• Title/Summary/Keyword: T-P Removal

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Nitrogen Removal Rate of A Subsurface Flow Treatment Wetland System Constructed on Floodplain During Its Initial Operating Stage (하천고수부지 수질정화 여과습지의 초기운영단계 질소제거)

  • Yang, Hong-Mo
    • Korean Journal of Environmental Agriculture
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    • v.22 no.4
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    • pp.278-283
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    • 2003
  • This study was carried out to examine the nitrogen removal rate of a subsurface-flow treatment wetland system which was constructed on floodplain of the Kwangju River from May to June 2001. Its dimensions were 29m in length, 9m in width and 0.65m in depth. A bottom layer of 45cm in depth was filled with crushed granite with about $15{\sim}30\;mm$ in diameter and a middle layer of 10cm in depth had pea pebbles with about 10 mm in diameter. An upper layer of 5 cm in depth contained course sand. Reeds (Phragmites australis) were transplanted on the surface of the system. They were dug out of natural wetlands and stems were cut at about 40 cm height from their bottom ends. Water of the Kwangju River flowed into it via a pipe by gravity flow and its effluent was funneled back into the river. The height of reed stems was 44.2 cm in July 2001 and 75.3cm in September 2001. The number of stems was increased from $80\;stems/m^2$ in July 2001 to $136\;stems/m^2$ in September 2001. Volume and water quality of inflow and outflow were analyzed from July 2001 through December 2001. Inflow and outflow averaged 40.0 and $39.2\;m^3/day$, respectively. Hydraulic detention time was about 1.5 days. Average nitrogen uptake by reeds was $69.31\;N\;mg/m^2/day$. Removal rate of $NO_3-N$, $NH_3-N$, T-N averaged 195.58, 53.65, and $628.44\;mg/m^2/day$, respectively. Changes of $NO_3-N$ and $NH_3-N$ abatement rates were closely related to those of wetland temperatures. The lower removal rate of nitrogen species compared with that of subsurface-flow wetlands operating in North America could be attributed to the initial stage of the system and inclusion of two cold months into the six-month monitoring period. Increase of standing density of reeds within a few years will develop both root zones suitable for the nitrification of ammonia and surface layer substrates beneficial to the denitrification of nitrates into nitrogen gases, which may lead to increment in the nitrogen retention rate.

Effect of Triticale Dried Distillers Grains with Solubles on Ruminal Bacterial Populations as Revealed by Real Time Polymerase Chain Reaction

  • Wu, R.B.;Munns, K.;Li, J.Q.;John, S.J.;Wierenga, K.;Sharma, R.;Mcallister, T.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.11
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    • pp.1552-1559
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    • 2011
  • Real time PCR was used in this study to determine the effect of triticale dried distillers grains with solubles (TDDGS) as a replacement for grain or barley silage in finishing diets on the presence of six classical ruminal bacterial species (Succinivibrio dextrinosolvens, Selenomonas ruminantium, Streptococcus bovis, Megasphaera elsdenii, Prevotella ruminicola and Fibrobacter succinogenes) within the rumen contents of feedlot cattle. This study was divided into a step-wise adaptation experiment (112 days) that examined the effects of adaptation to diets containing increasing levels of TDDGS up to 30% (n = 4), a short-term experiment comparing animals (n = 16) fed control, 20%, 25% or 30% TDDGS diets over 28 days, and a rapid transition experiment (56 days) where animals (n = 4) were rapidly switched from a diet containing 30% TDDGS to a barley-based diet with no TDDGS. It was found that feeding TDDGS as replacement for barley grain (control vs. 20% TDDGS) decreased 16S rRNA copy numbers of starch-fermenting S. ruminantium and S. bovis (p<0.001 and p = 0.04, respectively), but did not alter 16S rRNA copy numbers of the other rumen bacteria. Furthermore, feeding TDDGS as a replacement barley silage (20% vs. 25% and 30% TDDGS) increased 16S rRNA copy numbers of S. ruminantium, M. elsdenii and F. succinogenes (p<0.001; p = 0.03 and p<0.001, respectively), but decreased (p<0.001) the 16S rRNA copy number of P. ruminicola. Upon removal of 30% TDDGS and return to the control diet, 16S rRNA copy numbers of S. ruminantium, M. elsdenii and F. succinogenes decreased (p = 0.01; p = 0.03 and p = 0.01, respectively), but S. dextrinosolvens and S. bovis increased (p = 0.04 and p = 0.009, respectively). The results suggest that replacement of TDDGS for grain reduces 16S rRNA copy numbers of starch-fermenting bacteria, whereas substitution for barley silage increases 16S rRNA copy numbers of bacteria involved in fibre digestion and the metabolism of lactic acid. This outcome supports the contention that the fibre in TDDGS is highly fermentable.

