• Title/Summary/Keyword: Symmetric condition

Search Result 279, Processing Time 0.027 seconds

Synthesis of Aminated Poly(ether sulfone) as Anion Exchanger and its NO Gas Adsorption (Aminated Poly(ether sulfone)의 합성과 NO 가스의 흡착특성)

  • Son, W.K.;Park, S.G.
    • Applied Chemistry for Engineering
    • /
    • v.10 no.6
    • /
    • pp.857-862
    • /
    • 1999
  • Aminated poly(ether sulfone)(APES) was prepared by amination of nitrated poly(ether sulfone)(NPES) after poly(ether sulfone)(PES) was nitrated with mixed acid of nitric acid and sulfuric acid(sulfuric acid is a catalyst). As a results of the FT-IR spectrum analysis, the nitration of PES was confirmed by the bands of asymmetric stretching and symmetric stretching of $NO_2$ group at 1537 and $1351cm^{-1}$, respectively. Also when the NPES was aminated, it was disappeared to absorbance peaks of $NO_2$ group. And It was confirmed by the bands of asymmetric stretching and symmetric stretching of $NH_2$ group at 3470 and $3374cm^{-1}$, respectively. The optimum condition of the nitration on PES(5 g; 21.55 mmol.) was 12 hr of reaction time, $120^{\circ}C$ of reaction temperature, nitric acid of 28.00 mmol. and sulfuric acid of 52.00 mmol. As a result of the elemental analysis of APES, reapeating unit per amine groups were induced to 0.89. The adsorption rate of NO gas was lower than that of silica gel and active carbon. But the adsorption capacity of NO gas was higher than that of these. When the APES was absorbed to NO gas, the chemical adsorption rate was lower than the physical adsorption rate. But the chemical adsorption capacity of it was higher than physical adsorption capacity.

  • PDF

Laryngeal Measurement on Neck CT (경부 전산화단층촬영상에서 후두계측)

  • 유영채;오재식
    • Korean Journal of Bronchoesophagology
    • /
    • v.2 no.1
    • /
    • pp.71-81
    • /
    • 1996
  • The normal larynx locates to the front of the neck symmetrically and the thyroid notch lies in the center of the neck, but practically the larynx is not symmetric in all people. From a clinical point of views, there are vague cases to decide whether a disordered laryngeal structure is within normal variations or a pathologic condition. The purpose of this study is to investigate the anatomy of the laryngeal framework in normal population. Authors investigate various measures of normal laryngeal framework, such as symmetry and length of the larynx, levels of the hyoid bone and vocal cord and angle of thyroid cartilage by using calipers and protractor on 45 cases of neck CT. The results are summerized as follows. 1. The laryngeal framework was asymmetric to a greater or lesser extent in most cases with directional preponderance to the right side. The degree of asymmetry did not differ among different age groups and between seres. 2. The level of the hyoid bone ranged from C2-C3 vertebrae to C5-C6 intervertebral space with most frequent level of C5. 3. The level of the vocal cord ranged from 01 vertebra to C6-C7 intervertebral space with most frequent level of C5. 4. The angle of thyroid cartilage ranged from 58 degree to 100 degree with average of 81.5 and mean angle between both thyroid alae were 77.24 degree in male and 87.88 degree in female.

  • PDF

Optical Spectroscopy of$Eu^{3+}$in Borosilicate Glasses (붕규산유리 매질 내에서의$Eu^{3+}$이온의 형광특성)

  • Kim, Jong Goo;Lee, Jong Gyu;Kim, Jung Suk;Kim, Seung Soo;Chun, Kwan Sik
    • Journal of the Korean Chemical Society
    • /
    • v.41 no.5
    • /
    • pp.251-255
    • /
    • 1997
  • Fluorescence spectra and life time of $Eu^{3+}$ ion in borosilicate glass medium are measured. Electronic transitions of $Eu^{3+}$ ion in borosilicate glass medium are found to come from $5D0{\rightarrow}7FJ$(J=0, 1, 2, 3, 4) transitions of SL coupling system in $f^b$ electrons configuration. From the number of Stark sublevels in spetra, crystal field for $Eu^{3+}$ ion is also found to have the symmetric character of low symmetry order, $n{\leq}2$. The fraction and the number of components of life times were varied depending on the composition of $Eu^{3+}$ in borosilicate glasses, from which the binding condition between the $Eu^{3+}$ ion and anionic oxygen of borosilicate glass can be deduced.

