• Title/Summary/Keyword: Swelling behavior

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Effects of organic silicone additive material on physical and mechanical properties of mudstone

  • Chai, Zhaoyun;Kang, Tianhe;Chen, Weiyi
    • Geomechanics and Engineering
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    • v.6 no.2
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    • pp.139-151
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    • 2014
  • Mudstone is a very common rock that, when in contact with water, can exhibit considerable volume change and breakdown. This behavior of mudstone is frequently encountered in geotechnical engineering and has a considerable influence on infrastructure stability. This is particularly important in the present work, which focuses on mitigating the harmful properties of mudstone. The samples studied are of Permian Age mudstone from Shandong Province, China. Modification tests using organic silicone additive material were carried out. The mechanisms of physical properties modification of mudstone were comparatively studied using corresponding test methods, and the modification mechanism of organic silicone additive material acting on mudstone was analyzed. The following conclusions were drawn. The surface texture and characters of mudstone changed dramatically, surface character turns from hydrophilic to hydrophobic after organic silicone additive material modification. The changes in the surface character indicate a reduction in the water sensitivity of mudstone. After modification, the shape of porosity and fracture of mudstone changed unremarkable, and the total and free expansion ratios decreased obviously, whereas the strength increased markedly.

Clear cell odontogenic carcinoma: a mini review

  • Kim, Young Hwan;Seo, Eun Jin;Park, Jae Kyung;Jang, Il Ho
    • International Journal of Oral Biology
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    • v.44 no.3
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    • pp.77-80
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    • 2019
  • Clear cell odontogenic carcinoma (CCOC), a very rare neoplasm located mostly in the mandible, has been regarded as a benign tumor. However, due to the accumulation of case reports, CCOC has been reclassified as a malignant entity by the World Health Organization. Patients with CCOC present with regional swelling and periodontal indications with variable pain, often remaining misdiagnosed for a long period. CCOC has slow growth but aggressive behavior, requiring radical resection. Histologic analysis revealed the monophasic, biphasic, and ameloblastic types of CCOC with clear cells and a mixed combination of polygonal and palisading cells. At the molecular level, CCOC shows the expression of cytokeratin and epithelial membrane antigen, along with markers that assign CCOC to the sarcoma family. At the genetic level, Ewing sarcoma breakpoint region 1-activating transcription factor 1 fusion is regarded as the key feature for identification. Nevertheless, the scarcity of cases and dependence on histological data delay the development of an efficient therapy. Regarding the high recurrence rate and the potential of distant metastasis, further characterization of CCOC is necessary for an early and accurate diagnosis.

Constructional Verification Evaluation for Securing the Field Quality of Composite Membrane Waterproofing Material (멤브레인 복합 방수재의 현장품질 안정성 확보를 위한 시공성 실증 평가 연구)

  • Kim, Meong-Ji;Lee, Sang-Wook;Kim, Soo-Yeon;Oh, Sang-Keun
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.1
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    • pp.87-95
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    • 2021
  • In this study, seven companies(A~G) designated as new construction technology selected and evaluated KS F 2622: Method of test for performance evaluation of membrane roofing systems that are similar to field application conditions. As a result of the test, it was confirmed that although all test specimens exceeded KS standards in the basic physical, it was difficult to obtain field quality performance in weak areas such as joints and vertical parts of the adhesive coating method in water-tightness, sagging resistance, swelling resistance tests except for fatigue(crack behavior) tests.

Radiation damage analysis in SiC microstructure by transmission electron microscopy

  • Idris, Mohd Idzat;Yoshida, Katsumi;Yano, Toyohiko
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.991-996
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    • 2022
  • Microstructures of monolithic high purity SiC and SiC with sintering additives after neutron irradiation to a fluence of 2.0-2.5 × 1024 n/m2 (E > 0.1 MeV) at 333-363 K and after post-irradiation annealing up to 1673 K were observed using a transmission electron microscopy. Results showed that no black spot defects or dislocation loops in SiC grains were found after the neutron irradiation for all of the specimens owing to the moderate fluence at low irradiation temperature. Thus, it is confirmed that these specimens were swelled mostly by the formation of point defects. Black spots and small dislocation loops were discovered only after the annealing process in PureBeta-SiC and CVD-SiC, where the swelling almost diminished. Anomalous-shaped YAG grains were found in SiC ceramics containing sintering additives. These grains contained dense black spots defects and might lose crystallinity after the neutron irradiation, while these defects may annihilate by recrystallization during annealing up to 1673 K. Amorphous grain boundary phase was also presented in this ceramic, and a large part of it was crystallized through post-irradiation annealing and could affect their recovery behavior.

