• Journal of the Korean institute of surface engineering
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• v.42 no.2
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• pp.95-101
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• 2009

This study is the research on the thermal emissivity depending on the bulk graphite's alignment degree. Bulk graphites were manufactured by uni-axial pressing and subsequent heat treatment of natural graphite flakes with organic binder. The samples were prepared to be $0^{\circ}$ (relative to the 002 c-face), $45^{\circ}$, and $90^{\circ}$ (relative to the 100 a-face) for measuring alignment degree. The alignment degree of the sample was measured by XRD. The thermal emissivity was measured by infrared thermal image camera at $100^{\circ}C$ and compared with the value obtained by Infrared spectroscopy. The alignment degree and thermal emissivity of $0^{\circ}$ sample were measured to be 0 and 0.70 respectively. And those of $90^{\circ}$ sample were 0.73 and 0.80 respectively. The emissivity value was correlated with obtained by IR spectroscopy. Therefore it was considered that the thermal emissivity of the bulk graphite is correlated with the alignment degree.

• Textile Coloration and Finishing
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• v.30 no.2
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• pp.77-89
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• 2018

In the case of fiber/rubber composites for tire applications, the interfacial adhesion between fiber and rubber significantly affects the physical properties of the finished products. Generally, organic synthetic fibers used for tire cords are treated with resorcinol formaldehyde latex(RFL) primer on the surface of the fiber to improve the adhesion to rubber. Changes of adhesion between rubber and tire cords might weaken as temperature rises due to overheating of car engine and friction with road. In this study, the effects of temperature on the primer treated polyketone cord/rubber composites and the changes in interfacial adhesion were investigated. Polyketone cord/rubber composites were prepared after RFL solution treatment on the surface of polyketone fibers. After that, composites was thermally aged at different temperature conditions(60, 80, 100, $120^{\circ}C$) and times(1, 5, 10, 15days). The adhesion strength of polyketone cord/rubber composite treated with RFL primer was higher than untreated composite by more than 3 times. After heat aging, the adhesion strength of untreated polyketone cord/rubber composites increased while the RFL treated polyketone cord/rubber composites decreased somewhat.

• Journal of Korean Society of Water Science and Technology
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• v.26 no.6
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• pp.13-26
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• 2018

This research was conducted to elucidate the removal mechanism of heavy metals and sulfate ion from acid mine drainage(AMD) by porous zeolite-slag ceramics (ZS ceramics) packed in a column reactor system. The average removal efficiencies of heavy metals and sulfate ion from AMD by the 1:3(Z:S) porous ZS ceramics in the column reactor under the HRT condition of 24 hours were Al 97.5%, As 98.8%, Cd 86.1%, Cu 96.2%, Fe 99.7%, Mn 64.1%, Pb 97.2%, Zn 66.7%, and $SO_4{^{2-}}$ 76.0% during 121 days of operation time. The XRD analysis showed that the ferric iron from AMD could be removed by adsorption and/or ion-exchange on the porous ZS ceramics. In addition it was known that Al, As, Cu, Mn, and Zn could adsorb or coprecipitate on the surface of Fe precipitates such as schwertmannite, ferrihydrite, or goethite. The EDS analysis revealed that Al, Fe, and Mn, which were of relatively high concentration in the AMD, would be adsorbed and/or ion-exchanged on the porous ZS ceramics and also exhibited that Al, Cu, Fe, Mn, and Zn could be precipitated as the form of metal hydroxide or sulfate and adsorbed or coprecipitated on the surface of Fe precipitates. The microscopic results on the porous ZS ceramics and precipitated sludge in a column reactor system suggested that the heavy metals and sulfate ion from AMD would be eliminated by the multiple mechanisms of coprecipitation, adsorption, ion-exchange as well as precipitation.