  • PDF

Design of High Speed Tensile Test Machine for Flow Stress under Intermediate Strain Rate Condition (중변형률 속도 유동응력 확보를 위한 고속 인장 실험기 설계)

  • Choung, Joonmo;Yoon, Sung-Won;Park, Sung-Ju;Kim, Younghun
    • Journal of Ocean Engineering and Technology
    • /
    • v.29 no.1
    • /
    • pp.34-44
    • /
    • 2015
  • A hydraulic tensile test machine (HSTM) is one of the devices used to obtain the flow stress of a material during high-speed elongation. This paper first describes some features of a newly built HSTM. The improvement histories of the upper and lower jigs, which are the most vital parts of the HSTM, are also presented. We have frequently witnessed test failures with 1st generation jigs and specimens due to slip between the jig and specimen. 2nd generation jigs provide more stable test results, but the use of a longer upper jig induces excessive vibration and consequently makes it difficult to attach an environment chamber. 3rd generation jigs have some advances in terms of the symmetric fastening between the upper jig and specimen, as well as an exemption from direct contact between the lower jig and specimen. The performance of an environment chamber is verified by high and low temperature tests. A high-speed displacement measurement system is introduced based on a high-speed camera and motion-tracking software with aid of a surface grid device for the specimen.

High-Velocity Impact Damage Behavior of Carbon/Epoxy Composite Laminates

  • Kim, Young A.;Woo, Kyeongsik;Cho, Hyunjun;Kim, In-Gul;Kim, Jong-Heon
    • International Journal of Aeronautical and Space Sciences
    • /
    • v.16 no.2
    • /
    • pp.190-205
    • /
    • 2015
  • In this paper, the impact damage behavior of USN-150B carbon/epoxy composite laminates subjected to high velocity impact was studied experimentally and numerically. Square composite laminates stacked with $[45/0/-45/90]_{ns}$ quasi-symmetric and $[0/90]_{ns}$ cross-ply stacking sequences and a conical shape projectile with steel core, copper skin and lead filler were considered. First high-velocity impact tests were conducted under various test conditions. Three tests were repeated under the same impact condition. Projectile velocity before and after penetration were measured by infrared ray sensors and magnetic sensors. High-speed camera shots and C-Scan images were also taken to measure the projectile velocities and to obtain the information on the damage shapes of the projectile and the laminate specimens. Next, the numerical simulation was performed using explicit finite element code LS-DYNA. Both the projectile and the composite laminate were modeled using three-dimensional solid elements. Residual velocity history of the impact projectile and the failure shape and extents of the laminates were predicted and systematically examined. The results of this study can provide the understanding on the penetration process of laminated composites during ballistic impact, as well as the damage amount and modes. These were thought to be utilized to predict the decrease of mechanical properties and also to help mitigate impact damage of composite structures.

Stress Intensity factor Calculation for the Axial Semi-Elliptical Surface Flaws on the Thin-Wall Cylinder Using Influence Coefficients (영향계수를 이용한 원통용기 축방향 표면결함의 응력확대계수의 계산)

  • Jang, Chang-Heui;Moon, Ho-Rim;Jeong, Ill-Seok;Kim, Tae-Ryong
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.26 no.11
    • /
    • pp.2390-2398
    • /
    • 2002
  • For integrity analysis of nuclear reactor pressure vessel, including the Pressurized thermal shock analysis, the fast and accurate calculation of the stress intensity factor at the crack tip is needed. For this, a simple approximation scheme is developed and the resulting stress intensity factors for axial semi-elliptical cracks in cylindrical vessel under various loading conditions are compared with those of the finite element method and other approximation methods, such as Raju-Newman's equation and ASME Sec. Xl approach. For these, three-dimensional finite-element analyses are performed to obtain the stress intensity factors for various surface cracks with t/R = 0.1. The approximation methods, incorporated in VINTIN (Vessel INTegrity analysis-INner flaws), utilizes the influence coefficients to calculate the stress intensity factor at the crack tip. This method has been compared with other solution methods including 3-D finite clement analysis for internal pressure, cooldown, and pressurized thermal shock loading conditions. The approximation solutions are within $\pm$2.5% of the those of FEA using symmetric model of one-forth of a vessel under pressure loading, and 1-3% higher under pressurized thermal shock condition. The analysis results confirm that the VINTIN method provides sufficiently accurate stress intensity factor values for axial semi-elliptical flaws on the surface of the reactor pressure vessel.

Effects of Plastic AFO and Shoes on Static Standing Balance in Hemiplegic Patients (플라스틱 단하지 보조기와 신발 착용이 편마비 환자의 정적 선자세 균형에 미치는 영향)