International Joint Research for the Colloid Formation and Migration in Grimsel Test Site: Current Status and Perspectives

  • Sang-Ho Lee;Jin-Seok Kim;Bong-Ju Kim;Jae-Kwang Lee;Seung Yeop Lee;Jang-Soon Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.455-468
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    • 2022
  • Colloid Formation and Migration (CFM) project is being carried out within the Grimsel Test Site (GTS) Phase Ⅵ. Since 2008, the Korea Atomic Energy Research Institute (KAERI) has joined CFM to investigate the behavior of colloid-facilitated radionuclide transport in a generic Underground Research Laboratory (URL). The CFM project includes a long-term in-situ test (LIT) and an in-rock bentonite erosion test (i-BET) to assess the in-situ colloid-facilitated radionuclide transport through the bentonite erosion in the natural flow field. In the LIT experiment, radionuclide-containing compacted bentonite was equipped with a triple-packer system and then positioned at the borehole in the shear zone. It was observed that colloid transport was limited owing to the low swelling pressure and low hydraulic conductivity. Therefore, a postmortem analysis is being conducted to estimate the partial migration and diffusion of radionuclides. The i-BET experiment, that focuses more on bentonite erosion, was newly designed to assess colloid formation in another flow field. The i-BET experiment started with the placement of compacted bentonite rings in the double-packer system, and the hydraulic parameters and bentonite erosion have been monitored since December 2018.

Simplified analysis of creep for preloaded reconstituted soft alluvial soil from Famagusta Bay

  • Garoushi, Ali Hossien Basheer;Uygar, Eris
    • Geomechanics and Engineering
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    • v.28 no.2
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    • pp.157-169
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    • 2022
  • Preloading of soft clays is a common ground stabilization method for improvement of compressibility and the undrained shear strength. The waiting period under preload is a primary design criterion controlling the degree of improvement obtained. Upon unloading the overconsolidation attained with respect to actual loads defines the long term performance. This paper presents a laboratory study for investigation of creep behavior of Famagusta Bay alluvial soft soil preloaded under various effective stresses for analysis of long term performance based on the degree of overconsolidation. Traditional one-dimensional consolidation tests as well as modified creep tests are performed on reconstituted soft specimens. Compressibility parameters are precisely backcalculated using one dimensional consolidation theory and the coefficient of creep is determined using the traditional Cassagrande method as well as two modified methods based on log cycles of time and the inflection of the creep curve. The test results indicated that the long term creep can be successfully predicted considering the proposed method. The creep coefficients derived as part of this method can also be related to the recompression index (recompression index, swelling index) considering the results of the testing method adopted in this study.

Maximum shear modulus of rigid-soft mixtures subjected to overconsolidation stress history

  • Boyoung Yoon;Hyunwook Choo
    • Geomechanics and Engineering
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    • v.37 no.5
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    • pp.443-452
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    • 2024
  • The use of sand-tire chip mixtures in construction industry is a sustainable and environmentally friendly approach that addresses both waste tire disposal and soil improvement needs. However, the addition of tire chip particles to natural soils decreases maximum shear modulus (Gmax), but increases compressibility, which can be potential drawbacks. This study examines the effect of overconsolidation stress history on the maximum shear modulus (Gmax) of rigid-soft mixtures with varying size ratios (SR) and tire chip contents (TC) by measuring the wave velocity through a 1-D compression test during loading and unloading. The results demonstrate that the Gmax of tested mixtures in the normally consolidated state increased with increasing SR and decreasing TC. However, the tested mixtures with a smaller SR exhibited a greater increase in Gmax during unloading because of the active pore-filling behavior of the smaller rubber particles and the consequent increased connectivity between sand particles. The SR-dependent impact of the overconsolidation stress history on Gmax was verified using the ratio between the swelling and compression indices. Most importantly, this study reveals that the excessive settlement and lower Gmax of rigid-soft mixtures can be overcome by introducing an overconsolidated state in sand-tire chip mixtures with low TC.

Development of FURA Code and Application for Load Follow Operation (FURA 코드 개발과 부하 추종 운전에 대한 적용)

  • Park, Young-Seob;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • v.20 no.2
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    • pp.88-104
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    • 1988
  • The FUel Rod Analysis(FURA) code is developed using two-dimensional finite element methods for axisymmetric and plane stress analysis of fuel rod. It predicts the thermal and mechanical behavior of fuel rod during normal and load follow operations. To evaluate the exact temperature distribution and the inner gas pressure, the radial deformation of pellet and clad, the fission gas release are considered over the full-length of fuel rod. The thermal element equation is derived using Galerkin's techniques. The displacement element equation is derived using the principle of virtual works. The mechanical analysis can accommodate various components of strain: elastic, plastic, creep and thermal strain as well as strain due to swelling, relocation and densification. The 4-node quadratic isoparametric elements are adopted, and the geometric model is confined to a half-pellet-height region with the assumption that pellet-pellet interaction is symmetrical. The pellet cracking and crack healing, pellet-cladding interaction are modelled. The Newton-Raphson iteration with an implicit algorithm is applied to perform the analysis of non-linear material behavior accurately and stably. The pellet and cladding model has been compared with both analytical solutions and experimental results. The observed and predicted results are in good agreement. The general behavior of fuel rod is calculated by axisymmetric system and the cladding behavior against radial crack is used by plane stress system. The sensitivity of strain aging of PWR fuel cladding tube due to load following is evaluated in terms of linear power, load cycle frequency and amplitude.

