• Title/Summary/Keyword: Symmetry-Cell

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Variations of Ferroelectric Properties by Unit Cell Distortion of Pb(Zr, Ti)O3-Pb(Co, Nb)O3 Solid Solution in Morphotropic Phase Boundary (Morphotropic Phase Boundary 영역의 Pb(Zr, Ti)O3-Pb(Co, Nb)O3계 고용체의 격자변형에 따른 강유전 특성 변화)

  • 이전국;정형진
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.694-698
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    • 1988
  • Pb(Zr, Ti)O3-Pb(Co, Nb)O3 systems were investigated by x-ray diffraction method. System contains rhombohedral, tetragonal, and pseudocubic structures at room temperature. Crystal symmetry was changed from 4-fold symmetry to 3-fold symmetry by substituting Pb(Co1/3, Nb2/3)O3 ; PCN, to Pb(Zr0.52, Ti0.48)O3 ; PZT. As the substituted PCN concentration was increased, an increase in a-axis direction and a decrease in c-axis in the perovskite structure were occurred simultaneously, so that the crystal symmetry was changed into such way. In the higher sinteringtemperatures, the unit cell distortions occurred rather in the lower substitution range of PCN. The ferroelectric properties were maximized at the region that tetragonal and rhombohedral or pseudocubic structures were coexist.

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A 3D FEA Model with Plastic Shots for Evaluation of Peening Residual Stress due to Multi-Impacts (다중충돌 피닝잔류응력 평가를 위한 소성숏이 포함된 3차원 유한요소해석 모델)

  • Kim, Tae-Hyung;Lee, Hyungy-Il
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.8
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    • pp.642-653
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    • 2008
  • In this paper, we propose a 3-D finite element (FE) analysis model with combined physical behavior and kinematical impact factors for evaluation of residual stress in multi-impact shot peening. The FE model considers both physical behavior of material and characteristics of kinematical impact. The physical parameters include elastic-plastic FE modeling of shot ball, material damping coefficient, dynamic friction coefficient. The kinematical parameters include impact velocity and diameter of shot ball. Multi-impact FE model consists of 3-D symmetry-cell. We can describe a certain repeated area of peened specimen under equibiaxial residual stress by the cell. With the cell model, we investigate the FE peening coverage, dependency on the impact sequence, effect of repeated cycle. The proposed FE model provides converged and unique solution of surface stress, maximum compressive residual stress and deformation depth at four impact positions. Further, in contrast to the rigid and elastic shots, plastically deformable shot produces residual stresses closer to experimental solutions by X-ray diffraction. Consequently, it is confirmed that the FE model with peening factors and plastic shot is valid for multi-shot peening analyses.

Structure and Bonding of Perovskites A($Cu_{1/3}Nb_{2/3}$)$O_3$ (A=Sr, Ba and Pb) and their Series of Mixed Perovskites

  • Park Hyu-Bum;Huh Hwang;Kim Si-Joong
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.122-127
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    • 1992
  • Some perovskites $A($Cu_{1}3}Nb_{2}3}$)O_3(A=$Sr^{2+}$$, $Ba^{2+}$ and $Pb^{2+}$) and their series of mixed perovskites have been prepared by solid state reaction. Single perovskite phase was obtained in Sr or Ba rich samples, but pyrochlore phase was found in Pb rich samples. The stability of perovskite phase is dependent on the ionicity of bonding as well as the tolerance factor. All the obtained perovskites have tetragonal symmetry distorted by Jahn-Teller effect of $Cu^{2+}$. In the case of $Sr(Cu_{1}3}Nb_{2}3})O_3$, some superlattice lines caused by threefold enlarging of fundamental unit cell were observed. And, the symmetry of B site octahedron and the bonding character of B-O bond have been studied by IR, ESR and diffuse reflection spectroscopy. It appeared that the symmetry and the bonding character are influenced by such factors as the size and the basicity of A cation.

Characteristics of Interface States in One-dimensional Composite Photonic Structures

  • Zhang, Qingyue;Mao, Weitao;Zhao, Qiuling;Wang, Maorong;Wang, Xia;Tam, Wing Yim
    • Current Optics and Photonics
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    • v.6 no.3
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    • pp.270-281
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    • 2022
  • Based on the transfer-matrix method (TMM), we report the characteristics of the interface states in one-dimensional (1D) composite structures consisting of two photonic crystals (PCs) composed of binary dielectrics A and B, with unit-cell configurations ABA (PC I) and BAB (PC II). The dependence of the interface states on the number of unit cells N and the boundary factor x are displayed. It is verified that the interface states are independent of N when the PC has inversion symmetry (x = 0.5). Besides, the composite structures support the formation of interface states independent of the PC symmetry, except that the positions of the interface states will be varied within the photonic band gaps. Moreover, the robustness of the interface states against nonuniformities is investigated by adding Gaussian noise to the layer thickness. In the case of inversion symmetry (x = 0.5) the most robust interface states are achieved, while for the other cases (x ≠ 0.5) interface states decay linearly with position inside the band gap. This work could shed light on the development of robust photonic devices.

