• Proceedings of the KIEE Conference
• /
• 2007.07a
• /
• pp.623-624
• /
• 2007

This work examines the effects of swelling MI type HVDC cable oil on the semiconductive silicone rubber and silicone rubber as used in accessories for application on outdoor termination (EBA) slip on sleeve. The behavior of volume resistivity is monitored as a function of the amount of cable oil diffused into the material. Resistivities of semiconductive silicone samples up to the typical insulator range (${\sim}10^{10}{\Omega}-cm$) are observed as a consequence of swelling due to the presence of the diffused oil. The measured volume resistivities of the oil-impregnated semiconductive silicone rubber are compared to desired value as function of stress relief cone.

• Elastomers and Composites
• /
• v.48 no.1
• /
• pp.55-60
• /
• 2013

Swelling behaviors of raw (Specimen-R) and compressed (Specimen-C) samples of maleic anhydride-grafted EPDM (MAH-g-EPDM) depending on the treatment with dichloroacetic acid were investigated. Structural characteristics of the samples were analyzed by nuclear magnetic resonance spectroscopy (NMR) and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). When the samples were not treated with dichloroacetic acid, the swelling ratio of Specimen-R was greater than that of Specimen-C by about twice and the swelling ratio change was negligible though the process of swelling and drying was repeated. When the samples were treated with dichloroacetic acid, the first swelling ratios were increased but the second ones were decreased. For the Specimen-C, the swelling ratio of the sample without the dichloroacetic acid treatment and the second swelling ratio of the sample treated with dichloroacetic acid were nearly the same. However, for the Specimen-R, the second swelling ratio of the sample treated with dichloroacetic acid was strikingly lower than that of the sample without the dichloroacetic acid treatment. The swelling ratio change according to the dichloroacetic acid treatment was explained by dissociation of the existing crosslinks and formation of new crosslinks.

• Membrane Journal
• /
• v.5 no.1
• /
• pp.44-57
• /
• 1995

A mathematical model was proposed to describe the behavior of the liquid emulsion membrane(LEM) conraining sodium carbonate as internal stripping reagent. Experimental results of the batch extraction of lactic acid were compared with computed results by using the model. it was found that the model computations could predict fairly well the effects of parameter variations such as the carrier concentration, the stripping reagent concentration, the stirrer speed and the treatment ratio. An attempt has been made to reduce emulsion swelling which is one of the main problem of LEM. As the additives for swelling control, liquid paraffin, n-decanol, cyclohexanone and Span 85 were used. All the additives that were investigated tend to reduce the quantity of swelling to some extent. Cyclohexanone was found not only to reduce the swelling but also to increase largely the acid transport rate.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3163-3172
• /
• 2010

In this work, a novel method to synthesis of an acrylic superabsorbent hydrogel was reported. In the two stage hydrogel synthesis, first copolymerization reaction of acrylonitrile (AN) and acrylamide (AM) monomers using ammonium persulfate (APS) as a free radical initiator was performed. In the second stage, the resulted copolymer was hydrolyzed to produce carboxamide and carboxylate groups followed by in situ crosslinking of the polyacrylonitrile chains. The results from FTIR spectroscopy and the dark red-yellow color change show that the copolymerization, alkaline hydrolysis and crosslinking reactions have been do take place. Scanning electron microscopy (SEM) verifies that the synthesized hydrogels have a porous structure. The results of Brunauer-Emmett-Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 13.9 nm. The synthetic parameters affecting on swelling capacity of the hydrogel, such as AM/AN weight ratio and hydrolysis time and temperature, were systematically optimized to achieve maximum swelling capacity (330 g/g). The swollen gel strength of the synthesized hydrogels was evaluated via viscoelastic measurements. The results indicated that superabsorbent polymers with high water absorbency were accompanied by low gel strength. The swelling of superabsorbent hydrogels was also measured in various solutions with pH values ranging from 1 to 13. Also, the pH reversibility and on-off switching behavior makes the hydrogel as a good candidate for controlled delivery of bioactive agents. Finally, the swelling of synthesized hydrogels with various particle sizes obey second order kinetics.

• Polymer(Korea)
• /
• v.24 no.3
• /
• pp.418-430
• /
• 2000

A new hydroxylpropyl chitosan (HPCTO) capable of forming both thermotropic and lyotropic liquid crystalline phases was synthesized by reaction of alkali chitosan with propylene oxide and its solid films cross-linked with glyoxal were prepared by casting the liquid crystalline solution in methanol. The thermal and swelling properties of the cross-linked films were investigated. The films displayed fingerprint patterns characteristic of cholesteric liquid-crystalline phase, and their pitches increased with increasing temperature and cross-linker concentration. The cross-linked samples exhibited an anisotropic swelling in both water and methanol, suggesting that the two-dimensional cross-linking preferentially performs between HPCTO molecules. The degree of anisotropy highly depended on the solvent, but hardly on the cross-linker concentration investigated.

