• 한국물환경학회지
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• 제29권4호
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• pp.540-550
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• 2013

Temporal increase of SS induces concentrations in various forms of organic matter including BOD, COD, TOC. Consequently, it causes hard to identify sources of water pollution during or after precipitation. The objective of this study is to investigate variations of DOC concentration caused by increase of flow and changes of external factors in river by comparing to SS concentration. In results, monitoring sites (e.g., Banbyeonchen) consisting of hard riverbed showed high correlation between SS and organic matters, except BOD. On the contrary, other sites (e.g., Naesungcheon) where riverbed consists of sand were found in a wide range of annual fluctuation in SS level, whereas these sites showed a narrow range in annual DOC fluctuation. In Gumhogang and Namgang, a lower correlation between SS and other factors was found most likely because of high concentration in organic matter. However, lower annual fluctuation values of DOC were observed in comparison to those of COD and TOC. Similar results were also confirmed in main river sites, Sangju and Mulgeum. In conclusion, DOC concentration is better indicator for monitoring organic matter which cannot be provided by BOD, COD, TOC in the Nakdong river basin.

• 한국물환경학회지
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• 제32권1호
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• pp.98-107
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• 2016

This study examined the effects of environmental conditions and the presence of refractory organic matter on oxidation rates of total organic carbon (TOC) measurements based on high temperature combustion and ultraviolet-sulfate methods. Spectroscopic indices for prediction of oxidation rates were also explored using the UV spectra and fluorescence excitation-emission matrix (EEM) of humic acids. Furthermore, optimum TOC instrument conditions were suggested by comparing oxidation rates of a standard TOC material under various conditions. Environmental conditions included salts, reduced ions, and suspended solids. Salts had the greatest influence on oxidation rates in the UV-sulfate method. However, no effect was detected in the high temperature combustion method. The UV-sulfate method showed lower humic substance oxidation rates, refractory natural organic matter, compared to the other methods. TOC oxidation rates for the UV-sulfate method were negatively correlated with higher specific-UV absorbance, humification index, and humic-like EEM peak intensities, suggesting that these spectroscopic indices could be used to predict TOC oxidation rates. TOC signals from instruments using the UV-sulfate method increased with increasing chamber temperature and increasing UV exposure durations. Signals were more sensitive to the former condition, suggesting that chamber temperature is important for improving the TOC oxidation rates of refractory organic matter.

• Journal of the korean society of oceanography
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• 제33권4호
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• pp.157-167
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• 1998

The distribution of particulate organic carbon and nitrogen (POC and PON) and chlorophyll a of particulate organic matter was investigated in the southwestern East Sea in August and October 1995. The upwelled 'cold water mass' with temperature less than 14$^{\circ}$C occurred near the Campo coast in August. At most of the onshore stations, concentrations of POC and PON were high in surface water, rapidly decreased with depth down to 30 m and then remained constant. Differences in their concentrations between surface and bottom waters were larger in August than in October. At the offshore stations, POC and PON were higher in surface than in deep waters though the differences in concentration were small. The highest, vertically integrated inventories of POC, PON and phytoplanktonic carbon in the upper mixed waters of the onshore stations occurred in August. The mixed layers at onshore stations showed relatively high percentages of POC, PON and chlorophyll a in total suspended matter, low ratios of POC to chlorophyll a and high inventories of phytoplanktonic carbon, compared with the values at offshore stations. These phenomena were more obvious in August, when cold water mass developed strongly, than in October. These results indicate that primary production plays a significant role for the budget of particulate organic matter in the upwelled cold water mass of the southwestern East Sea.

• Journal of the korean society of oceanography
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• 제39권1호
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• pp.57-71
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• 2004

