• Title/Summary/Keyword: Surfactant modification

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Modification of Cotton Treated with Cellulase( I ) ―Effect of Treating Condition on the Weight Loss― (셀룰라아제 처리에 의한 면의 개질( I ) ―감량률에 미치는 처리조건의 영향―)

  • Hong, Ki Jeong;Lee, Mun Cheul;Bae, So Yeung;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.10-19
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    • 1993
  • Broad, mercerized broad, mercerized twill cotton fabrics and rayon fabric were treated with cellulase for 30~480 minutes at different temperature, concentration, time, and also treating methods such as continuously-treated or repeatedly-treated, and dyed with two direct dyes before or after enzyme treatment. From the experimental result by treating under the various conditions above, it was obtained that the weight loss increased more in thin fabric than thick one. In addition, it was considered that the treatment in 5$0^{\circ}C$ for 240 minutes brought about the ideal weight loss and flexible hand of the specimens. For both broad and mercerized broad, repeated treatment showed more weight loss than continuous. Direct dye on cotton fabric apparently inhibited hydrolysis. Ionic surfactants showed the inhibition effect of the catalytic hydrolysis of enzyme, on the other hand, nonionic surfactant did not.

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Effects of Mixed Oxidizer on the W-CMP Characteristics (혼합 산화제가 W-CMP 특성에 미치는 영향)

  • 박창준;서용진;김상용;이우선
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1181-1186
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    • 2003
  • Chemical Mechanical Polishing (CMP) is an essential dielectric planarization in multilayer microelectronic device fabrication. In the CMP process, it is necessary to minimize the extent of surface defect formation while maintaining good planarity and optimal material removal rates. The polishing mechanism of W-CMP process has been reported as the repeated process of passive layer formation by oxidizer and abrasion action by slurry abrasives. Thus, it is important to understand the effect of oxidizer on W passivation layer, in order to obtain higher removal rate (RR) and very low non-uniformity (NU %) during W-CMP process. In this paper, we compared the effects of oxidizer or W-CMP process with three different kind of oxidizers with 5 wt% hydrogen peroxide such as Fe(NO$_3$)$_3$, H$_2$O$_2$, and KIO$_3$. The difference in removal rate and roughness of W in stable and unstable slurries are believed to caused by modification in the mechanical behavior of Al$_2$O$_3$ particles in presence of surfactant stabilizing the slurry.

HMDS Treatment of Ordered Mesoporous Silica Film for Low Dielectric Application (저유전물질로의 응용을 휘한 규칙성 메조포러스 실리카 박막에의 HMDS 처리)

  • Ha, Tae-Jung;Choi, Sun-Gyu;Yu, Byoung-Gon;Park, Hyung-Ho
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.48-53
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    • 2008
  • In order to reduce signal delay in ULSI, an intermetal material of low dielectric constant is required. Ordered mesoporous silica film is proper to intermetal dielectric due to its low dielectric constant and superior mechanical properties. The ordered mesoporous silica film prepared by TEOS (tetraethoxysilane) / MTES (methyltriethoxysilane) mixed silica precursor and Brij-76 surfactant was surface-modified by HMDS (hexamethyldisilazane) treatment to reduce its dielectric constant. HMDS can substitute $-Si(CH_3)_3$ groups for -OH groups on the surface of silica wall. In order to modify interior silica wall, HMDS was treated by two different processes except the conventional spin coating. One process is that film is dipped and stirred in HMDS/n-hexane solution, and the other process is that film is exposed to evaporated HMDS. Through the investigation with different HMDS treatment, it was concluded that surface modification in evaporated HMDS was more effective to modify interior silica wall of nano-sized pores.

