• Title/Summary/Keyword: T/C

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Ab Initio Conformational Study on Ac-Pro-$NMe_2$: a Model of Polyproline

  • Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.75-75
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    • 2003
  • We report here the results on N-acetyl-N'-dimethylamide of proline (Ac-Pro-NM $e_2$) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level with the 6-31+G(d) basis set to investigate the conformational preference of polyproline depending on the cis/trans peptide bonds and down/up puckerings along the backbone torsion angle $\square$ in the gas phase, chloroform, and water. In the gas phase, Ac-Pro-NM $e_2$ has seven local minima of tFd, tFu, cFd, cFu, cAu, tAu, and cAd conformations. In particular, polyproline conformations tFd, tFu, cFd, and cFu are found to be more stable than $\square$-helical conformations cAu, tAu, and cAd. In contrast, Ac-Pro-NHMe has seven local minima of tCd, tCu, cBd, cAu, tAu, cFd, and cFu conformations. Conformations tCd and tCu are found to be most stable, which is ascribed to the intramolecular hydrogen bond between C=O of acetyl group and $N^{~}$ H of N'-methyl amide group. The stability of the cFd conformation (i.e., the polyproline I structure) in chloroform is somewhat increased, relative to that in water, although tFd and tFu conformations (i.e., the polyproline II structure) are dominate both in chloroform and water. The population of backbone conformations feasible in chloroform and water is consistent with the experiments. This work is supported by a Korea Research Foundation Grant (KRF-2002-041-C00129).

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A TRANSLATION OF AN ANALOGUE OF WIENER SPACE WITH ITS APPLICATIONS ON THEIR PRODUCT SPACES

  • Cho, Dong Hyun
    • Communications of the Korean Mathematical Society
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    • v.37 no.3
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    • pp.749-763
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    • 2022
  • Let C[0, T] denote an analogue of Weiner space, the space of real-valued continuous on [0, T]. In this paper, we investigate the translation of time interval [0, T] defining the analogue of Winer space C[0, T]. As applications of the result, we derive various relationships between the analogue of Wiener space and its product spaces. Finally, we express the analogue of Wiener measures on C[0, T] as the analogue of Wiener measures on C[0, s] and C[s, T] with 0 < s < T.

STRONG CONVERGENCE THEOREMS FOR LOCALLY PSEUDO-CONTRACTIVE MAPPINGS IN BANACH SPACES

  • Jung, Jong-Soo
    • Communications of the Korean Mathematical Society
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    • v.17 no.1
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    • pp.37-51
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    • 2002
  • Let X be a reflexive Banach space with a uniformly Gateaux differentiable norm, C a nonempty bounded open subset of X, and T a continuous mapping from the closure of C into X which is locally pseudo-contractive mapping on C. We show that if the closed unit ball of X has the fixed point property for nonexpansive self-mappings and T satisfies the following condition: there exists z $\in$ C such that ∥z-T(z)∥<∥x-T(x)∥ for all x on the boundary of C, then the trajectory tlongrightarrowz$_{t}$$\in$C, t$\in$[0, 1) defined by the equation z$_{t}$ = tT(z$_{t}$)+(1-t)z is continuous and strongly converges to a fixed point of T as t longrightarrow 1 ̄.ow 1 ̄.

Dynamic Cardiac Magnetic Resonance Fingerprinting During Vasoactive Breathing Maneuvers: First Results

  • Luuk H.G.A. Hopman;Elizabeth Hillier;Yuchi Liu;Jesse Hamilton;Kady Fischer;Nicole Seiberlich;Matthias G. Friedrich
    • Journal of Cardiovascular Imaging
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    • v.31 no.2
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    • pp.71-82
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    • 2023
  • BACKGROUND: Cardiac magnetic resonance fingerprinting (cMRF) enables simultaneous mapping of myocardial T1 and T2 with very short acquisition times. Breathing maneuvers have been utilized as a vasoactive stress test to dynamically characterize myocardial tissue in vivo. We tested the feasibility of sequential, rapid cMRF acquisitions during breathing maneuvers to quantify myocardial T1 and T2 changes. METHODS: We measured T1 and T2 values using conventional T1 and T2-mapping techniques (modified look locker inversion [MOLLI] and T2-prepared balanced-steady state free precession), and a 15 heartbeat (15-hb) and rapid 5-hb cMRF sequence in a phantom and in 9 healthy volunteers. The cMRF5-hb sequence was also used to dynamically assess T1 and T2 changes over the course of a vasoactive combined breathing maneuver. RESULTS: In healthy volunteers, the mean myocardial T1 of the different mapping methodologies were: MOLLI 1,224 ± 81 ms, cMRF15-hb 1,359 ± 97 ms, and cMRF5-hb 1,357 ± 76 ms. The mean myocardial T2 measured with the conventional mapping technique was 41.7 ± 6.7 ms, while for cMRF15-hb 29.6 ± 5.8 ms and cMRF5-hb 30.5 ± 5.8 ms. T2 was reduced with vasoconstriction (post-hyperventilation compared to a baseline resting state) (30.15 ± 1.53 ms vs. 27.99 ± 2.07 ms, p = 0.02), while T1 did not change with hyperventilation. During the vasodilatory breath-hold, no significant change of myocardial T1 and T2 was observed. CONCLUSIONS: cMRF5-hb enables simultaneous mapping of myocardial T1 and T2, and may be used to track dynamic changes of myocardial T1 and T2 during vasoactive combined breathing maneuvers.

