• Title/Summary/Keyword: Synthetic dyes

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Enzymatic Decolorization of Various Dyes by Trametes versicolor KCTC 16781 (Trametes versicolor KCTC 16781에 의한 다양한 염료의 색도제거 특성)

  • 박철환;이유리;김탁현;이명구;이병환;이진원;김상용
    • KSBB Journal
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    • v.18 no.5
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    • pp.398-403
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    • 2003
  • Due to the low biodegradability of dyes, conventional biological wastewater treatment systems are inefficient in treating dye wastewater. Various white-rot fungi were investigated for the decolorization of six industrial dyes (reactive blue 5, reactive blue 16, reactive black 5, acid black 52, reactive orange 16, and acid violet 43). Among ten fungi, T. versicolor KCTC 16781 was selected as a testing strain because this had the best performance of decolorization for six dyes from the results of the solid culture experiments. In liquid culture medium, T. versicolor KCTC 16781 decolorized over 96% of six dyes for 48 hrs. Laccase started to produce in the early stage of the culture, and showed the highest peak value of 2.3 U/mL in 24 hrs. Enzyme activity remained constant until the end of culture. Fungal decolorization is a promising alternative to replace or supplement present treatment process.

Synthetic aromatic dye degradation by white rot fungus, Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 방향족 합성염료 분해 특성)

  • Im, Kyung-Hoan;Baek, Seung-A;Lee, Tae Soo
    • Journal of Mushroom
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    • v.20 no.2
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    • pp.86-91
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    • 2022
  • Pleurotus eryngii, a white rot fungus, produces two extracellular lignin-degrading enzymes, laccase and manganese peroxidase (MnP). Owing to these enzymes, P. eryngii efficiently degrades synthetic chemicals such as azo, phthalocyanine, and triphenyl methane dyes. In this study, we investigated the degradation processes of four aromatic dyes, congo red (CR), methylene blue (MB), crystal violet (CV), and malachite green (MG), by P. eryngii under solid and liquid culture conditions. CR and MG were the most quickly degraded under solid and liquid culture conditions, respectively. However, compared to CR, CV, and MG, MB was not degraded well under both culture conditions. The activities of ligninolytic enzymes (laccase and MnP) were also investigated. Laccase was identified to be the major enzyme for dye degradation. A positive relationship between decolorization and enzyme activity was observed for CR, MB, and CV degradation. In contrast, decolorization of MG ensued after high enzyme activity. These results indicate that the degradation process differs between MG and the other aromatic dyes. Therefore, P. eryngii could be a potential tool for the bioremediation of synthetic aromatic dye effluent.

Healthy Fabrics for Natural-imageable Fashion Fabric Planning - Dyeability and antimicrobial activity of dyeable materials from Japan bamboo leaves extract - (내츄럴 이미지의 패션소재기획을 위한 건강소재 - Japan bamboo leaves 추출물 염색소재의 발색성과 항균성 -)

  • Park, Young-Mi;Koo, Kang;Kim, Sam-Soo
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.29-38
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    • 2009
  • Natural dyes seem to be more profitable on human and environment, and recently they could be considered as a better alternative to synthesized dyes. The aim of the current work was to investigate the dyeing property and antimicrobial activity of commercial cotton fabrics dyed with kumazasa (usually called in japan) which is known as conventional japan bamboo leaves. Actually, the dyeability and antimicrobial property of dyed fabric with natural mordant/dyeing was compared with synthetic mordant/dye process. The results of this study obtained are as follows. The apparently colour of kumazasa leaves extract dyed fabrics showed with light green or slightly yellow-green. In colorfastness to washing, ${\Delta}E$ and K/S values of dyed fabrics with natural chitosan as mordant used was shown to be more excellent results, than was synthetic mordant used. However, the decrease rate was recorded nearly 50% when washing repeated 20 cycles. In result of antimicrobial effect for bacteria, the dyed fabrics didn't show the significant antimicrobial activity to the both dyed with and without mordant. Results of this investigation considered that low-cost, natural, bio-mordant are relatively effective in natural coloration.