Area-Averaged Solution of Peening Residual Stress Using a 3D Multi-impact Symmetry-cell FE Model with Plastic Shots (소성숏이 포함된 3차원 다중충돌 대칭-셀 해석모델을 이용한 면적평균 피닝잔류응력해)

  • Kim, Tae-Hyung;Lee, Hyung-Yil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.310-320
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    • 2009
  • In this paper, we estimate area-averaged solution of peening residual stress using a 3-D multi-impact symmetry-cell FE model. The symmetry-cell model includes factors reflecting peening phenomena and plastic shot. Area-averaged solution is much closer to XRD experimental solution than 4-node-averaged solution in plastic shot FE model. We then obtain FE Almen saturation curve corresponding to experimental Almen curve based on area-averaged solution. Using the curve, we obtain FE area-averaged solution in major peening materials, and compare the FE solution with experimental solution. In peening materials, surface, maximum compressive residual stress and deformation depth reach experimental solutions. Thus, FE Almen curve is useful for estimation of residual stress solution and could improve the efficiency of peening process. Consequently, it is confirmed that concept of area-averaged solution is the realistic analytical method for evaluation of peening residual stress.

Complex Cell Image Segmentation via Structural Feature Information (구조적 특징 정보를 이용한 복잡한 세포영상 분할)

  • Kim, Seong-Gon
    • Journal of the Korea Society of Computer and Information
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    • v.17 no.10
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    • pp.35-41
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    • 2012
  • We propose a new marker driven Watershed algorithm for automated segmentation of clustered cell from microscopy image with less over segmentation. The Watershed Transform is able to segment extremely complex objects which are highly touched and overlapped each other. The success of the Watershed Transform depends essentially on the finding markers for each of the objects of interest. For extracting of markers positioning around center of each cell we used radial symmetry and iterative voting algorithms. With synthetic and real images, we quantitatively demonstrate the performance of our method and achieved better results than the other compared methods.

Symmetric-viewing liquid crystal display with alternating alignment layers in an inverse-twisted-nematic configuration

  • Na, Jun-Hee;Li, Hongmei;Park, Seung-Chul;Lee, Sin-Doo
    • Journal of Information Display
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    • v.12 no.4
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    • pp.191-194
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    • 2011
  • A symmetric-viewing inverse-twisted-nematic (ITN) liquid crystal display (LCD) with alternating alignment layers was developed using a stamping-assisted rubbing (SAR) technique. A patterned layer of a fluorinated acrylate polymer was transferred onto the first rubbed vertical-alignment layer prepared on a substrate by stamping. The fluorinated acrylate polymer provided a protective layer covering the first rubbed alignment layer during the second rubbing process, which promoted the vertical alignment of the LC molecules. The LC cell in the ITN geometry with two orthogonally rubbed alignment layers showed symmetric-viewing characteristics with fourfold symmetry. The SAR technique was shown to be a mask-free alignment method of producing multidomains for symmetric-viewing LCDs.

A Novel LC Device Associated with Optically Compensated Splay Structure (광학적 자기 보상 스플레이 구조를 갖는 새로운 액정 소자)

  • 김승재;이종문;이승희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.536-540
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    • 2004
  • A novel nematic liquid crystal (LC) cell with splay structure exhibiting wide viewing angle, fast response time and high transmittance at the same time has been developed. With rubbed homeotropic alignment in parallel directions, the device shows bend alignment in the absence of vertical electric field. However, with applied high voltage in a pulse form, the LC shows a optically compensated splay (OCS) orientation such that the mid-director is parallel to a substrate and at both surfaces the LCs are aligned vertically in parallel direction. In the device, the birefringence of the cell becomes tunable with applying voltage, i.e., the amount of light passed through the cell can be controlled by controlling the orientation of the LC. Since the OCS cell has a self-compensation structure such that the LC has a mirror symmetry along the mid-director, the device shows a wide viewing angle with only a single domain and a fast response time.

The Structure of Tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene (Tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene 구조에 관한 연구)

  • 박영자
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.105-112
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    • 1996
  • The structure of the tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene (C50H64O6) has been determined by X-ray diffraction methods. The crystal is monoclinic, space group C2/c, unit cell constant a=16.067(2), b=26.391(17), c=10.335(1)Å, β=94.26(1)°, Z=4, V=4370.2(29)Å3, Dc=1.16, Dm=1.2 gcm-3. The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with a graphite monochromated Cu-Kα radiation (λ=1.5418Å). The structure was solved by direct methods and refined by least-squares methods. The final R value was 0.07 for 2354 observed reflections. The molecule has the 1, 3-alternate conformation with own two-fold symmetry axis, : two propionyloxy phenyl groups are up and the other two hydroxy phenyl groups are down.

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A Study of the Relationship Analysis of Power Conversion and Changed Capacitance in the Depletion Region of Silicon Solar Cell

  • Kim, Do-Kyeong;Oh, Yeong-Jun;Kim, Sang-Hyun;Hong, Kyeong-Jin;Jung, Haeng-Yeon;Kim, Hoy-Jin;Jeon, Myeong-Seok
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.177-181
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    • 2013
  • In this paper, silicon solar cells are analyzed regarding power conversion efficiency by changed capacitance in the depletion region. For the capacitance control in the depletion region of silicon solar cell was applied for 10, 20, 40, 80, 160 and 320 Hz frequency band character and alternating current(AC) voltage with square wave of 0.2~1.4 V. Academically, symmetry formation of positive and negative change of the p-n junction is similar to the physical effect of capacitance. According to the experiment result, because input of square wave with alternating current(AC) voltage could be observed to changed capacitance effect by indirectly method through non-linear power conversion (Voltage-Current) output. In addition, when input alternating current(AC) voltage in the silicon solar cell, changed capacitance of depletion region with the forward bias condition and reverse bias condition gave a direct effect to the charge mobility.