• Polymer(Korea)
• /
• v.35 no.6
• /
• pp.558-564
• /
• 2011

The biocompatibility and biodegradability of poly(amino acid) make them ideal candidates for many bio-related applications. Poly(aspartic acid), PASP, is one of synthetic water-soluble polymers with proteinlike structure, and has been extensively explored for the potential industrial and biomedical applications due to its biodegradable, biocompatible and pH-responsive properties. In this work, amino acid-conjugated PASPs were prepared by aminolysis reaction onto polysuccinimide (PSI) using ${\gamma}$-aminobutylic acid(GABA) and ${\beta}$-alanine methyl ester and a subsequent hydrolysis process. Their chemical gels were prepared by crosslinking reaction with ethylene glycol diglycidyl ether (EGDE). The hydrogels were investigated for their basic swelling behavior, hydrolytic degradation and morphology. The crosslinked gels showed a responsive swelling behavior, which was dependent on pH and salt concentration in aqueous solution, and relatively fast hydrolytic degradation.

• Geomechanics and Engineering
• /
• v.22 no.3
• /
• pp.227-236
• /
• 2020

Expansive soils are renowned for their swelling-shrinkage property and these volumetric changes resultantly cause huge damage to civil infrastructures. Likewise, subgrades consisting of expansive soils instigate serviceability failures in pavements across various regions of Pakistan and worldwide. This study presents the use of polypropylene fibers to improve the engineering properties of a local swelling soil. The moisture-density relationship, unconfined compressive strength (UCS) and elastic modulus (E₅₀), California bearing ratio (CBR) and one-dimensional consolidation behavior of the soil treated with 0, 0.2, 0.4, 0.6 and 0.8% fibers have been investigated in this study. It is found that the maximum dry density of reinforced soil slightly decreased by 2.8% due to replacement of heavier soil particles by light-weight fibers and the optimum moisture content remained almost unaffected due to non-absorbent nature of the fibers. A significant improvement has been observed in UCS (an increase of 279%), E₅₀ (an increase of 113.6%) and CBR value (an increase of 94.4% under unsoaked and an increase of 55.6% under soaked conditions) of the soil reinforced with 0.4% fibers, thereby providing a better quality subgrade for the construction of pavements on such soils. Free swell and swell pressure of the soil also significantly reduced (94.4% and 87.9%, respectively) with the addition of 0.8% fibers and eventually converting the medium swelling soil to a low swelling class. Similarly, the compression and rebound indices also reduced by 69.9% and 88%, respectively with fiber inclusion of 0.8%. From the experimental evaluations, it emerges that polypropylene fiber has great potential as a low cost and sustainable stabilizing material for widespread swelling soils.

• Nuclear Engineering and Technology
• /
• v.24 no.1
• /
• pp.40-51
• /
• 1992

One of the important irradiation performance characteristics of the silicide dispersion fuel element in research reactors is the diameteral increase resulting from fuel swelling. This paper, will attempt to develop a physical model for the fuel swelling, DFSWELL, by analyzing the basic irradiation behaviours and some experimental evidences. From the experimental evidences, it was shown that the volume changes in irradiated U$_3$Si-Al were strongly dependent on temperature and fission rate. The quantitative-amount of swelling for silicide fuel is estimated by considering temperature, fission rate, solid fission product build-up and gas bubble behavior. The swelling for the silicide fuel is comprised of three major components : i ) a volume change due to the formation of an interfacial layer between the fuel particle and matrix. ii ) a volume change due to the accumulation of gas bubble nucleation iii ) a volume change due to the accumulation of solid fission products The DFSWELL model which takes into account the above three major physical components predicts well the absolute magnitude of silicide fuel swelling in accordance with the power histories in comparison with the experimental data.

• Geomechanics and Engineering
• /
• v.8 no.5
• /
• pp.687-706
• /
• 2015

Methods commonly used to evaluate the improvement of lime-treated expansive soil include swelling characteristics and unconfined compressive strength. In the field, lime-treated expansive soils are in compacted unsaturated state. Soil water characteristic curves (SWCCs) represent a key parameter to interpret and describe the behavior of unsaturated expansive soil. This paper investigates the use of SWCC as a technique to evaluate improvements acquired by expansive soil after lime treatment. Three different lime contents were considered 2%, 4% and 6% by dry weight of clay. Series of tests were performed to determine the SWCC for the different lime content under curing periods of 7 and 28 day. Correlations between key features of the soil water characteristic curves of lime treated expansive soils and basic engineering behavior such as swelling characteristics and unconfined compression strength were established. Test results revealed that initial slope ($S_1$), saturated water content ($w_{sat}$), and air entry value (AEV) play an important role in reflecting improvement in engineering behavior achieved by lime treatment.

• Journal of the Korean Geotechnical Society
• /
• v.40 no.3
• /
• pp.7-18
• /
• 2024

In this study, slope stability was evaluated in consideration of unsaturated soil behavior to predict landslides. Samples were collected from a landslide site due to heavy rainfall during Typhoon Hinnamnoh. Soil moisture characteristic tests were performed based on the evaporation method using a swelling undisturbed sample and a remolded sample. Based on the hydraulic-mechanical behavior, two-dimensional infiltration and stability analyses were performed. As a result, from the two sample types, it is found that both behaviors exhibited clear differences in the results, and the behavior of the swelling undisturbed sample was able to predict the actual slope failure appropriately.