• Title/Summary/Keyword: Synthetic Spectrum

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저온 대기압 아크젯의 플라즈마 발생부 물질에 따른 플라즈마 온도 변화 연구

  • Jeong, Hui-Su;Choe, Won-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.339-339
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    • 2011
  • 진공 플라즈마와 달리 개방된 공간에서 방전되는 대기압 플라즈마는 진공상태에서 수행되는 에칭, 증착 등의 복잡한 플라즈마 공정을 경제적이고 신속하게 수행할 수 있어, 최근 들어 연구가 활발히 진행 중이다. 이와 관련하여 He, Ar, $N_2$, $O_2$, Air 등의 여러 종류의 기체를 50 kHz 고전압에서 방전하여 대기 중에서 저온 플라즈마 공정이 가능한 아크젯 타입의 플라즈마 소스를 개발하였다. 개발된 플라즈마 소스에서는 입력전압, 기체유량, 노즐의 구조와 크기 등의 여러 운전변수에 따라 플라즈마의 방전특성이 변화되었다. 특히 본 연구에서는 아크젯의 플라즈마 발생부의 물질성분(SUS, Aluminum, Cupper)에 따른 플라즈마의 기체온도 및 전자여기 온도의 변화를 광방출분광법(OES)를 이용한 Synthetic spectrum method와 Boltzmann plot method을 통해 살펴보았다. 전압-전류 특성곡선, 시간분해 이미지 촬영법, 기체온도 측정법 등을 이용하여 발생된 플라즈마의 물리적인 특성을 분석하였다. 특히 물질의 성분에 따라 발생되는 플라즈마의 기체 및 전자여기 온도가 이차 전자 방출계수 및 물질의 전도도와의 상관관계가 있는지 연구가 진행 중이다.

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합성 스펙트럼 해석법과 소형 스펙트로메터를 이용한 Fulcher-α 시스템 해석 및 수소 분자 회전 운동 측정

  • Dang, Jeong-Jeung;Jeong, Gyeong-Jae;Hwang, Yong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.227.1-227.1
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    • 2016
  • 플라즈마 방출광 진단법은 플라즈마에 특별한 영향을 주지 않으면서도 진단 정보를 안정적으로, 지속적으로 취득할 수 있는 우수한 진단 방법이다. 이러한 분광 진단의 신뢰성을 확보하기 위해서는 방출광의 정확한 측정과 해석이 중요하다. 방출광의 측정에 이용되는 분광 장비는 모노크로메터(monochromator)와 소형 스펙트로메터(spectrometer)가 주로 사용된다. 스펙트로메터의 경우 모노크로메터보다 분광 성능은 다소 부족하지만 가볍고 작은 크기로 인해 장비의 설치가 용이하고 가격이 저렴하다는 장점이 있다. 또한 모노크로메터에 비해 분광 성능이 낮은 대신 넓은 범위의 파장을 동시에 측정할 수 있는 장점이 있다. 따라서 스펙트로메터는 플라즈마의 모니터링에 주로 사용된다. 그런데 스펙트로메터의 기기적 선폭 증대(instrumental broadening)보다 조밀하게 위치한 스펙트럼들은 서로 중첩이 일어나 진단이 어려워진다. 특히 분자 띠 스펙트럼(molecular band spectrum)과 같은 경우 선 스펙트럼들이 매우 밀집된 형태를 이루고 있어 범용적인 스펙트로메터로 진단하기가 어렵다. 이러한 문제점을 해결하기 위하여 합성 스펙트럼 해석법(synthetic spectrum method)을 이용할 수 있다. 본 연구에서는 수소 플라즈마의 Fulcher-${\alpha}$ 띠 스펙트럼 해석에 합성 스펙트럼법을 적용하여 분자의 회전 온도가 측정 가능한지 확인하고, 고성능의 모노크로메터를 이용한 온도 측정 결과와 서로 비교하였다. 그리고 분자의 진동 상태(vibrational state)가 분자 회전 온도 측정에 미치는 영향과 이에 따른 측정의 한계 등을 제시하였다.

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A Study on the Combustion Characteristics with Hydrogen Contents of SNG Fuel in Low-Swirl Combustor (저선회 연소기에서 합성천연가스(SNG) 연료의 수소함량에 따른 연소 특성 연구)

  • JEONG, HWANGHUI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.181-189
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    • 2017
  • This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

A Study on Phosphor Synthetic and Low Temperature Photoluminescence Spectrum (저온 photoluminescence 스펙트럼 및 형광체 합성에 관한 연구)

  • Kim, Soo-Yong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.10-16
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    • 2010
  • In this paper, synthesis here Mn add to Ar injection the state and a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1 : 1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum observation also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

Adsorption and Separation of U (VI), Co (II), and Dy (III) Metal Ions on Crown Synthetic Resin

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.10 no.1
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    • pp.43-50
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    • 2017
  • Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.