A study on characteristic by isolation of nitrogen synthetic microorganism and ammonia nitrogen removal in artificial wastewater (질소 합성 균주의 분리에 의한 특성검토와 합성폐수중의 암모니아성질소 제거)

  • Kim, Su-Il;Lee, Ki-Hyung;Phae, Jae-Gun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.3
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    • pp.117-125
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    • 2002
  • This study experimented a possibility of advanced treatment through microorganism that converts $NH_3-N$ to organic nitrogen in wastewater contaminated by ammoniac nitrogen unlike conventional nitrogen removal process. After distributing three kinds of special bacteria that use $NH_3-N$ as a substrate, when those bacteria were cultured in no salt condition and salt condition (3% NaCl), M11 showed better growth in salt condition and M12 showed better growth in no salt condition. However M7l grew well in both no salt condition and salt condition. In the test of glucose effect, maximum growth and removal rate were observed in glucose concentration of 5g/L but in high concentration (1000mg/L as $NH_3-N$) of $NH_3-N$ growth and removal rate were low. Removal rate was the highest in 100mg/L $NH_3-N$ and the fact that concentration of $NO_2-N$ and $NO_3-N$ didn't increase assumed $NH_3-N$ was converted to organic nitrogen. Optimum concentration of $K_2HPO_4$ for phosphorous supply and buffer was 5g/L. Special bacteria distributed could use $NO_2-N$ and $NO_3-N$ as well as $NH_3-N$ as substrates. This study showed that when growth rate of bacteria was high removal rate also was high. It is possible to apply as a method to treat wastewater polluted by $NH_3-N$.

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Impact of Grit Chamber Deposits on Water Quality at the Mouth of Yeocheoncheon, Ulsan (여천천 하구에 설치된 침사지내 퇴적토의 수질영향분석)

  • Lee, Sang-Hyeon;Cho, Hong-Je
    • Journal of Environmental Science International
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    • v.25 no.8
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    • pp.1191-1206
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    • 2016
  • Transported deposit was accumulated in a grit chamber built at the mouth of Yeocheoncheon in 1987 with the intention of blocking the influx of sediment into the Ulsan-harbor. This study attempted to analyze the effects of the transported deposit on the water quality at Yeocheoncheon. Only one episode of dredging has been performed in the approximately 25 years since the grit chamber were built, leading to the formation of stagnant water in the grit chamber due to a large amount of transported deposit. The deposit has a relatively high organic content, in the range of 11.7-25.9% (mean 18.3%). It appears that the main reason for the upstream transport of water pollution from the mouth of the Yeocheoncheon is the tides. The effects of organic content and stagnant water on water quality were analyzed using WASP. Moreover, the changes in water quality arising due to the removal of the grit chamber were analyzed. Results indicated that BOD improved by 18.8-100%, while T-P improved by 90.0-617.4%, between the grit chamber and Hanbi-Gyo, which is located 1.3 km away from the grit chamber.

