• Title/Summary/Keyword: TBB

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Effects of Dipping in Tooth Reserving Solution on Bond Strength of 4-META/MMA-TBB Dentin Bonding System.

  • Kubota, M.;Yanagidani, T.;Hashimoto, M.;Kudou, Y.
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.569.1-569
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    • 2001
  • The purpose of this investigation was to determine the effect of dipping in tooth reserving solution on bond strength of 4-META/MMA-TBB dentin bonding system. The flattened dentin surface of bovine lower incisor was used for this investigation. The tooth were dipped in the tooth reserving solution (ViaSpan; Du Pont Pharmatical / Teeth Server "NEO";Neo Dental Chemical products CO/LTD, Japan/ Saline, Fuso Chemical CO, LTD, Japan) for 30 min.(omitted)

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Examples of clinical applications of flexible composite resin that is quite different from conventional composite resins (Conventional composite resin과 사뭇 다른 flexible composite resin의 여러 임상 활용 예)

  • Kim, Woohyun
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.29 no.2
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    • pp.92-102
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    • 2020
  • Bond-Fill SB is made of powder/liquid, and the flowability can be controlled by adjusting the amount of liquid in the brush. Thanks to the strong catalyst called TBB, it has the advantage of being able to polymerize even in the presence of water and oxygen. Also, since it contains 4-META, it has the advantage of being able to adhere to metals and ceramics with appropriate surface treatment. If you fully understand these advantages, you can actively utilize them in cases where it is difficult to treat with conventional composite resin.

EFFECT OF COBALT-CHROMIUM ALLOY SURFACE TREATMENT WHEN BONDING WITH 4-META/MMA-TBB RESIN (Cobalt-Chromium 합금의 표면처리가 4-META/MMA-TBB 레진과의 접착에 미치는 영향)

  • Jin, Jae-Sik;Kim, Kyo-Han;Lee, Cheong-Hee;Jo, Kwang-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.4
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    • pp.510-525
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    • 2000
  • The effects of pretreatment of Co-Cr alloy, including two adhesive primers that contain either MDP or MAC-10, and silicoating on the bond The result sobtained as follows; o Strength of 4-META/MMA-TBB resin were investigated using FT-IR, SEM, and EDAX. o In the SEM observation of surface morphologies, the sandblasted specimen exibited a very rough surface, whereas the surfaces of the two groups primed with either MDP or MAC-10 were covered with a layer of primer, and the surface morphology of the silicoated specimen remained almost the same after sandblasting. o Before the thermocycling tests, the group treated with MDP demonstrated the highest mean tensile bond strength and the sandblasted group showed the lowest bond strength. o After 20,000 thermocyling, the mean tensile bond strength of the sandblasted group exhibited a 50% reduction in bond strength, while the others showed a $20\sim30%$ reduction. o Observation of the metal-resin interface revealed that in all groups the resin permeated the rough surface formed by sandblasting thereby producing a mechanical bond between the metal and the resin. It was also found that thermocycling resulted in a gap formation at the metal-resin interface of the specimens, and the sandblasted group exhibited a larger gap width than the other groups. o In fracture mode, all specimens indicated a cohesive fracture within the resin before thermocycling. However, thermocyling produced adhesive failure at the edge of the resin-metal interface in most specimens. The sandblasted group, which exhibited the lowest bond strength after thormocycling, also demonstrated the largest area of adhesive failure.

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Synthesis and Characterization of a New PPV Derivative Containing a Sterically Hindered 2,5-Dimethylphenyl Group

  • Kim, Yun-Hi;Lee, Hyun-Ouk;Lee, Ki-Suk;Kwon, Soon-Ki
    • Macromolecular Research
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    • v.11 no.6
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    • pp.471-475
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    • 2003
  • A new poly[2-(2',5'-dimethylphenyl)-1,4-phenylenevinylene] (PDMPPV) that features a bulky 2',5'-dimethylphenyl substituent, which can induce steric hindrance between the PPV backbone and the methyl groups, was designed and synthesized. The polymer structure having no TBB defects was confirmed by $^1$H-NMR and $\^$13/CNMR spectroscopy. The polymer showed good thermal stability with high T$\_$g/. The polymer film showed a maximum absorption at 415 nm with an absorption onset at 480 nm. The maximum emission peak showed at ca. 515 nm, with a shoulder at 530 nm. The turn-on voltages of ITO/PEDOT/PDMPPV/Al and ITO/PDMPPV/Al devices were 8 and 10 V, respectively. The electroluminescence spectrum from the device showed a maximum peak at 510 nm with a shoulder at ca. 535 nm.