Characterization of Acyl-CoA Oxidases from the Lipolytic Yeast Candida aaseri SH14

  • Ibrahim, Zool Hilmi;Bae, Jung-Hoon;Sung, Bong Hyun;Kim, Mi-Jin;Rashid, Ahmad Hazri Ab;Sohn, Jung-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.32 no.7
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    • pp.949-954
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    • 2022
  • The lipolytic yeast Candida aaseri SH14 contains three Acyl-CoA oxidases (ACOXs) which are encoded by the CaAOX2, CaAOX4, and CaAOX5 genes and catalyze the first reaction in the β-oxidation of fatty acids. Here, the respective functions of the three CaAOX isozymes were studied by growth analysis of mutant strains constructed by a combination of three CaAOX mutations in minimal medium containing fatty acid as the sole carbon source. Substrate specificity of the CaAOX isozymes was analyzed using recombinant C. aaseri SH14 strains overexpressing the respective genes. CaAOX2 isozyme showed substrate specificity toward short- and medium-chain fatty acids (C6-C12), while CaAOX5 isozyme preferred long-chain fatty acid longer than C12. CaAOX4 isozyme revealed a preference for a broad substrate spectrum from C6-C16. Although the substrate specificity of CaAOX2 and CaAOX5 covers medium- and long-chain fatty acids, these two isozymes were insufficient for complete β-oxidation of long-chain fatty acids, and therefore CaAOX4 was indispensable.

Generating Synthetic Raman Spectra of DMMP and 2-CEES by Mathematical Transforms and Deep Generative Models (수학적 변환과 심층 생성 모델을 활용한 DMMP와 2-CEES의 모의 라만 분광 생성)

  • Sungwon Park;Boseong Jeong;Hongjoong Kim
    • Journal of the Korea Institute of Military Science and Technology
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    • v.26 no.5
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    • pp.422-430
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    • 2023
  • To build an automated system detecting toxic chemicals from Raman spectra, we have to obtain sufficient data of toxic chemicals. However, it usually costs high to gather Raman spectra of toxic chemicals in diverse situations. Tackling this problem, we develop methods to generate synthetic Raman spectra of DMMP and 2-CEES without actual experiments. First, we propose certain mathematical transforms to augment few original Raman spectra. Then, we train deep generative models to generate more realistic and diverse data. Analyzing synthetic Raman spectra of toxic chemicals generated by our methods through visualization, we qualitatively verify that the data are sufficiently similar to original data and diverse. For conclusion, we obtain a synthetic dataset of DMMP and 2-CEES with the proposed algorithm.

Adsorption Characteristics of U ranium (VI) Ion on Cryptand Synthetic Resin Adsorbent

  • Kim, Hae-Jin
    • Journal of Integrative Natural Science
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    • v.10 no.4
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    • pp.225-231
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    • 2017
  • Cryptand resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 5%, and 10% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > calcium ($Ca^{2+}$) > neodymium ($Nd^{3+}$) ion, adsorbability of the uranium ion was the crosslink in order of 1%, 2%, 5%, and 10% and it was increased with the lower dielectric constant.

The Influence of the BTA on Electrical Properties of Synthetic Fluids (합성절연유의 전기적 특성에 미치는 BTA의 영향)

  • Shin, Jong-Yeol;Shin, Hyun-Teak;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.2
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    • pp.162-166
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    • 1998
  • Synthetic fluid, class 7 group 2, as an insulating and cooling material is selected as. specimen, arid it is studied for the physical and electrical properties. Also, Benzotriazole(following as BT A) known as a suppressant of streaming electrification is added to it, and the change of physical and electrical properties by addition of BT A is investigated. From the spectrum of FT-IR, it is confirmed that the absorption peak in wavenumbers $3400{\sim}3450[cm^{-1}]$ is small or disappears when BTA is added. AC breakdown strength and volume resistivity of each specimen are investigated. It is considered that the effective content of BTA is about 10[ppm] for the suppression of electrification in this experiment.

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Parametric study based on synthetic realizations of EARPG(1)/UPS for simulation of extreme value statistics

  • Seong, Seung H.
    • Wind and Structures
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    • v.2 no.2
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    • pp.85-94
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    • 1999
  • The EARPG(1)/UPS was first developed by Seong (1993) and has been tested for wind pressure time series simulations (Seong and Peterka 1993, 1997, 1998) to prove its excellent performance for generating non-Gaussian time series, in particular, with large amplitude sharp peaks. This paper presents a parametric study focused on simulation of extreme value statistics based on the synthetic realizations of the EARPG(1)/UPS. The method is shown to have a great capability to simulate a wide range of non-Gaussian statistic values and extreme value statistics with exact target sample power spectrum. The variation of skewed long tail in PDF and extreme value distribution are illustrated as function of relevant parameters.