• Journal of the Korean Chemical Society
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• v.57 no.3
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• pp.316-321
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• 2013

Electrocoagulation (EC) technique is applied for the treatment of wastewater containing heavy metals ions such as nickle (Ni), lead (Pb) and cadmium (Cd) by using sacrificial anodes corrode to release active coagulant flocs usually aluminium or iron cations into the solution. During electrolytic reactions hydrogen gas evolve at the cathode. All the experiments were carried out in Batch mode. The tank was filled with synthetic wastewater containing heavy metals and efficiency of electro-coagulation in combination with aluminum and iron electrodes were investigated for removal of such metals. Several parameters, such as contact time, pH, electro-coagulant concentration, and current density were optimized to achieve maximum removal efficiency (%). The concentrations of heavy metals were determined by using Atomic Absorption Spectroscopy (AAS). It is found that the electro-coagulation process has potential to be utilized for the cost-effective removal of heavy metals from wastewater specially using iron electrodes in terms of high removal efficiencies and operating cost.

• Journal of Korean Society of Water and Wastewater
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• v.11 no.4
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• pp.43-53
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• 1997

In this research, the synthetic livestock wastewater was prepared to study the characteristics of organic matter removal, the change of VFA production, and the amount of gas production with respect to the change of ammonium nitrogen concentration in the waste using anaerobic fixed bed process, which is an anaerobic biofilm process. The HRT and operation temperature were 1 day and $35{\pm}1^{\circ}C$, respectively. Also, the characteristics of organic matter removal and the inhibitory effect on microorganism in the anaerobic process were studied on the organic loading and ammonium nitrogen concentration. The results obtained were as follows: For COD loading of $10kg/m^3$-day and five levels of ammonium nitrogen concentration ranging from 1,000 to 5,000 mg/L, organic removal efficiencies were about 81, 74, 67, 58, and 51%, and gas productions were 3,860, 3,520, 3,240, 3,020, and 2,790 ml/l-day, respectively. Average methane contents in the gas produced on COD loading of $10kg/m^3$-day was about 76%. Throughout the whole period of experiment, remaining VFA (as COD base) in the effluent was over 90% of remaining COD. This result indicated the inhibitory effect of high concentration of ammonium nitrogen through the facts that accumulated VFA was almost COD and organic removal efficiency decreased also with the increase of ammonium nitrogen. Especially, that implys which high concentration of ammonium nitrogen not only inhibits methane forming bacteria, but also acid forming bacteria.

• Journal of Microbiology and Biotechnology
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• v.14 no.5
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• pp.1009-1013
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• 2004

The purpose of this study was to investigate the degradation of PVA (polyvinyl alcohol) contained in dyeing wastewater by a mixed culture of Microbacterium barkeri KCCM 10507 and Paenibacillus amylolyticus KCCM 10508. Firstly, synthetic wastewater which contained different initial concentrations of PVA varying from 50 to 3,500 mg/l were tested to obtain optimal PVA biodegradation activity of isolated strains, and the above two strains were found to degrade PVA up to 90%, when the initial concentration of PVA was 750 mg/l and below. Next, dyeing wastewater was tested by a nixed culture of the two isolated strains, and 42% and 55% of the initial concentrations of PVA and COD, respectively, was removed after five days. MLSS was gradually increased from an initial 1,400 to 2,500 mg/l, and the pH was also increased from 5.1 to 7.8. Sterilized dyeing wastewater was tested to find the effect of strains only on the biodegradation of PVA, and PVA degradation ratio and COD removal ratio were 50% and 72.8%, respectively. Thus, the results indicated that these two strains have good ability to degrade PVA and remove COD in dyeing wastewater, Finally, it is expected that if these two strains were used in the dyeing wastewater treatment, good efficiency for PVA degradation and COD removal could be achieved.