Effects of Pretreatment Method on the Bonding Strength of 4-META/MMA-TBB Resin to Bovine Dentin (상아질 전처리방법이 4-META/MMA-TBB계 레진의 접착강도가 미치는 영향)

  • 김교한;김영빈
    • Journal of Biomedical Engineering Research
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    • v.16 no.4
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    • pp.533-542
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    • 1995
  • The present study investigated the effectiveness of pretreatment on dentin bonding. The adhesive resin was 5% 4-methacryloyloxyethyl trimellitate anhydride (4-META) in methyl methacrylate (MMA) combined with poly-MMA powder. Polymerization of this resin was initiated by tri-n-butyl borage (TBB). Ground bovine dentin samples were etched with either an aqueous solution of 10% citric (10-0 solution) (Group I) or aqueous solution of 10% citric acid and 3% ferric chloride(10-3 solution) (Group ll ). After etching, the primer (an aqueous solution of 35% hydroxyethyl methacrylate (HEM- A) and 5% glutaraldehyde was applied on the differently etched surfaces (Group III , Group IV). The 10-0 treatment showed the lowest tensile bond strength, followed by the 10-3 treatment, primer application after the 10-0 treatment and primer application after the 10-3 treatment. The relationship among the surface morphology after pretreatment, fractured surface morphology and tensile bond strength was examined. It revealed that the surface morphology change by different pretreatment influenced the bond strength and the resulting fractured surface morphology. The correlation of tensile bond strength with the fracture morphology was explained.

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Cyclic Structural Characteristics of Thermal Bridge Breaker Systems embedded in Reinforced Concrete Slabs (벽-슬래브 접합부에 매립된 열교차단장치의 반복하중에 대한 거동특성 평가)

  • Shin, Dong-Hyeon;Oh, Moung-Ho;Kim, Young-Ho;Kim, Hyung-Joon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.28 no.5
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    • pp.511-521
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    • 2015
  • The thermal bridge occurring in a building influences its thermal performance and durability. The domestic typical multi-unit residential buildings suffer thermal losses resulting from thermal bridges of the balcony slab. To minimize the thermal loss between inside and outside of the balcony slab, thermal bridge breaker(TBB) systems have been developed and applied in building construction. Although thermal bridge breaker systems for reinforced concrete(RC) wall-slab joints can improve the thermal performance of a building, it is necessary to verify the structural performance of TBB systems whether they provide proper resistance for cyclic loading. In order to investigate the structural characteristics of TBB systems embedded in RC slabs, cyclic tests of wall-slab joints were performed by applying two reversed cycles at each up to 30 cycles. The test results show that the RC slabs embedding TBBS systems can present excellent structural performance and the maximum moment capacity, energy dissipation capacity and ductility of TBBs systems are enhanced compared to those of the typical RC slabs.

EFFECT OF METAL PRIMER TREATMENT OF THE Au-Ag-PD ALLOY SURFACE ON THE METAL-RESIN BONDING (치과용 금-은-팔라디움 합금에 대한 프라이머 처리가 금속-레진 접착에 미치는 영향)