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Physicochemical Characteristics of Fe3O4 Magnetic Nanocomposites Based on Poly(N-isopropylacrylamide) for Anti-cancer Drug Delivery

  • Davaran, Soodabeh;Alimirzalu, Samira;Nejati-Koshki, Kazem;Nasrabadi, Hamid Tayefi;Akbarzadeh, Abolfazl;Khandaghi, Amir Ahmad;Abbasian, Mojtaba;Alimohammadi, Somayeh
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.1
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    • pp.49-54
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    • 2014
  • Background: Hydrogels are a class of polymers that can absorb water or biological fluids and swell to several times their dry volume, dependent on changes in the external environment. In recent years, hydrogels and hydrogel nanocomposites have found a variety of biomedical applications, including drug delivery and cancer treatment. The incorporation of nanoparticulates into a hydrogel matrix can result in unique material characteristics such as enhanced mechanical properties, swelling response, and capability of remote controlled actuation. Materials and Methods: In this work, synthesis of hydrogel nanocomposites containing magnetic nanoparticles are studied. At first, magnetic nanoparticles ($Fe_3O_4$) with an average size 10 nm were prepared. At second approach, thermo and pH-sensitive poly (N-isopropylacrylamide -co-methacrylic acid-co-vinyl pyrrolidone) (NIPAAm-MAA-VP) were prepared. Swelling behavior of co-polymer was studied in buffer solutions with different pH values (pH=5.8, pH=7.4) at $37^{\circ}C$. Magnetic iron oxide nanoparticles ($Fe_3O_4$) and doxorubicin were incorporated into copolymer and drug loading was studied. The release of drug, carried out at different pH and temperatures. Finally, chemical composition, magnetic properties and morphology of doxorubicin-loaded magnetic hydrogel nanocomposites were analyzed by FT- IR, vibrating sample magnetometry (VSM), scanning electron microscopy (SEM). Results: The results indicated that drug loading efficiency was increased by increasing the drug ratio to polymer. Doxorubicin was released more at $40^{\circ}C$ and in acidic pH compared to that $37^{\circ}C$ and basic pH. Conclusions: This study suggested that the poly (NIPAAm-MAA-VP) magnetic hydrogel nanocomposite could be an effective carrier for targeting drug delivery systems of anti-cancer drugs due to its temperature sensitive properties.

Studies on the Graft Polymerization of Polyethyleneglycol Monomethacrylate onto Chitosan and Drug(Vitamin B12) Permeation Behavior (키토산과 폴리에틸렌글리콜 모노메타크릴레이트의 그라프트중합과 약물(Vitamin B12)방출에 관한 연구)

  • Chung, Joo-Eun;Chung, Byung-Ok;Chang, Byung-Kwon;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.524-536
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    • 1994
  • Chitosan is known to be a good biocompatible natural polymer. Polyethyleneglycol monomethacrylates(PEGM) were grafted onto chitosan and their reaction conditions and properties of the graft polymers obtained were estimated. Using ceric ammonium nitrate(CAN) as the initiator, the optimum condition for graft polymerization was determined amount of the initiator and monomer concentrations and reaction time. Grafting yields such as total conversion, the percentage of grafting and the efficiency of grafting were calculated and examined the optimum reaction condition for high grafting yields. The percentage of grafting and total conversion were maximum at condition that the concentration of initiator was $4{\sim}5{\times}10^{-3}M$, the concentration of monomer was 0.5~0.6M, the reaction time was 2~3 hours and the reaction temperature was about $40^{\circ}C$. Thermal characteristics, solubility for chitosan solvents and inherent viscosity of synthesized graft copolymers were investigated. In high initiator concentration, characteristics of chitosan were greatly diminshed. In case of inherent viscosities, chitosan-g-PE-90 was 2.81 dl/g, chitosan-g-PE-200, 3.01dl/g and chitosan-g-PE-350, 4.93dl/g. And a tendency of viscosity increase depending on the length of ethylene oxide residue was confirmed. Degree of swelling, tensile strength, elongation of membrane prepared from graft copolymers were determined. Properties of graft copolymers were affected by percentage of grafting and length of ethylene oxides residue in polyethylene glycol monomethacrylates. Tensile strength, elongation and degree of swelling of graft copolymers were remarkably improved than chitosan. As percentage of grafting increased, the amount of drug permeation was also increased.

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