• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2099-2104
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• 2013

We present here an efficient and simple method for preparation of highly active Pd heterogeneous catalyst (CNT-Pd), specifically by reaction of dichlorobis(triphenylphosphine)palladium ($Pd(PPh_3)_2Cl_2$) with thiolated carbon nanotubes (CNTs). The as-prepared CNT-Pd catalysts demonstrated an excellent catalytic activity for the carbon-carbon (C-C) cross-coupling reactions (i.e. Suzuki, Stille, and decarboxylative coupling reactions) under mild conditions. The CNT-Pd catalyst could easily be removed from the reaction mixture; additionally, in the decarboxylative coupling of iodobenzene and phenylpropiolic acid, it showed a six-times recyclability, with no loss of activity. Moreover, once its activity had decreased by repeated recycling, it could easily be reactivated by the addition of phosphine ligands. The remarkable recyclability of the decarboxylative coupling reaction is attributable to the high degree of dispersion of Pd catalysts in CNTs. Aggregation of the Pd catalysts is inhibited by their strong adhesion to the thiolated CNTs during the chemical reactions, thereby permitting their recycling.

• Advances in materials Research
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• 제7권1호
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• pp.73-81
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• 2018

$TiO_2/CH_3NH_3Pb_{1-x}Sb_xI_{3-3x}Br_{3x}-based$ photovoltaic devices were fabricated by a spin-coating method using mixture solutions with $SbBr_3$. Effects of $SbBr3$, CsI or RbBr addition to $CH_3NH_3PbI_3$ precursor solutions on the photovoltaic properties where investigated. The short-circuit current densities and photoconversion efficiencies were improved by adding a small amount of $SbBr_3$, CsI or RbBr to the perovskite phase, which would be due to the doping effect of Sb, Br and Cs/Rb atom at the Pb, I and $CH_3NH3$ sites, respectively.

• Asian-Australasian Journal of Animal Sciences
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• 제1권1호
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• pp.47-53
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• 1988

Daily milk yield estimates were obtained on 74 lactations of 35 Japanese Black cows on weeks 1 to 9, 11, 13, 17, 21 and 26 postpartum using the weigh-suckle-weigh method. The data obtained were analyzed by least-squares procedures according to the models including the following effects; dam, lactation number, season of calving, week of experiment and partial regressions on the lactation number. The overall mean and standard error for daily milk yield was $4.55{\pm}0.04\;kg$. The milk yield declined essentially linearly throughout the experimental period. The main effects of lactation number, season of calving and week of experiment were highly significant. Differences in daily milk yield among cows were significant, and the repeatability was estimated as $0.60{\pm}0.06$. The overall means(kg) and repeat-abilities of cumulative milk yield for 1, 4, 9, 13, 17, 21 and 26 weeks postpartum were 41, 0.08; 166, 0.40; 361, 0.61; 503, 0.66; 632, 0.67; 749, 0.65 and 884, 0.58; respectively. The means of calf weight at birth and 26 weeks weight for different lactations ranged from 25.5 to 33.6 kg and 145.6 to 185.4 kg, respectively. Calf daily gains between experiment weeks were low in earlier stages of lactation.

• Applied Microscopy
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• 제46권2호
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• pp.105-109
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• 2016

Palladium has been used as a catalyst not only in Suzuki and Heck cross coupling reaction in organic chemistry, but also in automobile industry for the reduction of vehicle exhausts. The catalytic activity of Pd nanoparticles depends strongly on their size and exposed crystalline facets. In this study, the single crystalline palladium nanocubes/nanorods were prepared in the presence of polyvinyl pyrrolidone (PVP) and potassium bromide (KBr) using the polyol method. Selected area diffraction pattern and high-resolution transmission electron microscopy (TEM) were performed by TEM. The result shows that the ratio of KBr/PVP is the key factor to determine whether the product is cubes or rods. The as-prepared Pd nanocubes were highly uniform in both size and shape. The ordered packing structures including monolayer and multilayer can be fabricated via the rate-controlled evaporation of solution solvent. The catalytic activity of these Pd nanocubes towards heck reaction of iodobenzene with acrylate or acrylic acid was found to be higher than that of Pd nanorods. We suspect it is caused by the difference of energy state while Pd nanocubes is {100} plane and nanorods is {111} plane.