  • Kim, Joong-Hwi;Kim, Chung-Sun
    • The Journal of Korean Physical Therapy
    • /
    • v.13 no.2
    • /
    • pp.381-397
    • /
    • 2001
  • In the patients with hemiplegia caused by stroke and TBI. postural sway is increased and open displaced laterally over the non-affected leg, reflecting asymmetry in weight bearing on lower extremities during standing balance. Recovery of symmetric weight bearing and postural stability is an important aim in physical therapy. Plastic AFO has been used for hemiplegic patients in order to help their abnormal walking patterns. Past studies have mainly focused on the AFO influences on hemiplegic walking patterns without balance function approaches. The purpose of this study was to identify the immediate effects of plastic AFO and shoes on the static balance in hemiplegic patients. The scale for static balance were weight bearing on affected leg(%), sway area(mm2), sway path(mm), maximal sway velocity(mm/s), anteroposterior sway angle($^{\circ}$ ), and lateral angle($^{\circ}$ ). Seventeen hemiplegic patients participated in this study: 13 men and 4 women, with an average age of 50.18 years. Static balance was measured using BPM(balance performance monitor; dataprint software version 5.3) under four standing condition namely bare-foot standing. standing in shoes, standing with AFO, and standing in shoes with AFO. In order to assure the statistical significance of the results, an one-way ANOVA, the independent t-test. and a pearson's correlation were applied at the .05 level of significant. The results of this study were as follows: 1) There were statistically significant differences in weight bearing(%) on the static balance between affected leg and non-affected leg(p<.01). 2) There were statistically significant differences in sway reverse frequence(Hz) in standing with AFO between affected leg and non-affected leg(p<.05). 3) Sway area(mm2) on standing in shoes with AFO was lower than bare-foot standing(p<.05), Lateral sway angle($^{\circ}$ ) on standing in shoes with AFO was lower than bare-foot standing and standing in shoes(p<.05). 4) Weight bearing in affected leg was not significantly correlated with postural sway.

  • PDF

THE CURVATURE TENSORS IN THE EINSTEIN′S *g- UNIFIED FIELD THEORY I. THE SE-CURVATURE TENSOR OF *g-SE $X_{n}$

  • Chung, Kyung-Tae;Chung, Phil-Ung;Hwang, In-Ho
    • Journal of the Korean Mathematical Society
    • /
    • v.35 no.4
    • /
    • pp.1045-1060
    • /
    • 1998
  • Recently, Chung and et al. ([11], 1991c) introduced a new concept of a manifold, denoted by *g-SE $X_{n}$ , in Einstein's n-dimensional *g-unified field theory. The manifold *g-SE $X_{n}$ is a generalized n-dimensional Riemannian manifold on which the differential geometric structure is imposed by the unified field tensor * $g^{λν}$ through the SE-connection which is both Einstein and semi-symmetric. In this paper, they proved a necessary and sufficient condition for the unique existence of SE-connection and presented a beautiful and surveyable tensorial representation of the SE-connection in terms of the tensor * $g^{λν}$. This paper is the first part of the following series of two papers: I. The SE-curvature tensor of *g-SE $X_{n}$ II. The contracted SE-curvature tensors of *g-SE $X_{n}$ In the present paper we investigate the properties of SE-curvature tensor of *g-SE $X_{n}$ , with main emphasis on the derivation of several useful generalized identities involving it. In our subsequent paper, we are concerned with contracted curvature tensors of *g-SE $X_{n}$ and several generalized identities involving them. In particular, we prove the first variation of the generalized Bianchi's identity in *g-SE $X_{n}$ , which has a great deal of useful physical applications.tions.

  • PDF

Three Phase Embedded Z-Source Inverter (3상 임베디드 Z-소스 인버터)

  • Oh, Seung-Yeol;Kim, Se-Jin;Jung, Young-Gook;Lim, Young-Cheol
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.17 no.6
    • /
    • pp.486-494
    • /
    • 2012
  • In this paper, we proposes the three-phase embedded Z-source inverter consisting of the three embedded Z-source converters and it's the output voltage control method. Each embedded Z-source converter can produce the bipolar output capacitor voltages according to duty ratio D such as single-phase PWM inverter. The output AC voltage of the proposed system is obtained as the difference in the output capacitor voltages of each converter, and the L-C output filter is not required. Because the output AC voltage can be stepped up and down, the boost DC converter in the conventional two-stage inverter is unnecessary. To confirm the validity of the proposed system, PSIM simulation and a DSP based experiment were performed under the condition of the input DC voltage 38V, load $100{\Omega}$, and switching frequency 30kHz. Each converter is connected by Y-connection for three-phase loads. In case that the output phase voltage is the same $38V_{peak}$ as the input DC voltage and is the 1.5 times($57V_{peak}$), the simulation and experimental results ; capacitor voltages, output phase voltages, output line voltages, inductor currents, and switch voltages were verified and discussed.

Behavior of Pile Groups in Granite Soil Under Lateral Loading (화강풍화토에서 수평력을 받는 무리말뚝의 거동)

  • Ahn, Kwangkuk;Ko, Pilhwan
    • Journal of the Korean GEO-environmental Society
    • /
    • v.10 no.5
    • /
    • pp.69-73
    • /
    • 2009
  • In this study, three dimensional numerical analyses were performed with variation of pile spacing (S=3D, 4D, 5D) to compare the behaviour of single pile and pile group with cap in granite soil. In order to compare and analyze the lateral resistance of single pile and pile group by changing pile spacing, the pile group with array of $1{\times}3$ was employed. To reduce the computation time the symmetric boundary condition was used. And Druker-Prager model and elasticity model were used for granite soil and for concrete pile and cap, respectively. Using the analyses results of pile group in granite soil under lateral loading, p-y curve for pile group and single pile with changing pile spacing was drawn. With p-y curve p-multiplier was evaluated. As a result of analysis, the value of p-multiplier was increased with increasing pile spacing under 1.0 due to pile shadow effects.

  • PDF