ON PATHOS BLOCK LINE CUT-VERTEX GRAPH OF A TREE

  • Nagesh, Hadonahalli Mudalagiraiah
    • Communications of the Korean Mathematical Society
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    • v.35 no.1
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    • pp.1-12
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    • 2020
  • A pathos block line cut-vertex graph of a tree T, written P BLc(T), is a graph whose vertices are the blocks, cut-vertices, and paths of a pathos of T, with two vertices of P BLc(T) adjacent whenever the corresponding blocks of T have a vertex in common or the edge lies on the corresponding path of the pathos or one corresponds to a block Bi of T and the other corresponds to a cut-vertex cj of T such that cj is in Bi; two distinct pathos vertices Pm and Pn of P BLc(T) are adjacent whenever the corresponding paths of the pathos Pm(vi, vj) and Pn(vk, vl) have a common vertex. We study the properties of P BLc(T) and present the characterization of graphs whose P BLc(T) are planar; outerplanar; maximal outerplanar; minimally nonouterplanar; eulerian; and hamiltonian. We further show that for any tree T, the crossing number of P BLc(T) can never be one.

Effect of Temperature on Mitotic Cycle of Rice Root Meristem Cells (벼 뿌리세포의 유사분열주기에 대한 배양온도의 영향)

  • 김재철;이승준;권성환;곽성희
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.1
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    • pp.65-72
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    • 1990
  • The mitotic cycle duration and component plase periods of rice (Oryza sativa L. 'Sumjinbyeo and Seokwangbyeo') root merisem cells at 15, 20, and 30$^{\circ}C$ were determined the use of tritiated thymidine, In this work, the time interval between the maxima of sequential mitotic appearances of marked cells was used to estimate the mitotic cycle duration (MCD) of rice, The MCD of rice of the cultivar 'Sumjinbyeo' and 'Seokwangbyeo' at 20. and 30$^{\circ}C$ was 12. and 20hr, respectively. But the MCD of 'Sumjinbyeo' and 'Seokwangbyeo' was 18 and 20hr, at 15$^{\circ}C$. respectively. The MCD decreased with increasing temperature, The duration of component phase of rice cultivar 'Seokwangbyeo' were essentially the same ratio at 20$^{\circ}C$ and 30$^{\circ}C$. but in 'Sumjinbyeo' cultivar the ratio of $G_1$ period was almost doubled while those of $G_2$ and M were decreased by almost two times at 20$^{\circ}C$ and 30$^{\circ}C$. Deoxyribonucleic acid (DNA). Ribonucleic acid (RNA), and protein synthesis were reduced with increasing temperature from 15$^{\circ}C$ to 30$^{\circ}C$ while the MCD was decreased, This result suggest that DNA, RNA and protein synthesis may not affect the MCD from 15$^{\circ}C$ to 30$^{\circ}C$ in rice.