• 지구물리와물리탐사
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• 제7권1호
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• pp.7-13
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• 2004

In this paper, we demonstrate that Common Mid-Point (CMP) cross-correlation gathers of multi-channel and multi-shot surface waves give accurate phase-velocity curves, and enable us to reconstruct two-dimensional (2D) velocity structures with high resolution. Data acquisition for CMP cross-correlation analysis is similar to acquisition for a 2D seismic reflection survey. Data processing seems similar to Common Depth-Point (CDP) analysis of 2D seismic reflection survey data, but differs in that the cross-correlation of the original waveform is calculated before making CMP gathers. Data processing in CMP cross-correlation analysis consists of the following four steps: First, cross-correlations are calculated for every pair of traces in each shot gather. Second, correlation traces having a common mid-point are gathered, and those traces that have equal spacing are stacked in the time domain. The resultant cross-correlation gathers resemble shot gathers and are referred to as CMP cross-correlation gathers. Third, a multi-channel analysis is applied to the CMP cross-correlation gathers for calculating phase velocities of surface waves. Finally, a 2D S-wave velocity profile is reconstructed through non-linear least squares inversion. Analyses of waveform data from numerical modelling and field observations indicate that the new method could greatly improve the accuracy and resolution of subsurface S-velocity structure, compared with conventional surface-wave methods.

• 동력기계공학회지
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• 제17권5호
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• pp.100-111
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• 2013

Indoor real-time positioning for multiple targets is required to realize human-robot symbiosis. This study firstly presents positioning accuracy on an autonomous mobile robot controlled by 3-D coordinates that is obtained by a real-time indoor positioning system with spread spectrum (SS) ultrasonic signals communicated by code-division multiple access. Although many positioning systems have been investigated, the positioning system with the SS ultrasonic signals can measure identified multiple 3-D positions in every 70 ms with noise tolerance and error within 100 mm. This system is also robust to occlusion and environmental changes. However, thus far, the positioning errors in an autonomous mobile robot, controlled by these systems using the SS ultrasonic signals, have not been evaluated as an experimental study. Therefore, a positioning experiment for trajectory control is conducted using an autonomous mobile robot and our positioning system. The effectiveness of this positioning method for robot self-localization is shown, from this experiment, because the average control error between the target position and the robot's position at 29 mm is obtained.

• Communications for Statistical Applications and Methods
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• 제24권6호
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• pp.605-625
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• 2017

This paper presents proportional odds cure models to allow spatial correlations by including spatial frailty in the interval censored data setting. Parametric cure rate models with independent and dependent spatial frailties are proposed and compared. Our approach enables different underlying activation mechanisms that lead to the event of interest; in addition, the number of competing causes which may be responsible for the occurrence of the event of interest follows a Geometric distribution. Markov chain Monte Carlo method is used in a Bayesian framework for inferential purposes. For model comparison some Bayesian criteria were used. An influence diagnostic analysis was conducted to detect possible influential or extreme observations that may cause distortions on the results of the analysis. Finally, the proposed models are applied for the analysis of a real data set on smoking cessation. The results of the application show that the parametric cure model with frailties under the first activation scheme has better findings.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.294-297
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• 2009

We computationally investigated the effects of oxygen and alkaline-earth on the emission wavelength of the $Eu^{2+}$-doped oxide phosphor. Using QSPR method, we found that the oxygen and alkaline-earth atom around the Eu atom increase and decrease the emission wavelength, respectively. We also investigated the $Eu^{2+}$-doped sulfide, nitride, and oxynitride phosphors.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2000년도 ITC-CSCC -2
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• pp.727-730
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• 2000

Recently, RoboCup soccer simulation has been regarded as a good benchmark problem for multiagent researches. Soccer agents have to make decision based on visual and auditory information, which are sent from the soccer server. In order to develop a strong team, we have to design decision-making process of each player agent. However, it is very difficult for us to design the decision-making processes in detail, because we don't know what actions of each player are effective for the team. In this paper, we attempt to apply co-evolutionary method, which is one type of analogies of evolution, to improve the team play. Agents have hand coded basic skills, which include dribble, shoot, pass etc. Agents already can play autonomously and independently. Individual agent skills are characterized by some parameters. By coevolving teams with these parameters, we obtained relatively interesting teams, in which players behave cooperatively in order to win the soccer game. From some experiments, we discuss what teams are evolved.

• 한국산림과학회지
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• 제76권4호
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• pp.390-396
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• 1987

지역삼림계획에 있어서 목재생산을 예측하는 모델을 작성하고 그 계산예를 제시하였다. 목재생산예측의 방법으로서 감은율법(減殷率法)이 이용되고 있다. 령목(鈴木)는 감마분포에 의해서 삼림의 수명을 결정하지만 본 예측 모델에서는 현재 삼림의 수명분포로서 적당하다고 생각되는 와이블분포나 감마분포 중 어느쪽을 사용해서라도 목재생산을 예측할 수 있도록 시스템화 하였다. 본 시스템을 분기별 수확량, 축적량, 노동량 등의 경영정보를 제공하게 되며 지역삼림계획 책정에 있어 유효한 수단으로 이용될 수 있을 것이다.