceeding the standard of 10 mg/L or less. In all other samples, formaldehyde, lead (Pb), and arsenic (As) levels could be considered very safe and remained below the standard. Moreover, we tested the PLA baby tablewares (n = 21) for migration into a food simulant (4% v/v acetic acid) upon repeated elution at 100℃ for 30 min or UV irradiation for 2 h. We detected increased formaldehyde and As amounts at the repeated 100℃ treatment for 30 min compared to those upon repeated UV irradiation. However, the migration level was markedly low under both conditions. Furthermore, the Estimated Daily Intake (EDI) calculated on an infant-to-child basis from the formaldehyde and As migration at 100℃ for 30 min in the PLA sample was at the maximum value, i.e., 6.0×10-4 mg/kg b.w./day and 1.3×10-1 ㎍/kg b.w./day, corresponding to 0.40% and 10.42% of the Tolerable Daily Intake (TDI, 0.15 mg/kg b.w./day) and Provisional Tolerable Weekly Intake (PTWI, 9.0 ㎍/kg b.w./week), respectively. Therefore, in this study, we confirmed that biodegradable synthetic resins are safe to use for food.

Health Assessment of the Nakdong River Basin Aquatic Ecosystems Utilizing GIS and Spatial Statistics (GIS 및 공간통계를 활용한 낙동강 유역 수생태계의 건강성 평가)

  • JO, Myung-Hee;SIM, Jun-Seok;LEE, Jae-An;JANG, Sung-Hyun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.18 no.2
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    • pp.174-189
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    • 2015
  • The objective of this study was to reconstruct spatial information using the results of the investigation and evaluation of the health of the living organisms, habitat, and water quality at the investigation points for the aquatic ecosystem health of the Nakdong River basin, to support the rational decision making of the aquatic ecosystem preservation and restoration policies of the Nakdong River basin using spatial analysis techniques, and to present efficient management methods. To analyze the aquatic ecosystem health of the Nakdong River basin, punctiform data were constructed based on the position information of each point with the aquatic ecosystem health investigation and evaluation results of 250 investigation sections. To apply the spatial analysis technique, the data need to be reconstructed into areal data. For this purpose, spatial influence and trends were analyzed using the Kriging interpolation(ArcGIS 10.1, Geostatistical Analysis), and were reconstructed into areal data. To analyze the spatial distribution characteristics of the Nakdong River basin health based on these analytical results, hotspot(Getis-Ord Gi, $G^*_i$), LISA(Local Indicator of Spatial Association), and standard deviational ellipse analyses were used. The hotspot analysis results showed that the hotspot basins of the biotic indices(TDI, BMI, FAI) were the Andong Dam upstream, Wangpicheon, and the Imha Dam basin, and that the health grades of their biotic indices were good. The coldspot basins were Nakdong River Namhae, the Nakdong River mouth, and the Suyeong River basin. The LISA analysis results showed that the exceptional areas were Gahwacheon, the Hapcheon Dam, and the Yeong River upstream basin. These areas had high bio-health indices, but their surrounding basins were low and required management for aquatic ecosystem health. The hotspot basins of the physicochemical factor(BOD) were the Nakdong River downstream basin, Suyeong River, Hoeya River, and the Nakdong River Namhae basin, whereas the coldspot basins were the upstream basins of the Nakdong River tributaries, including Andong Dam, Imha Dam, and Yeong River. The hotspots of the habitat and riverside environment factor(HRI) were different from the hotspots and coldspots of each factor in the LISA analysis results. In general, the habitat and riverside environment of the Nakdong River mainstream and tributaries, including the Nakdong river upstream, Andong Dam, Imha Dam, and the Hapcheon Dam basin, had good health. The coldspot basins of the habitat and riverside environment also showed low health indices of the biotic indices and physicochemical factors, thus requiring management of the habitat and riverside environment. As a result of the time-series analysis with a standard deviation ellipsoid, the areas with good aquatic ecosystem health of the organisms, habitat, and riverside environment showed a tendency to move northward, and the BOD results showed different directions and concentrations by the year of investigation. These aquatic ecosystem health analysis results can provide not only the health management information for each investigation spot but also information for managing the aquatic ecosystem in the catchment unit for the working research staff as well as for the water environment researchers in the future, based on spatial information.

Dispersity of CNT and GNF on the Polyurethane Matrix: Effect of Polyurethane Chemical Structure (폴리우레탄 분자구조 변화에 따른 CNT와 GNF의 분산특성 연구)

  • Im, Hyun-Gu;Kim, Hyo-Mi;Kim, Joo-Heon
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.340-346
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    • 2008
  • The aim of this study is to understand the effect of structure on the dispersion of both CNT and GNF in the phase of synthesized polyurethanes matrix. Various CNT/PU and GNF/PU composite films were prepared. Polyurethane having a different hard segment was blended with both CNT and GNF. PU having HDI as hard segment showed good dispersion with both CNT and GNF because of their linear structural character and molecular kinesis while PU having aromatic ring showed poor dispersion with those due to their structural complexity. Structural effect also induced the increase of its electro conductivity. The PU/CNT composite showed a bad dispersion (because of phase separation between PU matrix and CNT) but good electro conductivity at its surface (because CNT was collected on the surface of composite film due to low density of CNT). PU/CNT and PU/GNF composite films have quite low normalized sheet resistance value compared with silver/PU nanocomposite film because the fiber type filler could have much more contact points than that of sphere shaped silver particles have.