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Effects of Maternal 5, 10-Methylenetetrahydrofolate Reductase (MTHFR) Genotypes, Serum Homocysteine and B Vitamin Levels on Postnatal Growth in Their Offsprings (임신부의 MTHFR 유전자형, 호모시스테인 및 비타민 B군 영양상태가 영아 성장에 미치는 영향)

  • Kim Hye-Sook;Kim Young-Ju;Chang Nam-Soo
    • Journal of Nutrition and Health
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    • v.39 no.3
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    • pp.264-273
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    • 2006
  • Elevated maternal plasma homocysteine concentrations have been associated with adverse pregnancy outcomes. Serum homocysteine levels may be affected by the MTHFR genotypes and the nutritional status of B vitamins including vitamin $B_2,\;B_6$, folate and vitamin $B_{12}$. We investigated whether postnatal growth measurements were influenced by maternal MTHFR genotypes and their mid-pregnancy serum vitamin B and homocysteine levels. In 130 pregnant women of 24-28 wks of gestation, the MTHFR genotypes, serum B vitamins and homocysteine concentrations were analyzed. Physical growth status was assessed in their offsprings by measuring height, weight, and head and chest circumferences from birth up to 24 months. Serum homocysteine levels were higher in the subjects with T/T genotype than those with the C/T or C/C. Heights and head and chest circumferences of offsprings from the T/T mothers were significantly lower than those from the C/C or C/T mothers only when the serum homocysteine levels were above the median. The mean height of offsprings from the T/T mothers was significantly lower than those from the C/C and C/T mothers. The mean weight and head circumferences of offsprings born from the mothers whose mid-term pregnancy PLP levels were in the lowest quartile was significantly lower than those from mothers in the highest quartile. Heights and head circumferences of offsprings from the T/T mothers were significantly lower than those from the C/C or C/T mothers only when the serum FAD levels were in the lowest quartile. These results suggest that postnatal growth up to 24 months may be influenced by the maternal C677T MTHFR genotypes, and mid-pregnancy serum homocysteine and vitamin B status.

CONVERGENCE OF APPROXIMATING FIXED POINTS FOR MULTIVALUED NONSELF-MAPPINGS IN BANACH SPACES

  • Jung, Jong Soo
    • Korean Journal of Mathematics
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    • v.16 no.2
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    • pp.215-231
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    • 2008
  • Let E be a uniformly convex Banach space with a uniformly $G{\hat{a}}teaux$ differentiable norm, C a nonempty closed convex subset of E, and $T:C{\rightarrow}{\mathcal{K}}(E)$ a multivalued nonself-mapping such that $P_T$ is nonexpansive, where $P_T(x)=\{u_x{\in}Tx:{\parallel}x-u_x{\parallel}=d(x,Tx)\}$. For $f:C{\rightarrow}C$ a contraction and $t{\in}(0,1)$, let $x_t$ be a fixed point of a contraction $S_t:C{\rightarrow}{\mathcal{K}}(E)$, defined by $S_tx:=tP_T(x)+(1-t)f(x)$, $x{\in}C$. It is proved that if C is a nonexpansive retract of E and $\{x_t\}$ is bounded, then the strong ${\lim}_{t{\rightarrow}1}x_t$ exists and belongs to the fixed point set of T. Moreover, we study the strong convergence of $\{x_t\}$ with the weak inwardness condition on T in a reflexive Banach space with a uniformly $G{\hat{a}}teaux$ differentiable norm. Our results provide a partial answer to Jung's question.

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Influence of the C.T.I of phenolic resin (페놀수지의 C.T.I에 미치는 영향)

  • 이보호;박동화;정인성
    • Electrical & Electronic Materials
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    • v.1 no.1
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    • pp.70-77
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    • 1988
  • This paper describes the influence of the electrode materials, moisture content, electrolyte density, temperature, surface state, ion absorbent on the C.T.I of phenolic resin by the I.E,C, 112 method. C.T.I are increased for electrode materials with low hydrogen overvoltage and high soluble point. Increusing moisture content of samples increased by logarithmical on the droplet number to tracking breakdown. Increasing electrolyte temperature region above 70-80(.deg.C) decreased hydrogen over-voltage, following the density changes are decreased by C.T.I=1/aD$^{2}$-bD+C.

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Estimation of C(t) -Integral Under Transient Creep Conditions for a Cracked Pipe Subjected to Combined Mechanical and Thermal Loads Depending on Loading Conditions (열응력 및 기계응력이 작용하는 균열배관의 하중조건에 따른 천이 크리프 조건 C(t)-적분 평가)

  • Oh, Chang-Young;Song, Tae-Kwang;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.6
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    • pp.609-617
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    • 2011
  • There is a trend towards the progressive use of higher operating temperatures and stresses to achieve improved efficiencies in power-generation equipment. It is important to perform the crack assessment under hightemperature and high-pressure conditions. The C(t)-integral is a key parameter in crack assessment for transient creep states. The estimation of the C(t)-integral is complex when considering the mechanical and thermal loads simultaneously. In this paper, we study estimation of C(t)-integral under combined mechanical and thermal load depending on loading conditions.