• The Journal of Korean Academy of Prosthodontics
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• v.42 no.3
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• pp.307-326
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• 2004

Statement of problem. The long-term success of implants is the development of a stable direct connection between bone and implant surface, which must be structural and functional. To improve a direct implant fixation to the bone, various strategies have been developed focusing on the surface of materials. Among them, altering the surface properties can modify cellular responses such as cell adhesion, cell motility and bone deposition. Purpose. This study was to evaluate the cellular behaviors on the surface-modified titanium by morphological observation, cellular proliferation and differentiation. Material and methods. Specimens were divided into five groups, depending on their surface treatment: electropolishing(EP) anoclizing(AN), machining(MA), blasting with hydroxyapatite particle(RBM) and electrical discharge machining(EDM). Physicochemical properties and microstructures of the specimens were examined and the responses of osteoblast-like cells were investigated. The microtopography of specimens was observed by scanning electron microscopy(SEM). Surface roughness was measured by a three-dimensional roughness measuring system. The microstructure was analyzed by X-ray diffractometer(XRD) and scanning auger electron microscopy(AES). To evaluate cellular responses to modified titanium surfaces, osteoblasts isolated from neonatal rat were cultured. The cellular morphology and total protein amounts of osteoblast-like cell were taken as the marker for cellular proliferation, while the expression of alkaline phosphatase was used as the early differentiation marker for osteoblast. In addition, the type I collagen production was determined to be a reliable indicator of bone matrix synthesis. Results. 1. Each prepared specimen showed specific microtopography at SEM examination. The RBM group had a rough and irregular pattern with reticulated appearance. The EDM-treated surface had evident cracks and was heterogeneous consisting of broad sheet or plate with smooth edges and clusters of small grains, deep pores or craters. 2. Surface roughness values were, from the lowest to the highest, electropolished group, anodized group, machined group, RBM group and EDM group. 3. All groups showed amorphous structures. Especially anodized group was found to have increased surface oxide thickness and EDM group had titaniumcarbide(TiC) structure. 4. Cells on electropolished, anodized and machined surfaces developed flattened cell shape and cells on RBM appeared spherical and EDM showed both. After 14 days, the cells cultured from all groups were formed to be confluent and exhibited multilayer proliferation, often overlapped or stratified. 5. Total protein amounts were formed to be quite similar among all the group at 48 hours. At 14 days, the electropolished group and the anodized group induced more total protein amount than the RBM group(P<.05). 6. There was no significant difference among five groups for alkaline phosphatase(ALP) activity at 48 hours. The AN group showed significantly higher ALP activity than any other groups at 14 days(P<.05). 7. All the groups showed similar collagen synthesis except the EDM group. The amount of collagen on the electropolished and anodized surfaces were higher than that on the EDM surface(P<.05).

• Journal of Korean Society of Water and Wastewater
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• v.22 no.1
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• pp.79-86
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• 2008

In Korea, most of the drinking water treatment relied upon the availability of the surface water, of which the raw water quality varied significantly by season and location. Therefore, the comparison of two operation modes (Pressurized type and Submerged type membrane system) must be estimated before the long-term establishment of two systems. In this study, two pilot-scale microfiltration systems with the capacity of $50m^3/day$ were installed and operated in two different modes, and the applicability of the system was determined based on the results such as the TMP (Trans-Membrane Pressure) and flux. For quantitatively comparing the two systems, a new concept, DRF (Differential Resistance Fraction) was introduced. The accumulated sum of the permeate after each cycle of chemical cleaning was also used as a tool for the system comparison.

• Fibers and Polymers
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• v.6 no.2
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• pp.121-126
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• 2005

Semicrystalline poly(ethylene terephthalate) (cPET)/amorphous poly(ethylene terephthalate) with isophthalic acid (aPET) blends with 100/0, 75/25, 50/50, 25/75, and 0/100 by weight ratios were dissolved in a mixture of trifluoroacetic acid (TFA)/methylene chloride (MC) (50/50, v/v) and electrospun via the electrospinning technique. Solution properties such as solution viscosity, surface tension and electric conductivity were determined. The solution viscosity slightly decreased as aPET content increased, while there was no difference in surface tension with respect to aPET composition. The characteristics of the electro spun cPET/aPET blend nonwovens were investigated in terms of their morphology, pore size and gas permeability. All these measurements were carried out before and after heat treatment for various blend weight ratios. The average diameter of the fibers decreased with increasing aPET composition due to the decrease in viscosity. Also, the morphology of the electrospun cPET/aPET blend nonwovens was changed by heat treatment. The pore size and pore size distribution varied greatly from a few nanometers to a few microns. The gas permeability after heat treatment was lower than that before heat treatment because of the change of the morphology.