Analysis of Stream Ecosystem Health in Headwater Areas Using Landcover Data (소하천 수변 토지피복에 따른 하천 건강성 분석)

  • Han, Dae-Ho;Kim, Ik-Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.496-500
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    • 2009
  • 소하천은 하천 네트워크의 최상류에 넓게 소재하는 하천이다. 본 연구의 목적은 올바른 소하천 수생태계 관리방안을 도출하기 위하여 소하천의 건강성을 분석하고 현행 소하천 관리제도의 개선점을 모색하는 것이었다. 본 연구에서는 다음과 같은 분석방법을 이용하였다. 첫째, 2007년 한강수계 소하천 28개 지점에서의 부착조류($DAI_{PO}$, TDI), 저서성 대형무척추동물(KSI), 어류(IBI), 서식환경, 수변환경 등 6개 항목에 대한 수생태 건강성 조사결과를 토대로 공간적 분포와 수질현황을 조사하여 소하천에 대한 종합적인 건강성 평가를 실시하였다. 둘째, 분석대상지역을 각각 소하천 구간스케일(28개 지점)과 유역스케일(팔당호, 안성천 유역)로 선정, 하천차수도(1:25,000)를 활용하여 해당 구간과 유역의 소하천도를 작성하였다. 셋째, 작성된 소하천도 는ArcGIS(ver. 9.3)에서 30, 60, 90, 120, 150-m Buffering을 하였다. 다음으로 소하천 구간은 중분류(23개 항목, $2000{\sim}2006$ 또는 2007년) 토지피복도를, 팔당호 및 안성천 유역의 소하천은 대분류(8개 항목, $1975{\sim}2000$년) 토지피복도를 적용하여 분류항목별 면적변화비율을 산정하였다. 끝으로 소하천 정비에 대한 제도적 문제점을 분석하여 소하천 관리의 개선점을 연구하였다. 그 연구 결과, 첫째 연구대상 소하천(28개)의 건강성은 도심 소하천에서 가장 낮게 조사되었고, 일부 소하천은 비록 상류에 위치함에도 불구하고 부착조류의 유기물, 영양염류 평가가 낮게 평가되었다. 둘째, 소하천 구간 스케일의 수변토지피복변화 분석결과 소하천 수생태 건강성은 거시적으로 산림, 도시화, 밭 등의 피복변화에 민감한 것으로 나타났으며 도시화 피복변화의 영향은 수변 30m에서 60m보다 3배 정도 큰 것으로 나타났다. 유역 스케일 분석에서는 상대적으로 도시화가 많이 진행된 안성천 유역의 소하천이 팔당호 유역보다 낮은 건강성일 것으로 예측되었다. 결론적으로 적절한 소하천 수변관리는 지역 하천의 건강성을 온전히 회복시키고 개선 유지하기 위한 중요한 수단들 중에 하나이며 수변토지피복의 변화율은 (소)하천 건강성 또는 유역관리의 지표로 활용될 수가 있는 것으로 조사되었다. 이와 더불어 본 연구를 통해 소하천 복원 및 관리는 소하천 특성을 고려한 장기적인 계획과 관리대상의 우선순위를 바탕으로 점진적인 대안마련이 필요할 것으로 사료된다.

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Geochemistry and Mineralogy of Mine Drainage Water Precipitate and Evaporite Minerals in the Hwasoon Area (화순 폐탄광지역 광산배수와 침전 및 증발잔류광물에 대한 지구화학적 및 광물학적 연구)

  • 박천영;정연중;강지성
    • Economic and Environmental Geology
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    • v.33 no.5
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    • pp.391-404
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    • 2000
  • This study investigated the geochemical characteristics of mine drainage discharged from an abandoned coal mine in the Hwasoon area. Surface water samples were collected from 23 locations along the Hancheon creek. The concentration of Zn and Cu in stream waters was highest at low pH (3.53), whereas the content of TDS and TDI was highest at high pH (7.78) due to the concentration of Ca, $HCO_3$ and $SO_4$. At the upstream site, the Ba, Fe, Mn, Zn, and $SO_4$ contents were relatively high but decreased significantly with the distance from the coal mine. On the contrary, the Na and $NO_3$ contents were low at the upstream site but increased downstream. Yellow precipitate material collected in the Hancheon consisted mainly of iron and LOI. This yellow precipitate was heated from 100 to $900^{\circ}C$ for 1 hour. With increasing temperature, the intensity of hematite peaks were sharply produced in X-ray pattern and the absorption band Fe-O of hematite increased in IR due to dehydration and melting. The yellow to brown precipitate and evaporite materials were collected by a air-dry from the acid mine water at the laboratory. After drying, the concentration of ions in the acid water samples increased progressively in oversaturation with respect to either gypsum, ferrohexahydrite or quenstedetite. The X-ray powder diffraction studies identified that the precipitated and evaporated materials after drying were well crystallized gypsum, ferrohexahydrite and quenstedetite. Diagnostic peaks used for identification of gypsum were the 7.65, 4.28, 3.03, 2.87 and 2.48$\AA$ peaks and those for ferrohexahydrite were the 5.46, 5.12, 4.89, 4.44, 4.05, 3.62, 3.46, 3.40, 3.20, 3.03, 2.94, 2.53, 2.28, 2.07, 1.88 and 1.86${\AA} peaks. The IR spectra with OH-stretching, deformation of $H_2O$and ${SO_4}^{2-}$stretching vibration include the existence of gypsum, ferrohexahydrite and quenstedetite in the precipitated and evaporite materials. In the SEM and EDS analysis for the evaporite material, gypsum with well-crystallized, acicular, and columnar form was distinctly observed.

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