Decolorization of Synthetic Dyes and Ligninolytic Enzymes Production by White Rot Fungi (백색부후균에 의한 합성염료의 탈색과 리그닌분해 효소의 생산)

  • Gu, Bon-Joon;Kim, Min-Sik;Kim, Yin-Man;Kim, Seon-Woong;Choi, Won-Hyeok;Lee, Mi-Hwa;Cho, Hae-Jin;Lee, Tae-Soo
    • The Korean Journal of Mycology
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    • v.40 no.2
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    • pp.98-103
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    • 2012
  • This study has been conducted to screen the decolorization of 4 aromatic synthetic dyes and production of ligninolytic enzymes by 4 white rot fungi such as Bjerkanderia adusta, Cerrena unicolor, Pleurotus pulmonarius and Abortiporus biennis. It was found that B. adusta, C. unicolor, and P. pulmonarius have the ability to efficiently decolorize congo red and moderately decolorized amaranth and orange G in solid and liquid culture media. However, the decolorization rate of 4 synthetic dyes by A. biennis was relatively low. The decolorization of congo red, amaranth, orange G were related to the growth rate of the fungal mycelia in the solid medium. But, the all fungi tested did not efficiently decolorize methylene blue in the liquid culture media. To investigate the production of ligninolytic enzymes in media containing aromatic compounds, fungi were cultured in 1% naphthalene supplemented potato dextrose broth medium. All fungi tested had the capability to produce laccase, lignin peroxidase and manganese peroxidase, and B. adusta was the best ligninolytic enzymes producing white rot fungus among other fungi tested.

Dyeing properties of Nylon/Spandex blends with vat dye (배트염료에 의한 나일론/스판덱스 교직물의 염착특성)

  • Park, Young-Min;Kim, Byung-Soon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.63-68
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    • 2006
  • In synthetic/spandex blends fibers, contents of the synthetic fiber by percentage is higher than those of spandex. Thus, the dyeing process of the blends fiber is mainly focused on the synthetic fiber, but not the spandex. In this study, we used several series of vat dyes for dyeing the nylon/spandex blend fabrics and their dyeing properties(fk value) were investigated at various reduction agents, temperatures, pH which have the potential for deep shade dyeing effects. The formamidinesulfinic acid were found to be effective to increase the fk values of the blend fiber compared to sodium hydrosulfite and Rongalit C. Higher temperature($100^{\circ}C$) and lower pH(pH 4) were observed as suitable conditions for maximum fk values.

On Bath Dyeing of silk/synthetic Fibre Blends(III) ―Adsorption Behavior of Acid Dyes/Disperse Dyes on Silk/PET― (견/합성섬유 혼방품의 일욕염색(III) ―산성염료/분산염료 염욕에서의 견/PET의 염착거동―)

  • Gwag, In Jun;Yoon, Kyung Sup;Kim, Ae Soon;Kim, Gong Ju
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.67-78
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    • 1993
  • In one bath dyeing system of silk/PET fiber blend fabric with acid/disperse dyes, adsorption behavior of disperse dyes and acid dyes on silk and PET fabrics were examined. In the dyeing of PET with C.I.Disperse Red 19(Red 19) and C.I.Disperse Red 60(Red 60) at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake with Red 60 was higher than that with Red 19. When the silk/PET dyed with Red 19 and Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake on PET was influenced by affinity of the dye to the silk fabric dyed together. When the silk/PET dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$ for 60 minutes, color of PET dyed with Red 19 and Red 60 was little influenced by Blue 80 but silk dyed with Blue 80 was influenced. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

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Dyeing Characteristics and Mechanical Properties of High Tenacity Polyethylene(HTPE) Filament using Solvent Dyes (솔벤트 염료를 이용한 고강도 폴리에틸렌(HTPE) 필라멘트사의 염색성 및 기계적 물성 평가)