Exhaust emissions of a diesel engine using ethanol-in-palm oil/diesel microemulsion-based biofuels

  • Charoensaeng, Ampira;Khaodhiar, Sutha;Sabatini, David A.;Arpornpong, Noulkamol
    • Environmental Engineering Research
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    • v.23 no.3
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    • pp.242-249
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    • 2018
  • The use of palm oil and diesel blended with ethanol, known as a microemulsion biofuel, is gaining attention as an attractive renewable fuel for engines that may serve as a replacement for fossil-based fuels. The microemulsion biofuels can be formulated from the mixture of palm oil and diesel as the oil phase; ethanol as the polar phase; methyl oleate as the surfactant; alkanols as the cosurfactants. This study investigates the influence of the three cosurfactants on fuel consumption and exhaust gas emissions in a direct-injection (DI) diesel engine. The microemulsion biofuels along with neat diesel fuel, palm oil-diesel blends, and biodiesel-diesel blends were tested in a DI diesel engine at two engine loads without engine modification. The formulated microemulsion biofuels increased fuel consumption and gradually reduced the nitrogen oxides ($NO_x$) emissions and exhaust gas temperature; however, there was no significant difference in their carbon monoxide (CO) emissions when compared to those of diesel. Varying the carbon chain length of the cosurfactant demonstrated that the octanol-microemulsion fuel emitted lower CO and $NO_x$ emissions than the butanol- and decanol-microemulsion fuels. Thus, the microemulsion biofuels demonstrated competitive advantages as potential fuels for diesel engines because they reduced exhaust emissions.

Comparison of Liquid-Liquid Extraction and Solid-Phase Extraction Coupled with GC/MS for Determination of Priority Pollutants in Water (액체 추출법과 고체상 추출법에 의한 수질 중 유해물질 농축법 비교)

  • Yook, Keun-Sung;Hong, Sa-Moon;Kim, Jong-Ho
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.441-453
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    • 1994
  • Two extraction methods, liquid-liquid extraction(LLE) and solid-phase extraction(SPE), coupled with GC/MS were compared as preconcentration procedures for priority pollutants in water. Among the semi-volatile priority pollutants, 11 acid and 44 base/neutral compounds were spiked in reagent water. With LLE, which is a modification of EPA Method 625, the overall mean recovery of the 54 compounds was 91% with a mean relative standard deviation(RSD) of 4.6%. With SPE, the overall mean recovery of the 52 compounds was 53% with a mean RSD of 8.9%. The detection limits of both methods were in the range of $1{\sim}5{\mu}g/l$.

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Wheat Quality and Its Effect on Bread Staling

  • Lee, Mee-Ryung;Lee, Won-Jae
    • Journal of agriculture & life science
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    • v.46 no.1
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    • pp.153-161
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    • 2012
  • Wheat is a very popular crop in all over the world due to the various use of wheat flour as staple foods, such as bread. As many food products are made from wheat, the property of wheat can be a determinant of the quality of final food products. Staled bread is not harmful to health but is normally rejected by consumers due to the absence of desirable sensory attributes. The phenomena of staling can be increased hardness of bread, the migration of moisture from center of bread to the crust of bread, loss of flavor and etc. The exact mechanism of staling has not been established completely. To delay or prevent staling, either addition of anti-staling agent, such as surfactant and enzyme or modification of wheat component, such as wheat starch has been adapted. The development of waxy wheat made it possible to reconstitute the starch component in bread. When the content of amylopect in was increased in bread, the loss of moisture was decreased and the reduction in softness of bread was decreased during storage. Increased retrogradation of starch did not always accompany the staling of bread indicating that the retrogradation of starch may not be a single indicator of bread staling. To find out the exact relationship between bread staling and starch retrogradation, further research is necessary.