Based on the data obtained under the China-Korea joint project (1997-2001) and historic observations, the distribution, transportation and sedimentation of sediment in the southern Yellow Sea (SYS) are discussed, and the controversial formation mechanism of muddy sediments is also explored. The sediment transport trend analysis indicates that the net transport direction of sediment in the central SYS (a fine-grained sediment deposited area) points to $123.4^{\circ}E,\;35.1^{\circ}N$, which is a possible sedimentation center in the central SYS. The sediment transport pattern is verified by the distribution of total suspended matter (TSM) concentration and ${\delta}^{13}C$ values of particulate organic carbon (POC), the latter indicates that the bottom water plays a more important role than the surface water in transporting the terrigenous material to the central deep-water area of the SYS, and the Yellow Sea circulation is an important control factor for the sediment transport pattern in the SYS. The carbon isotope signals of organic matter in sediments indicate that the Shandong subaqueous delta has high sedimentation rate and the deposited sediments originate mainly from the modern Yellow River. The terrigenous sediments in deep-water area of the SYS originate mainly from the old Yellow River and the modern Yellow River, and only a small portion originates from the modern Yangtze River. The analytical results of TSM and stable carbon isotopes are further confirmed by another independent tracer of sediment source, polycyclic aromatic hydrocarbons (PAHs). Five light mineral provinces in the SYS can be identified and they indicate inhomogeneity in sources and sedimentary environment. The modern shelf sedimentary processes in the SYS are controlled by shelf dynamic factors. The muddy depositional systems are produced in the shelf low-energy environments, which are controlled by some meso-scale cyclonic eddies (cold eddies) in the central SYS and the area southwest of the Cheju Island. On the contrary, an anticyclonic muddy depositional system (warm eddy sediment) appears in the southeast of the SYS (the area northwest of the Cheju Island). In this study, we give the cyclonic and anticyclonic eddy sedimentation patterns.

• 대한원격탐사학회지
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• 제31권5호
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• pp.473-490
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• 2015

우리나라 주변을 한 시간 간격으로 관측하고 있는 GOCI의 관측영역 안에는 매우 맑은 대양의 성격을 띠는 동해부터 세계적인 큰 강인 양쯔강 하구의 극심하게 탁한 해역까지 매우 폭 넓은 해수 환경이 포함되어 있다. 따라서 본 연구에서는 대표적인 해수 구성 성분인 식물 플랑크톤, 부유물질, 용존유기물질의 흡광 특성자료를 이용하여 각 해역별 해수 환경의 차이를 상세하게 분석하였다. 이를 위하여 2009 ~ 2014년까지 6년 동안 한반도 주변 해역의 총 959개 정점에서 얻어진 해양 광학 자료 및 해양 환경 자료가 사용되었다. 그 결과 동해, 남해, 동중국해, 황해 외해역은 DOM과 식물 플랑크톤의 기여도가 높은 비슷한 분포 패턴을 나타냈고, 이와는 달리 목포 및 경기만 연안 해역은 부유물질과 용존유기물질의 기여도가 높은 분포 패턴을 보였다. 클로로필 및 부유물질 알고리즘의 정확도를 검증해 본 결과, 클로로필은 주로 과대 추정되고, 부유물질은 주로 과소 추정되는 경향을 보였다. 큰 오차의 경우 클로로필, 부유물질, 용존유기물질 중에서 부유물질에 의해 가장 많은 영향을 받았으며, $a_{SPM}$의 기여도가 60% 이상으로 높을 때 연안 해역에서 나타났다.

• 한국대기환경학회지
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• 제15권4호
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• pp.495-503
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• 1999

Airborne particulate matter $(PM_{10})$ collected using high volume air sampler and silica fiber filter were analyzed by Instrumental Neutron Activation Analysis(INAA), Inductively Coupled Plasma Atomic Emission Spectrometry(ICP-AES) and Atomic Absorption Spectrometry(AAS), and the results were compared with each other. 30~40 trace elements in environmental standard reference materials(NIST SRM 1648 and NIES CRM No.8) were analyzed for the analytical quality control. The relative error for two-third of elements detected was less than 10%, and the standard deviation was less than 15%. During the sampling period for 24 hours, the mass concentration of total suspended particulate was 36.1$\mu\textrm{g}$/㎥ and the value is lower than the critical level in Korea. In the results of NAA, the elements of Al, As, Ba, Fe, La, Mg, Na, Sb, Zn were well agreed with those of other methods. In statistical estimation between different methods, the deviation of Al, Ba, Cr, Fe was less than 10% and quite reliable.