  • Lee, Jeong Hoon;Lee, Beom Young;Lee, Seung O;Choi, Kyeong Yong;Ko, Jae Wang;Kim, Jung Su;Kim, Taekyeong;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.105-114
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    • 2017
  • High tenacity polyethylene(HTPE) fiber is one of the most important synthetic fibers which possesses outstanding properties such as low density, excellent surface hardness and scratch resistance, superior electrical insulation and low cost. In this study, we dyed high tenacity polyethylene filaments using three different solvent dyes based on log P calculations. We evaluated the dyeing characteristics of dyed high tenacity polyethylene filaments based on dyeing temperature, dyeing time and concentration of solvent dyes. We also analyzed the tensile strength and elongation properties of dyed high tenacity polyethylene filaments with various dyeing temperature and dyeing times. The optimized dyeing condition can be found at $120^{\circ}C$ for dyeing time of 1 hour with 4%(o.w.f.) of solvent dyes.

Decolorization of Acid Green 25 by Surface Display of CotA laccase on Bacillus subtilis Spores

  • Park, Jong-Hwa;Kim, Wooil;Lee, Yong-Suk;Kim, June-Hyung
    • Journal of Microbiology and Biotechnology
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    • v.29 no.9
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    • pp.1383-1390
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    • 2019
  • In this study, we expressed cotA laccase from Bacillus subtilis on the surface of B. subtilis spores for efficient decolorization of synthetic dyes. The cotE, cotG, and cotY genes were used as anchoring motifs for efficient spore surface display of cotA laccase. Moreover, a $His_6$ tag was inserted at the C-terminal end of cotA for the immunological detection of the expressed fusion protein. Appropriate expression of the CotE-CotA (74 kDa), CotG-CotA (76 kDa), and CotY-CotA (73 kDa) fusion proteins was confirmed by western blot. We verified the surface expression of each fusion protein on B. subtilis spore by flow cytometry. The decoloration rates of Acid Green 25 (anthraquinone dye) for the recombinant DB104 (pSDJH-EA), DB104 (pSDJH-GA), DB104 (pSDJH-YA), and the control DB104 spores were 48.75%, 16.12%, 21.10%, and 9.96%, respectively. DB104 (pSDJH-EA) showed the highest decolorization of Acid Green 25 and was subsequently tested on other synthetic dyes with different structures. The decolorization rates of the DB104 (pSDJH-EA) spore for Acid Red 18 (azo dye) and indigo carmine (indigo dye) were 18.58% and 43.20%, respectively. The optimum temperature for the decolorization of Acid Green 25 by the DB104 (pSDJH-EA) spore was found to be $50^{\circ}C$. Upon treatment with known laccase inhibitors, including EDTA, SDS, and $NaN_3$, the decolorization rate of Acid Green 25 by the DB104 (pSDJH-EA) spore decreased by 23%, 80%, and 36%, respectively.

Capacity of Activated Carbon Derived from Agricultural Waste in the Removal of Reactive Dyes from Aqueous Solutions

  • Manoochehri, Mahboobeh;Rattan, V.K.;Khorsand, Ameneh;Panahi, Homayon Ahmad
    • Carbon letters
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    • v.11 no.3
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    • pp.169-175
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    • 2010
  • The study describes the results of batch experiments on the removal of Reactive Yellow 15 (RY15) and Reactive Black 5 (RB5) from synthetic textile wastewater onto Activated Carbon from Walnut shell (ACW). The experimental data were analyzed by the Langmuir, Freundlish, Temkin and Dubinin-Radushkevich (D-R) models of adsorption. The experiments were carried out as function of initial concentrations, pH, temperature (303-333), adsorbent dose and kinetics. The surface area and pore volumes of adsorbent were measured by BET and BJH methods. The findings confirm the surface area (BET) is 248.99 $m^2/g$. The data fitted well with the Temkin and D-R isotherms for RY15 and RB5, respectively. The most favorable adsorption occurred in acidic pH. Pseudo-second order kinetic model were best in agreement with adsorption of RY15 and RB5 on ACW. The results indicate that walnut shell could be an alternative to more costly adsorbent currently being used for dyes removal.