Preparation of Porous Mullite-Corundum Ceramics Via Organic Foam Impregnation

  • Zhou, Xianzhi;Zhu, Shaofeng;Wang, Yuxi;Zhang, Tong
    • Korean Journal of Materials Research
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    • v.32 no.2
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    • pp.85-93
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    • 2022
  • Porous mullite-corundum ceramics were prepared using organic foam impregnation method with alumina and silica as raw materials. The influence of alkaline treatment and surfactant modification on polyurethane foam were studied. Effects of sintering process and material composition on porous mullite-corundum ceramics were investigated. The results show that the hang-pulp quantity of polyurethane foam increases with alkaline treatment. After treatment with 3 wt% SDS solution, the hang-pulp quantity of polyurethane foam further improved. Open porosity of sample decreased with elevation of sintering temperature and holding time, and compressive strength of sample showed a trend opposite to the change of porosity. The open porosity of the sample was enhanced by the increase of m(Al2O3/SiO2); the compressive strength decreased with increase of m(Al2O3/SiO2). However, when m(Al2O3/SiO2) was 2.5, the compressive strength of the sample reached 6.23 MPa, and the open porosity of the sample was 80.7 %.

Study on deodorizing polyethylene film made from waste shell powder (패각 폐자원을 재활용한 악취제거기능을 갖는 폴리에틸렌 필름에 대한 연구)

  • Chun Byoung Chul;Chung Yong-Chan;Chong Mi Hwa;Park Jung-Hwan;Kweon Oh-Cheul
    • Resources Recycling
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    • v.12 no.1
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    • pp.48-54
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    • 2003
  • Odor-removing polyethylene film utilizing waste shell powder (annual production: 250,000 ton) was prepared. Odor removal was designed to work by cation or cationic surfactant adsorbed onto the shell surface by ion-exchange: cationic surfactants (DTAB (n-dodecyltrimethylammonium bromide), CTAB (n-cetyltrimethylammonium bromide) and DHAB (n-dihexade-cyldimethylammonium bromide), and cations $Ce^{3+}$ , $Mg^{2+}$ and $Al^{3+}$) were used. Surface-modified waste shell powder was com-pounded with LDPE to produce 20 wt% shell masterbatch (MB), and the MB was again blended with LDPE to get shell-containing LDPE films with 3,5, 10 wt% of shell (width: 40 cm, thickness: 40 $\mu\textrm{m}$). Mechanical properties of the various shell-LDPE films maintained more than 80 % of that of pure LDPE film. Both shell film modified with cationic surfactant and one without shell surface-modification showed excellent odor-removing ability.

Injection moldable material utilizing shell waste and recycled polyethylene (貝角 廢棄物과 混合 廢플라스틱을 이용한 射出用 素材에 대한 硏究)

  • Chong, Mie-Hwa;Chung, Yong-Chan;Chun, Byoung-Chul;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.14 no.3
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    • pp.55-62
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    • 2005
  • Mechanical properties of shell powder containing mixed recycled plastics were investigated depending on the shell content and surface modification. First, shell powder and LDPE were compounded using the twin screw extruder to manufacture 40 wt% master batch(M/B), and the M/B was blended with LDPE to produce bulk specimens with 10, 20, 30 and 40 wt% shell content. To improve the compatibility of shell powder with mixed recycled plastics matrix, surface of shell powder was chemically modified with cations or cationic surfactant. Surface modified shell was also used to prepare bulk specimens with the same shell content. Mechanical property analysis showed obvious improvement for the surface modified shell containing bulk specimens compared to unmodified ones. These results can lead to the development of new applications for the mixed recycled plastics.

Preparation and Thermal Insulation Property of UV Curable Hybrid Coating Materials Based on Silica Aerogel (실리카 에어로겔을 이용한 자외선 경화형 복합 코팅 물질의 제조 및 단열 특성)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.141-148
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    • 2012
  • In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hydrophobic silica aerogel. The surface modification of silica aerogel was performed to obtain UV curable urethane acrylate hybrid coating sols with good compatibility by using surfactant(Brij 56). The polycarbonate substrates were coated by the prepared composites and cured under UV radiation. The incorporation of aerogel with only 10 vol% of content resulted in remarkable improvement by about 28% in the thermal insulation property of the coated film, as compared with substrate. In addition, increasing aerogel content was found to give minor effect on the variation of optical transparency, adhesion, and surface hardness of the coated film.