• Membrane and Water Treatment
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• v.8 no.5
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• pp.449-462
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• 2017

Direct treatment of municipal wastewater by forward osmosis (FO) process was evaluated in terms of water flux decline, reverse salt diffusion, pollutants rejection and concentration efficiency by using synthetic seawater as the draw solution. It was found that when operating in PRO mode (active layer facing the draw solution), although the FO membrane exhibited higher osmotic water flux, more severe flux decline and reverse salt diffusion was also observed due to the more severe fouling of pollutants in the membrane support layer and accompanied fouling enhanced concentration polarization. In addition, although the water flux decline was shown to be lower for the FO mode (active layer facing the feed solution), irreversible membrane fouling was identified in both PRO and FO modes as the water flux cannot be restored to the initial value by physical flushing, highlighting the necessity of chemical cleaning in long-term operation. During the 7 cycles of filtration conducted in the experiments, the FO membrane exhibited considerably high rejection for TOC, COD, TP and $NH_4{^+}-N$ present in the wastewater. By optimizing the volume ratio of seawater draw solution/wastewater feed solution, a concentration factor of 3.1 and 3.7 was obtained for the FO and PRO modes, respectively. The results demonstrated the validity of the FO process for direct treatment of municipal wastewater by using seawater as the draw solution, while facilitating the subsequent utilization of concentrated wastewater for bioenergy production, which may have special implications for the coastline areas.

• Journal of Navigation and Port Research
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• v.28 no.5
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• pp.463-468
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• 2004

A lab-scale fundamental study to develop the solvent extraction process of ship wash wastewater containing TBT was carried out. For various solvents, including diesels for car and ship, bunker B, thinner, toluene, and ether, the extraction efficiencies of TBT from synthetic ship wash wastewater were compared The effect of extraction conditions, such as solvent amount, time and intensity of agitation, and pH, on the extraction efficiency of TBT was evaluated Diesel for ship showed better extraction efficiency of TBT than those of other tested solvents, and the proper amount of the extraction solvent for 1L of the wastewater was l0mL. When the agitation intensity was increased from 50rpm to 250rpm, the TBT remained in the wastewater after the extraction was decreased from around 120ppb to 2.8ppb. The remaining TBT in the wastewater was sharply decreased from 1hr of the extraction time, but was slightly increased again after 5hrs of the extraction time. The efficiency of TBT extraction was good in the weak acid range of pH, but was not significant as much as the others.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.6
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• pp.479-485
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• 2018

Large amounts of oily wastewater discharged from various industrial operations (petroleum refining, machinery industries and chemical industries) cause serious pollution in the aquatic environment. Although dissolved air flotation (DAF) separating oil pollutants using microbubbles represents current practice, bubble size cannot be selectively controlled, and lots of power is required to generate microbubbles. Therefore, to investigate performance of the DAF process, this study examined the distribution of different sizes of microbubbles resulting from changes in physical shear force via modifying shapes of a slit-nozzle without an additional power supply. Three types of slit-nozzles (different angle, shape and length of the slit-nozzle) were used to analyze the distribution of bubble size. At a slit angle of $60^{\circ}$, shear force was 4.29 times higher than a conventional slit, and particle size distribution (PSD) in the range between 2 and $20{\mu}m$ more than doubled. Treatment efficiency of synthetic oily wastewater through the coagulation-DAF process achieved 90% removal of COD by injecting $FeCl_3$ and PACl of 250 mg/L and 100 mg/L, respectively, and the same performance resulted using $FeCl_3$ of 200 mg/L and PACl of 80 mg/L employing a slit-nozzle angle of $60^{\circ}$. This study shows that a coagulation-DAF process using a modified slit-nozzle can improve the pre-treatment of oily wastewater.

• Journal of the Korean GEO-environmental Society
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• v.5 no.4
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• pp.25-31
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• 2004

In conventional activated sludge process, COD fractions in wastewater are important parameters, significantly. Depending on characteristics of influent COD fractionation, activated sludge process requires a major change of a process operation to ensure meeting a stricter standards. In order to validate and evaluate the accuracy of the traditional COD fractionation methodologies, readily and slowly biodegradable COD was mixed using glucose and peptone as a sole carbon source in a synthetic wastewater, respectively. In this research, prediction of the COD fraction was made using the OUR(Oxygen Utilization Rate) and the NUR(Nitrate Utilization Rate) experiments. The result showed that COD fractions calculated by OUR experiment were similar to the composition of synthetic wastewater. On the other hand, it was found that an error was generated during the NUR experiment. This error was due to the intracellular storage period for storage microorganisms such as PAOs, and the error in COD fraction was observed about 8-14 % in terms of Total COD.