• Environmental Engineering Research
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• v.21 no.2
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• pp.196-202
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• 2016

Membrane bioreactor (MBR) technology has previously been used by water industry to treat high salinity wastewater. In this study, an anoxic-oxic biofilm-membrane bioreactor (AOB-MBR) system has been developed to treat mustard tuber wastewater of 10% salinity (calculated as NaCl). To figure out the effects of operating conditions of the AOB-MBR on membrane fouling rate ($K_V$), response surface methodology was used to evaluate the interaction effect of the three key operational parameters, namely time interval for pump (t), aeration intensity ($U_{Gr}$) and transmembrane pressure (TMP). The optimal condition for lowest membrane fouling rate ($K_V$) was obtained: time interval was 4.0 min, aeration intensity was $14.6 m^3/(m^2{\cdot}h)$ and transmembrane pressure was 19.0 kPa. And under this condition, the treatment efficiency with different influent loads, i.e. 1.0, 1.9 and $3.3kgCODm^{-3}d^{-1}$ was researched. When the reactor influent load was less than $1.9kgCODm^{-3}d^{-1}$, the effluent could meet the third discharge standard of "Integrated Wastewater Discharge Standard". This study suggests that the model fitted by response surface methodology can predict accurately membrane fouling rate within the specified design space. And it is feasible to apply the AOB-MBR in the pickled mustard tuber factory, achieving satisfying effluent quality.

• Journal of Power System Engineering
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• v.21 no.3
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• pp.37-44
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• 2017

In this study, failure analysis of the angular pin for molding machines to aluminum component molding was carried out. SM45C steel was used for the angular pin, it was surface hardened by the induction surface hardening heat treatment. The cross section of damaged angular pin was observed, and micro Vickers hardness value from the fractured part was measured. Brittle fracture was occurred from the fracture surface of angular pin, therefore, impact toughness value was evaluated by V-notch Charpy impact test. It was confirmed that the impact absorption energy was high when was tempered at a high temperature for a long time, and the toughness was slightly increased. Also, 2-parameter Weibull statistical analysis was investigated in order to evaluate the reliability of the measured micro Vickers hardness values and absorbed energy. The micro Vickers hardness and absorbed energy well followed a two-parameter Weibull probability distribution, respectively. The reverse design against angular pin was proposed as possible by using test results.

• Applied Biological Chemistry
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• v.45 no.3
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• pp.145-151
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• 2002

Molinate, a thiolcarbamate herbicide widely used for control weeds in paddy soil, has been suspected for a possibile transportation into surface water due to its relatively high solubility in water. This study was performed to know that how much molinate could be removed during treatment processes for drinking water. The removal effciency of molinate in water was negligible in treatment process of polyaluminium chloride for coagulation. Molinate was gradually decreased up to 60.2% during contact time of 4 hours when chloride, an disinfectant used in water treatment system was treated. And in an hour treatment of ozone, molinate removal ranged $28.9%{\sim}58%$ However by treatment system of granular activated carbon, molinate was removed 93.9 to 100% at all concentrations used with a range of concentrations of granular activated carbon treated. The removal effciency of whole system simulated with removal efficiencies of molinate in each step of treatment processes was 99.5%. Therefore, if molinate happen to come into water treatment facilities, it could be removed effectively through the treatment processes.

• Journal of the Korean Society for Precision Engineering
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• v.23 no.7 s.184
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• pp.39-50
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• 2006

Laser heat treatment technologies have been used to improve characteristics of wear and to enhance the fatigue resistance for automotive parts. The bjective of this research work is to investigate the influence of the process parameters, such as power of laser and defocused spot position, on the characteristics of laser heat treatment for the case of SM45C medium carbon steel. CW Nd:YAG laser is selected as the heat source. The optical lens with the elliptical profile is designed to obtain a wide heat treatment area with a uniform hardness. From the results of the experiments, it has been shown that the maximum hardness is approximatly 780 Hv when the power and the travel of laser are 1,095 W and 0.6 m/min, respectively. In addition, the hardening width using the elliptical lens was three time larger than that using the defocusing of laser beam.