• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2748-2752
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• 2012

Cr(III) and Co(III) complexes with acetylacetonate were anchored onto a mesoporous MCM-41 through Schiff condensation. The materials were characterized by XRD, FT-IR, BET, CHN and ICP techniques. Elemental analysis of samples revealed that one C=N bond was formed through Schiff condensation on MCM-41 surface. The catalysts were tested for the alcohol oxidations using t-butyl hydroperoxide (TBHP) and $H_2O_2$ as oxidant. The catalytic experiments were carried out at both room temperature and reflux condition. Various solvents such as dichloromethane, acetonitrile and water were examined in the oxidation of alcohols. Among the different solvents, catalytic activity is found more in acetonitrile. Further, the catalysts were recycled three times in the oxidation of alcohols and no major change in the conversion and selectivity is observed, which shows that the immobilized metal-acetylacetonate complexes are stable under the present reaction conditions.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.782-784
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• 2008

Ag/Ni bimetallic cluster loading on porous carbon fibers was accomplished in order to enhance the HCl removal efficiency of the carbons. The surface properties of the Ag/Ni/carbons were determined by XRD and SEM. N2/77 K adsorption isotherms were investigated using BET and Boers t-plot methods. The HCl removal efficiency was confirmed by a gas chromatography technique, and it was found that that efficiency was predominantly improved in the presence of Ag/Ni clusters compared with the efficiencies of the as-received and single-metal-plated carbons. This indicates that synergetic reactions exist between Ag/Ni and HCl gas, resulting in advanced HCl removal capacity of porous carbons.

• 상하수도학회지
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• 제25권5호
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• pp.719-724
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• 2011

The excessive phosphate in water causes eutrophication which destroys water environment. In this study, mesoporous silica was synthesized and several functional groups were attached on it. Samples were tested to identify the ability to remove phosphate. The structures of synthesized materials were analyzed by X-ray diffractions (XRD), Fourier transform-infrared (FT-IR) and surface area analysis, Brunauer-Emmett-Teller (BET). To determine the maximum phosphate adsorption capacities and sorption rate, the equilibrium test and kinetic test was conducted. Among functionalized SBA-15 samples, pure SBA-15 didn't adsorb phosphate but Al-SBA-15 and Ti-SBA-15 showed good performances to remove phosphate. The maximum phosphate adsorption capacity of Al-SBA-15 was efficient compared to other adsorbents.

• 설비공학논문집
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• 제14권2호
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• pp.108-115
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• 2002

The fundamental mechanism of a dispersed two-phase flow was investigated. Experiments were carried out to understand how the particles behaves under the influence of the particle size, shape, metamorphoses (bubble) and buoyancy of a single particle which is ascending from the standstill water. Two CCD cameras were employed for image processing of the behavior of the particles and the surrounding flow, which was interpreted with the technique of correlation PIV (Particle Image Velocimetry) and PTV (Particle Tracking Veloci- metry), respectively The experimental results showed that the large density difference bet- ween a particle and water caused high relative velocity and induced zigzag motion of the particle. Furthermore, the turbulence intensity of a bubble was about twice the case of the spherical solid particle of similar diameter.

• Carbon letters
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• 제7권1호
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• pp.9-18
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• 2006

Activated carbons were obtained by activating wild cherry stones with different concentrations of phosphoric acid or zinc chloride at different temperatures. The adsorption of $N_2$ at 77 K and of $CO_2$ at 273 K was followed and the data were analyzes by considering different adsorption models. The activated carbons obtained measured high surface area with the most of the surface in all samples located in micropores. Fair agreement was found between the nitrogen surface areas calculated from the BET-, t-, ${\alpha}$- and DR- methods, although the first three are based on surface coverage whereas the latter is based on micropore filling. The carbon dioxide surface areas calculated by the DA equation were smaller than the comparable nitrogen areas. This was ascribed to domination of surface coverage mechanism, the absence of activated diffusion process. Based on this explanation the $CO_2$-surface areas as calculated by DA equation should be taken with great reservation.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1856-1860
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• 2012

$SnO_2/SiO_2$ nanocomposite has been synthesized by using sol-gel method. Prepared catalytic materials has been well characterized by using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmer-Teller (BET) surface area, and temperature-programmed desorption of ammonia ($NH_3$-TPD). $SnO_2/SiO_2$ nanocomposite catalyzed synthesis of 2-arylbenzothiazoles by the cyclocondensation of 2-aminothiophenol and aromatic aldehydes under reflux condition in 1:1 EtOH:$H_2O$. After completion of the reaction, catalyst can be recovered efficiently and reused with consistent activity.

