• Title/Summary/Keyword: Surfactant solution

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DNAPL removal from a rough-welled single fracture with Density-surfactant-motivated method

  • Lee Hang-Bok;Ji Seong-Hun;Yeo In-Uk;Lee Gang-Geun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.215-218
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    • 2005
  • We applied the density-surfactant-motivated method to the removal of DNAPL within a rough-walled single fracture. Observations are made to compare the DNAPL residual distribution before and after the flushing of surfactant-enhanced solution or water flushing. Results show that density-motivated method with surfactant-enhanced solution effectively removed DNAPL in a single fracture.

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Growth of Ice Crystal with Concentration of Surfactant in Water Solution (계면활성제 농도가 빙결정의 입자크기에 미치는 영향)

  • ;稻葉英男
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.2
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    • pp.240-247
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    • 2002
  • Recently, a thermal energy storage system has been developed actively fur the purpose of saving energy and reducing the peak electrical demand. Especially, ice slurry is a promising working fluid for low temperature energy storage systems. A flow of ice crystals has a large cooling capacity as a result of the involvement of latent heat. However, there are still problems related to the recrystallization of ice crystals for realizing long term storage and long distance transportation. To find improvements fur this, a method for the creation of ice crystals resistant to recrystallization has been proposed and researched by the use of an antifreeze protein (AFP) solution etc. In the present study, it has been investigated the growth of ice crystal in several kinds of water solution added non-ionic surfactant. The results shows that size of ice crystal was smaller with increasing in added surfactant. And ice crystal was not increased with added surfactant.

Study on Ice Making Behavior of Water Solution with Surfactant (계면활성제 첨가수용액의 제빙에 관한 기초연구)

  • ;Hideo Inaba;Akihiko horibe
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1175-1183
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    • 2001
  • Recently, a great attention has been paid to the ice thermal storage system for the purpose of energy saving and reduction in peak electrical demand. In the present study, it has been investigated the freezing behavior of several kinds of water solutions with nonionic surfactant. In order to prevent ice blockage in a cooled pipe, the amount and wall adhesion behavior of ice of the test fluids were observed experimentally under different concentration of water solution with surfactant, temperature of cooled wall, and the shear velocity of test fluids. The results showed that the size of ice crystal became smaller at higher shear velocity at wall. And the lowest limit of wall adhesion of ice in water solution with surfactant was found at 230 W/$m^2$ of heat flux.

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Fluid and Heat Transfer Characterization of Surfactant Turbulent Pipe Flows (계면활성제가 첨가된 관내 난류의 열유동 특성에 관한 고찰)

  • Shin, Kwang-Ho;Yoon, Hyung-Kee;Chang, Ki-Chang;Ra, Ho-Sang
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.982-987
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    • 2006
  • The fluid mechanics and heat transfer of surfactant turbulent pipe flows are characterized with particular emphasis on the effects of surfactant concentration and solution temperature on drag reduction and heat transfer reduction. The test fluids are the surfactant solutions of DR-IW616 supplied by Akzo Nobel Chemical in concentration of $100{\sim}3000ppm$. The solution temperatures studied are $5^{\circ}C$ to $50^{\circ}C$. The critical values of surfactant concentration and solution temperature are clearly identified for drag reduction phenomena.

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Rheological Behaviour of Surfactant Mixtures by Varying the Concentration of Polyols (폴리올 농도를 변화시킨 계면활성제 혼합물의 유변학적 거동)

  • Cho, Wan-Goo;Kim, Gee-Sun
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.422-427
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    • 2009
  • We have investigated the effects of polyols and NaCl on the rheological behaviours of surfactant mixtures. Sodium lauryl ether sulfate (SLES), cocamidopropyl betaine (CAPB), disodium cocoamphodiacetate (DSCA), cocamide DEA (CDEA) and lauroyl/myristoyl DEA (LMDE) were used as surfactants. The polyols added into the surfactant mixture were 1,3-butylene glycol, propylene glycol, glycerin, sorbitol, dipropylene glycol, PEG 1500 and PEG 400. The addition of amphoteric surfactant to SLES aqueous solution lead to increase the height of foam and the viscosity of the system. The addition of nonionic surfactant, LMDE or CDEA to the SLES aqueous solution increased the viscosity and the effect of LMDE was better than that of CDEA. The effect of adding polyols and NaCl into the surfactant mixture aqueous solution lead to increase or decrease the viscosity of the systems depending on the concentration of NaCl and the kinds of polyols. These results can be explained through the salting in or salting out of surfactant of the systems.

Optimization of DOSL Surfactant Solution Conditions in Surfactant-Enhanced Remediation of Soil Contaminated by Toluene (톨루엔으로 오염된 토양에서 DOSL 계면활성제를 이용한 최적의 정화 조건 규명)

  • ;;Robert D. Cody
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.23-30
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    • 2001
  • Column tests were carried out to examine the effect of surfactant solution conditions on the surfactant-enhanced remediation of soil columns contaminated by toluene. The conditioned parameters of the surfactant solution for the column tests were concentration, pH, temperature and flow rate. The test results revealed that an optimum condition was achieved for 4% (v/v) of concentration, 10 of pH, $20^{\circ}C$ of temperature and 4 mL/min of flow rate respectively. The removal of 95% of toluene was obtained when optimal conditions of each surfactant solution parameter were simultaneously met. This was a marked improvement and removal efficiency increased by 6-19% compared to that with unadjusted conditions. The optimum range of these parameters may be useful for a surfactant-based remediation in the aquifer contaminated by toluene.