• Journal of environmental and Sanitary engineering
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• v.16 no.3
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• pp.22-27
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• 2001

It have been investigated how algal and bacterial symbiotic reaction influences on removal of organic carbon in river ecosystem. And artificial experimentation apparatus was made for algae'and bacteia'culture as lab scale. Investigating and researching minutely the change of concentration of organic carbon substrate and the change of population density of algae'and of bacteria'with this artificial experimentation apparatus, the next results could be obtained. 1. Successful decrease of DOC(dissolved organic carbon) could not be expected unless algal and bacterial biomass floe was nut formed effectively and unless biosorption was not proceeded effectively in the very culture system in which artificial synthetic wastewater was supplied continuously at constant rate. 2. In conditions of culture liquid of 1335 glucnse mg/L(type 1) and of 267 glucose mg:L(type 2), the algal dominant species was always Chlorella vulgaris in both types in which artificial synthetic wastewater were supplied continuously at constant rate and algae population density was around maximum 107 cells/mL. 3. It was around 108 ~ 107 cells/mL that the population density of heterotrophic bacterium. In culture medium systems type 1 and type 2 in which artificial wastewater were supplied continuously at constant rate, the same density appeared initially when using the population density of Escherichia coli w 3110 as indirect indicator. And this density decreased rapidly till the culturing date 35 days were passed away, while this density increased with gentle slope after same date and then the trend of change at type 2 was more severe than one at type 1. 4. When seeing such a change of population density of Escherichia coli w 3110, the growth of heterotrophic bacterium appeared as survival instinct pattern of broader requirement of nutrient at condition of low concentration of organic carbon substrate than condition of high concentration of same substrate.

• Korean Journal of Microbiology
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• v.38 no.1
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• pp.1-6
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• 2002

$\alpha$-Amylase producing bacteria were isolated from activated sludge of corn processing wastewater plant and paddy field soil samples and selected by the direct iodine reaction. The isolate was identified as Bacillus sp. after morphology, API system and fatty acid analyses. To enchance $\alpha$-amylase productivity, a successive mutation of Bacillus sp. AIV 19 was performed using the treatment of nitrosoguanidine(NTG).The mutant, Bacillus sp. AIV 1940, showed about 1.8-fold level of amylase activity compared with parental strain. The isolate was Gram-positive and rod (2.8-3.0 $\mu$m long, 0.5-0.6 $\mu$m wide) type. The strain increased the bacterial mass at 3000 mg/l starch concentration. Organic substance removal rate was 40.2, 72.3% respectively after 1 and 3 day reaction using starch synthetic wastewater (intial CODcr was 4,455 mg/l).

• Journal of Environmental Science International
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• v.17 no.12
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• pp.1343-1351
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• 2008

The activated sludge obtained from wastewater coke oven plant was immobilized by entrapment with polyethylene glycol (PEG). The effects of several factors on the biodegradation of $CN^-$ from. synthetic wastewater were investigated using batch and continuous reactors. The degradation rate of $CN^-$ increased with increasing of the immobilized bead volume in the reactor. Approximately 7.65mg/L of $NH_4-N$ was produced upon the degradation of 35mg/L of $CN^-$. When high concentrations of the toxic cyanide complex were used in the testing of cyanide degradation, the free activated sludge could be inhibited more than that of the immobilized activated sludge. When the phenol concentration was higher than 400mg/L in the synthetic wastewater, approximately 98.4% of $CN^-$ was removed within 42 hours by the immobilized activated sludge. However, the cyanide was not completely degraded by the tree activated sludge. This indicates that high phenol concentrations can act as a toxic factor for the free activated sludge. A $CN^-$ concentration of less than 1mg/L was achieved by the immobilized sludge at the loading rate of 0.025kg $CN^-/m^3-d$. Moreover, it was found that the HRT should be kept for 48 hours in order to obtain stable treatment conditions.