• 한국세라믹학회지
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• 제27권5호
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• pp.613-618
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• 1990

The pure and 6mol% MgO-doped ZrO2 powders were prepared by hot petroleum drying method. The power characterization of homogeneous fine powder was indentified by the method of thermal analysis, BET and electron microscope. The transformation, content of t-ZrO2, crystallite size and apparent strain were measured by X-ray diffraction technique. The prepared powders were transformed in order of amorphouslongrightarrowmetastable cubic ZrO2longrightarrowmetastable tetragonal ZrO2longrightarrowstable monoclinic ZrO2 by a adequate heat treatment. The stabilization of metastable phase can be discussed in terms of energetial concept ; the difference of surface energy and internal strain in particle.

• Asia Marketing Journal
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• 제15권4호
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• pp.187-200
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• 2014

The case study of OB shows dramatic market dynamics between leader brand vs. follower brand similar to Kirin vs. Asahi in Japan for two decades. Almost 20yrs ago, the brand status of OB was dramatically fallen because of the environmental pollution of subsidiary company and harsh competition of rivalry brand. But OB made a ground change in its brand strategy. OB departed from the pride in its past to bet on the new. OB decided to vitalize Cass brand through brand portfolio strategy. They deployed 3 phase articulated marketing plans; Phase I, Acquisition of Cass brand through M&A and strategic segmentation/targeting (1993-2005), Phase 2 - Mega Brand Strategy through Line Extension(2006-2009), Phase 3 - Experiential Marketing focused on Young Culture (2010- present). Finally, OB restored not only brand reputation of Cass and other brands but dominant market position in beer market. Now Cass has been growing rapidly in the last 20 years achieving 50% M/S. The three phases shows the typical successful process of brand management and revitalization adopting brand concept management and S-T-P strategy of manufacturing company.

• 한국염색가공학회지
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• 제11권5호
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• pp.22-29
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• 1999

The increase in color depth of polyester fiber dyed with black disperse dyes was investigated with respect to the kinds of resins and alkali treatment. The color depth of the dyed polyester fiber increased continuously according to the concentration of resins coated onto the fabrics. The alkali treatment to polyester fiber before dyeing also enhanced the color depth. It was thought that the polyester fiber was hydrolyzed by alkali resulting micropores on the sample. And the following treatment with a resin, Jet Black T-101, to the polyester fiber increased the color depth much higher. The successive process of alkali treatment, dyeing and Jet Black T-101 treatment could give the best color depth to polyester fiber. Although the alkali treatment reduced the tensile strength of polyester fiber, the color depth of polyester fiber enhanced sufficiently within the range of practically acceptable weight loss and strength. To analyze the micropore on the polyester fiber formed by alkali treatment, nitrogen porosimeter was used. As the weight loss of polyester fiber treated with alkali increased, the BET(Brunauer-Emmett-Teller) surface area, total pore volume, and average pore size of the sample increased.

• 한국농공학회지
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• 제45권4호
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• pp.66-77
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• 2003

Monitoring data from agricultural reservoirs throughout the country were analyzed to classify agricultural reservoirs according to physical characteristics and COD concentrations, and evaluate the relationships bet-ween water quality items. The physical and chemical data of total 498 reservoirs were analyzed from 1990 to 2001. Average COD, TP, TN, Chl-a, SS concentrations for the reservoirs and pollutant loadings from their watersheds were used for the analysis. It was possible that reservoirs were classified to 4 types using the relationships between the ratios of effective storage per water surface (ST/WS ratio) and COD concentrations. It is recommended that the improvement measures of polluted reservoirs should be performed as following order : integrated consolidation type (complex mechanism type) $\rightarrow$ watershed consolidation type $\rightarrow$ integrated consolidation type (external mechanism type) $\rightarrow$ in-lake consolidation type $\rightarrow$ conservation type and the depth (ST/WS ratio) of reservoir maintained over 5~6 m for water quality improvement. The decision coefficients ($r^2$) between Chl-a and other items (COD, T-P, SS, T-N) were 0.6915, 0.6732, 0.5327, 0.3352, respectively. Therefore, reservoir managers could evaluate the trophic state of reservoirs by COD concentrations.