  • Lee Kang;Lee Cheong-Hee;Jo Kwang-Hun;Kim Kyo-Han
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.4
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    • pp.417-432
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    • 2001
  • The pcf metal primers on the bond strength and durability of 4-META/MMA-TBB resins adhered to an Au-Ag-Pd alloy. For this study, the specimens were divided into 8 groups as follows: Thermocyle 0 : (1) control group : sandblast, (2) Group I : sandblast + Cesead Opaque Primer; (3) Group II : sandblast + Metal Primer; (4) Group III : sandblast + V-Primer; Thermocyle 10,000 (5) control sandblast: (6) Group I : sandblast + Cesead Opaque Primer: (7) Group II : sandblast + Metal Primer; (8) Group III sandblast + V-Primer. The shear bond strength was determined using an Instron were observed with the use of scanning electron microscope. Finally, the strengths of bonded joints were evaluated with regard to their adherence energy using a wedge test. The results obtained were as follows ; (1) The shear bond strength of 4-META/MMA-TBB resin to the Au-Ag-Pd alloy was significantly improved in all the groups treated with the primers (p<0.05). (2) Regardless of the adhesive primers used, a significant difference was observed in the bond strength of the thermocycle 0 groups and 10,000 groups (p<0.05). (3) Both before and after thermocycling, the strongest bond strength between the resin an the alloy was obtained after treatment with a metal primer containing MEPS (p<0.05). (4) In the wedge test, the adherence energies of the control group and Group III decreased more rapidly than those of Group I and II during the 2nd day of storage in water.

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Separation Characteristics of Ibuprofen in Kromasil HPLC Column (Kromasil HPLC 칼럼을 이용한 Ibuprofen의 분리특성 연구)

  • Park Joon Sub;Kim Byung Lip;Yoon Tae Ho;Kim In Ho
    • KSBB Journal
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    • v.20 no.3
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    • pp.244-249
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    • 2005
  • Chiral separation of racemic ibuprofen was achieved on a Kromasil KR100-5CHI-TBB column. Some chromatographic parameters (resolution, number of theoretical plates, HETP, capacity factor) are calculated under different separation conditions such as change of mobile phase compositions (hexane / t-BME : 85 / 15, 75 / 15, 65 / 35, 55 /45) as well as acetic acid concentrations for adjusting pH (0.1 to 1 $v/v\%$). Flow rate versus number of theoretical plates and HETP were compared to evaluate column efficiency. To determine the adsorption isotherms, PIM (Pulsed Input Method) was carried out. At concentrations of racemic ibuprofen between 0.1 and 0.3 mg/ml, S- and R-ibuprofen have the same retention time of 4.48 and 5.81 min. Ibuprofen isotherms show a linear form under concentrations of 0.3 mg/ml with eluent (hexane / t-BME = 55 / 45).

Application of Images and Data of Satellite to a Conceptual Model for Heavy Rainfall Analysis (호우사례 분석을 위한 개념모델 구성에 위성영상과 위성자료의 활용 연구)

  • Lee, Kwang-Jae;Heo, Ki-Young;Suh, Ae-Sook;Park, Jong-Seo;Ha, Kyung-Ja
    • Atmosphere
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    • v.20 no.2
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    • pp.131-151
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    • 2010
  • This study establishes a conceptual model to analyze heavy rainfall events in Korea using multi-functional transport satellite-1R satellite images. Three heavy rainfall episodes in two major synoptic types, such as synoptic low (SL) type and synoptic flow convergence (SC) type, are analyzed through a conceptual model procedure which proceeds on two steps: 1) conveyer belt model analysis to detect convective area, and 2) cloud top temperature analysis from black body temperature (TBB) data to distinguish convective cloud from stratiform cloud, and eventually estimate heavy rainfall area and intensity. Major synoptic patterns causing heavy rainfall are Changma, synoptic low approach, upper level low in the SL type, and upper level low, indirect effect of typhoon, convergence of tropical air in the SC type. The relationship between rainfall and TBBs in overall well resolved areas of heavy rainfall. The SC type tended to underestimate the intensity of heavy rainfall, but the analysis with the use of water vapor channel has improved the performance. The conceptual model improved a concrete utilization of images and data of satellite, as summarizing characteristics of major synoptic type causing heavy rainfall and composing an algorism to assess the area and intensity of heavy rainfall. The further assessment with various cases is required for the operational use.