Pillared clays from natural resources as catalysts for catalytic wet peroxide oxidation: Characterization and kinetic insights

  • Kalmakhanova, Marzhan Seitovna;Diaz de Tuesta, Jose Luis;Kabykenovna, Bakytgul;Gomes, Helder Teixeira
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.186-196
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    • 2020
  • Pillared clays with Zr and Fe/Cu/Zr polycations have been prepared from natural clays found in large deposits of Kazakhstan and assessed as catalysts for the catalytic wet peroxide oxidation (CWPO), using 4-nitrophenol (4-NP) as model compound. The performance of the catalysts was followed by measuring the concentration of 4-NP, H2O2 and the total organic carbon (TOC), considering C4-NP = 5 g L-1, $C_{H_2O_2}$ = 17.8 g L-1, Ccat = 2.5 g L-1, initial pH = 3.0 and T = 50℃. At those selected conditions, the pillared clays showed higher activity than natural clays in the CWPO of 4-NP. The conversion of the model pollutant was complete when Fe/Cu/Zr-PILCs were used, with the TOC removal reaching 78.4% after 24 h with the best Fe/Cu/Zr-PILC. The H2O2, 4-NP and TOC time-evolution was well described by a kinetic model based on TOC lumps in three blocks, considering the initial TOC (corresponding to 4-NP), the production of oxidizable intermediates and the formation of refractory products.

Needlestick injuries in the dental hygienists (일부 치과위생사의 치과 주사바늘 상해 실태)

  • Jeon, Jeong-Mi;Lim, Soon-Ryun;Cho, Young-Sik
    • Journal of Korean society of Dental Hygiene
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    • v.15 no.5
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    • pp.751-757
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    • 2015
  • Objectives: The purpose of the study is to investigate the needlestick injuries in the dental hygienists. Methods: A self-reported questionnaire was completed by 253 dental hygienists by convenience sampling from December 1, 2014 to March 20, 2015. The questionnaire consisted of 11 questions of sociodemographic characteristics, 5 questions of needlestick injuries experience, 3 questions of needlestick injuries during treatment and 2 questions of needlestick handling method. Data were analyzed by chi-square test, t-test and one way ANOVA analysis using SPSS 18.0 statistical program. Results: Those who had needlestick injuries within a year were 150 persons (59.3%) and the mean was 1.28 times per year. The needlestick injuries were frequent in the local anesthetic injection to gum. The completion and removal of the needle injection by hand accidently stung the digits and hand (p<0.01). Conclusions: Needlestick injuries can happen at any time to the dental hygienists in the dental clinics, so it is necessary to handle the needlestick carefully in case of anesthetic injection.

A Study on the Equipment Type of Stream Purification System that Applies Combined Physicochemical and Biological Treatment (물리·화학적 및 생물학적 처리가 결합된 장치형 하천정화 시스템에 관한 연구)

  • Eom, Han Ki;Kim, Sung Chul;Kim, Sung Su;Kim, Sam Ju
    • Journal of Korean Society on Water Environment
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    • v.33 no.3
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    • pp.273-281
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    • 2017
  • The objective of this study is to evaluate the performance of stream purification equipment system combined MBP (Micro Bubble Process) and AGBP (Aerobic Granular Biofilm Process). Based on results, the optimal HRT (Hydraulic Retention Time) of MBP and AGBP set as 0.72 and 2.4 h, respectively. In the results of continuous operation on combined MBP and AGBP, it is possible to achieve a BOD, TSS and T-P removal efficiency of 85, 90 and 94%, respectively. It also confirmed that the water quality of the stream can be purified with increasing circulation flow through water simulation evaluation applied the QUAL-NIER model. Consequently this purification system can resolve the stream purification and dry stream problem.

