• 제목/요약/키워드: Surface-active agents

검색결과 58건 처리시간 0.025초

Impact of combined at-home bleaching and whitening toothpaste use on the surface and color of a composite resin

  • Carolina Meneghin Barbosa;Renata Siqueira Scatolin;Waldemir Francisco Vieira-Junior;Marcia Hiromi Tanaka;Laura Nobre Ferraz
    • Restorative Dentistry and Endodontics
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    • 제48권3호
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    • pp.26.1-26.12
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    • 2023
  • Objective: This in vitro study aimed to evaluate the effects of different whitening toothpastes on a composite resin during at-home bleaching with 10% carbamide peroxide. Materials and Methods: Sixty samples (7 mm × 2 mm) were used for color and roughness analyses, while another 60 samples (3 mm × 2 mm) were utilized to assess microhardness. The factors analyzed included toothpaste, for which 5 options with varying active agents were tested (distilled water; conventional toothpaste; whitening toothpaste with abrasive agents; whitening toothpaste with abrasive and chemical agents; and whitening toothpaste with abrasive, chemical, and bleaching agents). Brushing and application of whitening gel were performed for 14 days. Surface microhardness (SMH), surface roughness (Ra), and color (ΔL*, Δa*, Δb, ΔE*ab, and ΔE00) were analyzed. The Ra and SMH data were analyzed using mixed generalized linear models for repeated measures, while the color results were assessed using the Kruskal-Wallis and Dunn tests. Results: Between the initial and final time points, all groups demonstrated significant increases in Ra and reductions in SMH. No significant differences were found between groups for SMH at the final time point, at which all groups differed from the distilled water group. Conventional toothpaste exhibited the lowest Ra, while whitening toothpaste with abrasive agent had the highest value. No significant differences were observed in ΔL*, Δa*, and Δb. Conclusions: While toothpaste composition did not affect the color stability and microhardness of resin composite, combining toothbrushing with whitening toothpaste and at-home bleaching enhanced the change in Ra.

플렉서블 플라즈마 패치에서 발생되는 활성종이 다당류 표면에 미치는 영향 (Effect of Active Species Generated from Flexible Plasma Patch on Polysaccharide Surface)

  • 이유리;이승훈;김도근
    • 한국표면공학회지
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    • 제51권2호
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    • pp.133-137
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    • 2018
  • Plasma devices such as jets, pencils, and torches have been developed as new tools that help penetration of target agents and applied to plasma medicine. However, these devices cannot be used in a large area. Therefore, we introduced a flexible plasma device, which can be treated of large area and designed as bendable plasma. In additional, in vitro model based on agarose gel was prepared that can be show effectiveness in the depth of penetration. Plasma treatment conditions such as power, time and distance can be optimized on the agarose gel wound model. The chemical structure of changed polysaccharides was predicted due to reactive excited atoms and molecules, UV photons, charged particles and reactive oxygen and nitrogen species (RONS).

계면활성제의 농도가 유하액막의 열전달 특성에 미치는 영향에 관한 실험적 연구 (An Experimental Study on Heat Transfer in a Falling Liquid Film with Surfactant)

  • 김경희;강병하;이대영
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.150-155
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    • 2006
  • Falling liquid plays a role in a wide variety of naturally occurring phenomena as well as in the operation of industrial process equipment where heat and mass transfer take place. In such cases, it is required that the falling film should spread widely on the surface forming thin liquid film to enlarge contact surface. An addition of surface active agent to a falling liquid film affects the flow characteristics of the falling film. In this study the heat transfer characteristics for a falling liquid film has been investigated by an addition of the surface active agents. The falling liquid film was formed on a vertical flat plate. As the mass flow rate of liquid falling film is increased, the wetted area is a little increased while the heat transfer rate as well as heat transfer coefficient is significantly increased. It is also found that both wetted area and heat transfer rate is substantially increased while heat transfer coefficient is a little increased with an increase in the surfactant concentration at a given mass flow rate.

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Kinetics of In-situ Degradation of Nerve Agent Simulants and Sarin on Carbon with and without Impregnants

  • Saxena, Amit;Sharma, Abha;Singh, Beer;Suryanarayana, Malladi Venkata Satya;Mahato, Timir Haran;Sharma, Mamta;Semwal, Rajendra Prasad;Gupta, Arvind Kumar;Sekhar, Krishnamurthy
    • Carbon letters
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    • 제6권3호
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    • pp.158-165
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    • 2005
  • Room temperature kinetics of degradation of nerve agent simulants and sarin, an actual nerve agent at the surface of different carbon based adsorbent materials such as active carbon grade 80 CTC, modified whetlerite containing 2.0 and 4.0 % NaOH, active carbon with 4.0 % NaOH, active carbon with 10.0 % Cu (II) ethylenediamine and active carbon with 10.0 % Cu (II) 1,1,1,5,5,5-hexafluoroacetylacetonate were studied. The used adsorbent materials were characterized for surface area and micropore volume by $N_2$ BET. For degradation studies solution of simulants of nerve agent such as dimethyl methylphosphonate (DMMP), diethyl chlorophosphate (DEClP), diethyl cyanophosphate (DECnP) and nerve agent, i.e., sarin in chloroform were prepared and used for the uniform adsorption on the adsorbent systems using their incipient volume at room temperature. Degradation kinetics was monitored by GC/FID and was found to be following pseudo first order reaction. Kinetics parameters such as rate constant and half life were calculated. Half life of degradation with modified whetlerite (MWh/NaOH) system having 4.0 % NaOH was found to be 1.5, 7.9, 1206 and 20 minutes for DECnP, DEClP, DMMP and sarin respectively. MWh/NaOH system showed maximum degradation of simulants of nerve agents and sarin to their hydrolysis products. The reaction products were characterized using NMR technique. MWh/NaOH adsorbent was also found to be active against sulphur mustard.