• 상하수도학회지
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• 제26권1호
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• pp.47-54
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• 2012

This study analyzed influence factors and the correlation among pollutants which affect occurrence of leaked pollution based on the long-term runoff flow and water quality investigation results to understand the characteristics of highway rainfall runoff pollution load. According to the result of correlation analysis on TSS (Total Suspended Solid) concentration, anteceded dry days, rainfall intensity, traffic volume and etc. as major influence factors of highway rainfall runoff pollution loads, the correlations were weak or scarce in most items. These results might be attributed that runoff pollutant concentration changes vary severely on changes of rainfall intensity and rainfall duration within rainfall and it is affected by disturbances of vehicles and street cleaning and etc. as characteristics of the highway. While Cu, Fe and Zn which are discharged with high concentrations out of heavy metals showed high correlation with particulate matter, organic matter(COD), nutrient(TN, TP), Ni and Pb showed relatively low correlation in a correlation evaluation by pollutant. Significant correlation with traffic volumes was not shown and TSS concentration even decreased in accordance with increase of the traffic volume. In the comparison with precedent studies, it was considered necessary additional analysis of the effects of rainfall section analysis, road type, disturbances of surface contaminants by vehicles, rainfall and climate conditions, surrounding terrains etc.

• Asian-Australasian Journal of Animal Sciences
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• 제13권3호
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• pp.317-322
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• 2000

In situ and in vivo digestion trials were conducted to determine the degradation of dry matter (DM), crude protein (CP) and effective protein degtadability (EPD), and digestibility of nutrients of Hazelnut kernel oil meal (HKOM), and effects of HKOM on nitrogen (N) balance. In the in situ study, nylon bag were suspended in the rumen of 3 Karayaka rams to estimate protected protein. Protein sources were analyzed for pepsin soluble protein (PSP) using a Pepsin Digestion Method. In the digestion trials, 4 Karayaka rams (36 mo.) were used in a $4{\times}4$ Latin square to evaluate the digestibility of nutrients and N retention to measure effects of diets containing HKOM, soybean meal (SBM) corn gluten meal (CGM) and urea (U). The degradability of DM and CP, and PSP content of HKOM were lower (p>0.05) than that of SBM, but higher (p<0.001) than that of CGM. EPD of HKOM was higher (p<0.01) than that of SBM or CGM. The apparent digestion coefficients of organic matter and CP for HKOM were lower than for SBM, but higher than for CGM. N retention of HKOM was higher than that of SBM and lower than that of CGM (p>0.05). In conclusion, these data may indicate that the HKOM is a high digestible feed source with a value between SBM and CGM.

• 한국연초학회지
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• 제20권1호
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• pp.124-130
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• 1998

This study was conducted to evaluate the ability of anion generating air cleaner to remove gases, vapor and particles from closed room contaminated with environmental tobacco smoke (ETS). The measurements covered particle sizes of 13.8-542.5nm, particle concentration, surface area, volumes UVPM, FPM, solanesol, and the following gases and vapor; carbon dioxide, carbon monoxide, nicotine, and 3-ethenylpyridine. Tobacco smoke was generated and mixed in a closed room in which the airflow rates were in the range of 0.00-0.04 m/s. The anion generating air cleaner was startedl and the decay rates for the gases, vapor and particles were measured, When the use of anion generating air cleaner, solid components of ETS, such as respirable suspended particle (RSP), utraviolet particulate matter (UVPM, fluorescent particulate matter (FPM) and solanesol was sharply decreased, and vapor phase components of ETS, such as nicotines 3-ethenylpyidine were modelately decreased by time elapse. Even the use of anion generation air cleaner, the decreasing rate of carbon dioxide concentration was similar with control, and the decreasing rate of carbon monoxide was slower than that of control. Our results indicated that the use of anion generting air cleaner had an effect on reduction of solid and vapor components from ETs, but it had no effect on gaseous components of ETS.

• Asian Journal of Atmospheric Environment
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• 제9권3호
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• pp.205-213
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• 2015

The objective of the current study was to assess the comparative risk associated with exposure to particulate matter (PM) while commuting via different public transport modes in Fukuoka, Japan. For the given routes and measuring days, a trip-maker carried a lightweight portable bag loaded the real-time measurement devices which take simultaneous measurement for size-fractioned particle number concentration, $PM_{2.5}$ mass concentration, and total suspended particle (TSP) collection. The results of the present study have shown significant differences between public transports as commuting modes in Fukuoka. The PM exposure levels on subway platform and inside subway train were overwhelmingly higher than those of other points on commuting route. The relative ratio between modes (i.e., the ratio of $PM_{2.5}$ inside subway to that inside bus) provides an idea for choosing a right commuting mode for our health. This study clearly provided evidence of the extremely high levels of iron exposure by subway uses compared to bus uses. The result of theoretically reconstructed mass concentration of $PM_{2.0-0.3}$ collected on subway platform suggests that the PM of underground subway will be associated with PM both generated in subway system and inleakaged from outdoor environment.