Development of Thiourea-Formaldehyde Crosslinked Chitosan Membrane Networks for Separation of Cu (II) and Ni (II) Ions

  • Sudhavani, T.J.;Reddy, N. Sivagangi;Rao, K. Madhusudana;Rao, K.S.V. Krishna;Ramkumar, Jayshree;Reddy, A.V.R.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1513-1520
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    • 2013
  • Novel chitosan (CS) based membrane networks were developed by solution casting and followed by crosslinking with different crosslinkers such as glutaraldehyde, urea-formaldehyde, and thiourea-formaldehyde. The developed membrane networks were designated as CS-GA, CS-UF and CS-TF. Crosslinking reaction of CS membranes was confirmed by Fourier transform infrared spectroscopy. Membrane rigidity and compactness were studied by the differential scanning calorimetry. The surface morphology of CS membranes was characterized by scanning electron microscopy. The sorption behaviour with respect to contact time, initial pH and initial metal ion concentration were investigated. The maximum adsorption capacity of CS-GA, CS-UF and CS-TF sorbents was found to be 1.03, 1.2 and 1.18 mM/g for $Cu^{2+}$ and 1.48, 1.55 and 2.18 mM/g for $Ni^{2+}$ respectively. Swelling experiments have been performed on the membrane networks at $30^{\circ}C$. Desorption studies were performed in acid media and EDTA and it was found that the membranes are reusable for the metal ion removal for three cycles. The developed membranes could be successfully used for the separation of $Cu^{2+}$ and $Ni^{2+}$ metal ions from aqueous solutions.

Comparison of the shaping ability of novel thermally treated reciprocating instruments

  • Keskin, Cangul;Demiral, Murat;Sariyilmaz, Evren
    • Restorative Dentistry and Endodontics
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    • v.43 no.2
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    • pp.15.1-15.7
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    • 2018
  • Objectives: The present study aimed to evaluate the shaping ability of 2 thermally treated nickel-titanium reciprocating systems in simulated curved canals. Materials and Methods: Forty simulated canals were prepared to apical size 25 using Reciproc Blue R25 (VDW) and WaveOne Gold Primary (Dentsply Sirona) instruments. Standard pre- and post-preparation images were taken and superimposed. The removal of resin material was measured at 5 standard points: the canal orifice, halfway between the canal orifice and the beginning of the curve, the beginning of the curve, the apex of the curve, and the end-point of the simulated canal. The data were analysed using the independent sample t-test with a 5% significance threshold. Results: The canals in which Reciproc Blue R25 was used showed a significantly greater widening than those in which WaveOne Gold was used at 4 of the 5 measurement points (p < 0.05). The Reciproc Blue R25 instrument removed significantly more resin from the inner aspect of the curve at 2 of the 5 points and similar amounts at the remaining 3 points. At the 2 apical points, there was no significant difference between the Reciproc Blue R25 and WaveOne Gold Primary instruments. Conclusion: Both instruments respected the original canal anatomy; however, WaveOne Gold resulted in a more conservative shape with less transportation.

Corrosion Characteristics of Diffusion Barrier in Copper CMP (구리 CMP시 확산방지막의 부식특성)

  • Lee, Do-Won;Kim, Nam-Hoon;Lim, Jong-Heun;Kim, Sang-Yong;Lee, Chul-In;Chang, Eui-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.162-165
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    • 2003
  • The corrosion characteristics of diffusion barrier in Copper CMP has been investigated. Key experimental variables that has been investigated are the corrosion rate by different agents containing slurry of Cu CMP. Whenever Cu and Ta films were corroded adding each oxidizer, the corrosion rate of Ta was much lower than that of Cu. That is, the difference in the corrosion rates of Ta by oxidizer was not larger as compared with Cu. As corroded by complexing agents, the corrosion rate of Ta was close to O. The corrosion rate of Ta increased as added $HNO_3$ and $CH_3COOH$ compared with the reference slurry; on the other hand, it decreased with addition of HF. In addition, resulting corrosion rate went up with lower pH of agent. The corrosion rates by agents were however significant small; hence, it doesn't affect on the removal rate of Cu CMP practically. Consequently, this can be explained by assuming that the mechanical effect dominates than the chemical effect on the polishing rate of Ta(TaN).

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