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Iron Oxide Nanoparticle-incorporated Alginate Capsules as Magnetic Field-assisted Potential Delivery Platforms for Agriculture Pesticides and Biocontrol Agents

  • Lee, Dohyeon;Choi, Kyoung Soon;Kim, Daun;Park, Sunho;Kim, Woochan;Jang, Kyoung-Je;Lim, Ki-Taek;Chung, Jong Hoon;Seonwoo, Hoon;Kim, Jangho
    • Journal of Biosystems Engineering
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    • 제42권4호
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    • pp.323-329
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    • 2017
  • Purpose: Biocompatible capsules have recently been highlighted as a novel platform for delivering various components, such as drug, food, and agriculture pesticides, to overcome the current limitations of living systems, such as those in agriculture, biology, the environment, and foods. However, few active targeting systems using biocompatible capsules and physical forces simultaneously have been developed in the agricultural engineering field. Methods: Here, we developed an active targeting delivery platform that uses biocompatible alginate capsules and controls movements by magnetic forces for agricultural and biological engineering applications. We designed and fabricated large-scale biocompatible capsules, using custom-made nozzles ejecting alginate solutions for encapsulation. Results: To develop the active target delivery platforms, we incorporated iron oxide nanoparticles in the large-scale alginate capsules. The sizes of alginate capsules were controlled by regulating the working conditions, such as concentrations of alginate solutions and iron oxide nanoparticles. Conclusions: We confirmed that the iron oxide particle-incorporated large-scale alginate capsules moved actively in response to magnetic fields, which will be a good strategy for active targeted delivery platforms for agriculture and biological engineering applications, such as for the controlled delivery of agriculture pesticides and biocontrol agents.

사과주(酒) 산막효묘(産膜酵母) Hansenula beijerinckii FY-5 의 소수성(疏水性)과 산막성(産膜性)과의 관련성(關聯性) (Relationship between Hydrophobicity and Pellicle Formation in a Film Strain of Hansenula beijerinckii FY-5 Isolated from Apple Wine)

  • 송형익;정기택
    • 한국식품과학회지
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    • 제17권3호
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    • pp.203-207
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    • 1985
  • 저장사과주에서 분리(分離) 동정(同定)한 산막효모(産膜酵母) Hansenula beijerinckii FY-5의 소수성(疎水性)과 피막형성(皮膜形成)과의 관계(關係)를 조사하였다. 비(非)이온계(系) 계면활성제(界面活性劑) 첨가에 의해 균생육(菌生育)은 가능(可能)하지만 피막(皮膜)이 전혀 형성(形成)되지 않으며 소수도(疎水度)도 크게 낮아지는 사실로 미루어 볼때, 피막형성(皮膜形成)에는 효모세포(醉母細胞)를 배지표면(表面)에 보존(保持)시키는 어떤 인자(因予)가 요구되며 그 인자(因子)가 바로 효모세포표면(酵償細胞表面)외 소수성(疎水性)이 아닌가 생각된다. 산막성효모(産膜性酵母)에 있어서는 소수도(疎水度)가 클수록 피막형성(皮膜形成)이 왕성하였으나 비산막성효모(非産膜性酵母)는 대체로 소수도(疎水度)가 낮았다. 탄소원이 에타놀일때 소수도(疎水度)가 높았으며 pH의 상승에 따라 소수도(疎水度)는 감소(減少)하는 경향이었다. 배양기간별로는 균생육(菌生育)과 더불어 소수도(疎水度)도 비례적으로 증가하여 정상기(正常期)에 최대치를 보였다.