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Effects of Mixed Characteristics of Oily Soil on Detergency of PET Fabric in Oily/Particulate Soil Mixed System (지용성/고형오구의 혼합오염계에서 지용성오구의 혼합특성에 따른 PET직물의 세척성)

  • Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.10
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    • pp.1242-1251
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    • 2011
  • This study investigates the effect of mixed characteristics of oily soil such as mixed ratio, polarity of oily soil on contact angle of fabric, removal of oily and particulate soil from PET fabric in oily/particulate soil mixed system. The contact angle of fabric in the surfactant solution with suspended oily soil was examined as a fundamental environment of detergency of soil from fabrics. Detergency was investigated as function of mixed ratios of oily/ particulate soil, type of oily soil, surfactants concentration, surfactant type and temperature of detergency in surfactant solution. The contact angle of fabric in surfactant solution sharply increased with mixing nonpolar oily soil; in addition, the contact angle slightly increased with increasing contents of oily soil and decreased with increasing surfactant concentration. The removal of oily and particulate soil from fabric was higher in the solution mixed with polar versus nonpolar oily soil. The detergency increased with increasing surfactant concentration and the increased temperature of surfactants solution that were relatively improved in NPE compared to DBS solutions, The results indicated that the detergency of oily and particulate soil showed a similar trend in oily/ particulate mixed soil systems. The general contact angle of fabric was well related with the detergency of oily and particulate soil in oily/particulate mixed soil system, therefore, the primary factor determining the detergency of soil in oily/particulate mixed soil system may be the contact angle of fabric caused by wettability.

The Effect of Particle Size on the Detergency of Particulate Soil (고형오구 입자크기가 고형오구의 세척성에 미치는 영향)

  • Mun, Mi-Hwa;Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.4
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    • pp.653-662
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    • 2010
  • This study investigates the effect of particle size on the detergency of particulate soil using an $\alpha-Fe_2O_3$ particle as the model. Monodispersed spherical $\alpha-Fe_2O_3$ particles were prepared by the hydrothermal aging of an acidic $FeCl_3$ and HCl solution. The $\xi$-potential of PET fiber was measured by the streaming potential method. The potential energy of interaction between the particle and fiber was calculated using the heterocoagulation theory for a sphere-plate model. The $\xi$-potential of PET fiber and potential energy of interaction between particles and fiber increased with a decreasing particle size in a DBS solution. However, in the nonionic surfactant solution, the $\xi$-potential signs of PET fiber and $\alpha-Fe_2O_3$ particles were (-) and (+), respectively; there was no repulsive power between the particles and substrate. The adhesion of particles to the fabric increased with increasing particle size in the anionic surfactant solution and their removal from the fabric increased with a decreasing particle size. The adhesion of particles to the fabric and their removal from the fabric was biphasic with a maximum and minimum at 0.1% concentration of the surfactant solution. In the nonionic surfactant solution the adhesion of particles to fabric and their removal from the fabric were greater than the ones in the anionic surfactant DBS solution.

Preparation and Characterization of Mesoporous Ni Film Made by Electroplating Method (전착법을 이용한 메조포러스 니켈 필름의 제조와 특성 분석)

  • Lee, Ji-Hoon;Baik, Young-Nam;Kim, Young-Seok;Shin, Seung-Han
    • Journal of the Korean institute of surface engineering
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    • v.40 no.1
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    • pp.16-22
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    • 2007
  • Recently, mesoporous metallic materials are becoming more and more important in various applications like catalysts, electrochemical detectors, batteries, and fuel cells because of their high surface area. Among the various methods for manufacturing mesoporous structure, surfactant templating method followed by electroplating has been tried in this study. A mesoporous metallic film was prepared by electrodeposition from electroplating solution mixed with surfactant template. Nonionic type lyotropic liquid crystalline surfactant, Brij56, and nickel acetate based solution were selected as a template material and electroplating solution, respectively. To determine the content of surfactant forming a hexagonal column structure, the phase diagram of electroplating solution and surfactant mixture has been exploited by polarized optical microscopy equipped with heating and cooling stage. Nickel films were electroplated on Cu foil by stepwise potential input method to alleviate the concentration polarization occurred during the electroplating process. TEM and XRD analyses were performed to characterize the size and shape of mesostructures in manufactured nickel films, and electrochemical characterization was also carried out using cyclic voltammetry.

Effect of Surfactant Concentration and pH on Surfactant-Enhanced Remediation in lowa Soil Contaminated by TCB (삼염화벤젠으로 오염된 아이오와토양의 복원시 계면활성제의 농도와 pH의 영향)

  • Dal-Heui Lee;Robert D. Cody
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.149-154
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    • 2002
  • Column tests were carried out to examine the effect of surfactant solution conditions on surfactant-enhanced remediation of contaminated soil. The selected conditions of the surfactant solution were concentration and pH. 1,2,4-trichlo-robenzene (TCB) was chosen as the model hydrophobic organic substances. Sodium diphenyl oxide disulfonate (DOSL) and octylphenoxypoly ethoxyethanol (OPEE) surfactants were selected for this study. Two Iowa soils, Fruitfield sand and Webster clay loam, were leached with surfactant solution. The test results revealed that an optimum condition was achieved for 4 %(v/v) of concentration and 10 of pH, respectively. The maximum recoveries of added TCB (93-98%) were obtained when optimal conditions of each surfactant solution parameter were simultaneously met. The optimum conditions of these parameters may be useful for surfactant-assisted remediation in soil contaminated by TCB.