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다중 에이전트 기반의 고대 국가 형성 시뮬레이션 (The Multi-Agent Simulation of Archaic State Formation)

  • S. Kim;A. Lazar;R.G. Reynolds
    • 한국시뮬레이션학회:학술대회논문집
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    • 한국시뮬레이션학회 2003년도 춘계학술대회논문집
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    • pp.91-100
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    • 2003
  • In this paper we investigate the role that warfare played In the formation of the network of alliances between sites that are associated with the formation of the state in the Valley of Oaxaca, Mexico. A model of state formation proposed by Marcos and Flannery (1996) is used as the basis for an agent-based simulation model. Agents reside in sites and their actions are constrained by knowledge extracted from the Oaxaca Surface Archaeological Survey (Kowalewski 1989). The simulation is run with two different sets of constraint rules for the agents. The first set is based upon the raw data collected in the surface survey. This represents a total of 79 sites and constitutes a minimal level of warfare (raiding) in the Valley. The other site represents the generalization of these constraints to sites with similar locational characteristics. This set corresponds to 987 sites and represents a much more active role for warfare in the Valley. The rules were produced by a data mining technique, Decision Trees, guided by Genetic Algorithms. Simulations were run using the two different rule sets and compared with each other and the archaeological data for the Valley. The results strongly suggest that warfare was a necessary process in the aggregations of resources needed to support the emergence of the state in the Valley.

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전착제 가용이 6-Benzylamino Purine의 사과묘목 덧가지 발생촉진에 미치는 영향 (Effects of Surface-active Agents to 6-Benzylamino Purine on Feathering of Maiden Apple Trees)

  • 윤태명;이재열;한수곤;우영재;최석원;김규래;신종길
    • 원예과학기술지
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    • 제19권1호
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    • pp.39-42
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    • 2001
  • 사과묘목의 덧가지 발생을 촉진하기 위하여 BAP 처리에 대한 전착제의 가용효과를 확인하기 위하여 Spreader 500ppm, Cover 500ppm, Spreadersticker 250ppm, Siloxane 350ppm, Tween 201%를 각각 BAP 400ppm에 가용하여 3회 처리한 다음 BAP 단용처리구와 덧가지 발생을 비교하였다. Tween 20을 제외하면 공시한 전착제는 모두 가용효과가 없었다. Tween 20의 적정 가용농도를 구명한 결과 0.2, 0.5, 0.8, 1.0% 모두 BAP 400ppm 단용 4회 처리에 비해 덧가지 발생이 현저히 많아 가용효과가 인정되었으나 농도간에는 뚜렷한 차이를 나타내지 않았다.

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작물 보호제로서 살균제와 살충제의 활성 성분에 대한 물리-화학 파라미터의 범위 (The Range of Physicochemical Parameters for the Active Ingredients of Fungicides and Insecticides as Crop Protection Agents)

  • 송선섭;성낙도
    • Applied Biological Chemistry
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    • 제46권4호
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    • pp.280-284
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    • 2003
  • 농업용 살균제와 살충제로서의 활용성 진단과 예측평가 자료로 사용하기 위하여 상용화 된 살균제 133품목과 살충제 152품목의 활성 성분들에 대하여 소수성(LogP), 쌍극자능율(DM), HOMO 및 LUMO 에너지, molar refractivity(MR), polarizability(Pol), van der Waals 분자 표면적 및 부피(Vol), 분자량 및 수화 에너지(hydralion energy) 등, 10 가지의 다양한 물리-화학 파라미터들을 계산하였다. 그리고 살균제와 sterol 생합성 저해제 (DMI: demethylation inhibitor) 및 살충제와 acetylcholine esterase 저해제(AChE)이 가지는 특정한 물리-화학 파라미터들의 범위 값을 설정하였다. 그 결과에 기초하여 다양한 화합물들이 작물 보호제로서 살균제와 살충제로의 활용 가능성이 예측될 것으로 판단되었다.

Modification of polyamide reverse osmosis membranes seeking for better resistance to oxidizing agents

  • Silva, Lucinda F.;Michel, Ricardo C.;Borges, Cristiano P.
    • Membrane and Water Treatment
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    • 제3권3호
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    • pp.169-179
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    • 2012
  • One of the major limitations in the use of commercial aromatic polyamide thin film composite (TFC) reverse osmosis (RO) membranes is to maintain high performance over a long period of operation, due to the sensitivity of polyamide (PA) skin layer to oxidizing agents, such as chlorine, even at very low concentrations in feed water. This article reports surface modification of a commercial TFC RO membrane (BW30-Dow Filmtec) by covering it with a thin film of poly(vinyl alcohol) (PVA) crosslinked with glutaraldehyde (GA) to improve its resistance to chlorine. Crosslinking reaction was carried out at 25 and $40^{\circ}C$ by using PVA 1.0 wt.% solutions at different GA/PVA mass ratio, namely 0.0022, 0.0043 and 0.013. Water swelling measurements indicated a maximum crosslinking density for PVA films prepared at $40^{\circ}C$ and GA/PVA 0.0043. ATR-FTIR and TGA analysis confirmed the reaction between GA and PVA. SEM images of the original and modified membranes were used to evaluate the surface coating. Chlorine resistance of original and modified membranes was evaluated by exposing it to an oxidant solution (NaClO 300 mg/L, NaCl 2,000 mg/L, pH 9.5) and measuring water permeability and salt rejection during more than 100 h period. The surface modification effectively was demonstrated by increasing the chlorine resistance of PA commercial membrane from 1,000 ppm.h to more than 15.000 ppm.h.