• 제목/요약/키워드: Surface shape measurement

검색결과 336건 처리시간 0.051초

플라즈모닉 금 나노입자의 흡광 특성을 활용한 생화학적 비색 분석법 연구 동향 (Recent Progress in Colorimetric Assays Using the Absorption of Plasmonic Gold Nanoparticles)

  • 김봉근;윤상빈;황수경;나현빈
    • 공업화학
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    • 제35권2호
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    • pp.67-78
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    • 2024
  • 흡광은 측정이 간편하고 해석의 직관성이 높다는 점에서 생화학 기반 분석법의 신호로서 강점을 가진다. 흡광을 가지는 물질 중에서 금 나노입자는 화학적 안정성, 생물학적 친화성, 가시광선 범위에서 야기되는 국소 표면 플라즈몬 공명(localized surface plasmon resonance, LSPR)에 의한 독특한 광학적 특성 등의 유용한 성질을 지니며, 특정 표적 물질에만 유효한 다른 발색물질과 비교해 항체나 압타머 등 다양한 검출 활성물질과 접합이 용이하여 확장성을 가진다. 특히, 기질의 산화로 발색을 야기하는 효소 기반 발색법에 비해 낮은 가격, 쉬운 입자 합성, 높은 환경안정성 등의 장점으로 인해 비색화 분석법의 신호물질로서 광범위하게 연구되고 있다. 본 총설에서는 이와 같은 금 나노입자를 신호물질로 활용하는 다양한 전략을 최근의 연구들을 중심으로 요약 정리하였으며, 입자의 형태에 광학 특성이 영향을 받는 금 나노입자의 특징에 착안하여 신호생성 시에 활용한 금 나노입자의 형태 제어 전략을 기준으로 문헌들을 분류하고 검토하였다. 이를 통해 이미 오랜 기간 활용되어온 금 나노입자가 현재에도 흡광 신호물질로서 여전히 활발하게 연구되고 있다는 사실을 고찰하고, 향후에도 광범위하고 지속적으로 개선될 여지를 가진다는 점을 확인하였다.

상아질과 Gutta-Percha에 대한 근관충전용 Sealer의 결합강도의 측정 (MEASUREMENT OF ADHESION OF ROOT CANAL SEALER TO DENTINE AND GUTTA-PERCHA)

  • 허미자;유미경;이세준;이광원
    • Restorative Dentistry and Endodontics
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    • 제28권1호
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    • pp.89-99
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    • 2003
  • The purpose of this study was to investigate the bonding of resin- based root canal sealer, AH26 when the sealer was applied as a thin layer between dentine and gutta-percha surface. In this study forty non-caries extracted human molars and resin-based root canal sealer(AH 26, DeTrey/Dentsply, Germany) were used. Disks of gutta-percha, 6mm in diameter.6mm thick (Diadent/Dentsply, Korea) for thermoplastic obturation were used and dentin surfaces were treated with 2% NaOCl(Group 1) or 2%NaOCl+17% EDTA(Group 3). Disks of gutta-Percha, 6mm in diameter.6mm thick (Diadent/Dentsply, Korea) for conventional obturation were used and dentin surface were treated with 2% NaOCl(Group 2) or 2%NaOCl+17% EDTA(Group 4). Enamel was removed by a horizontal section 1mm below the deepest portion of the central occlusal groove by using a watercooled low speed diamond saw. A second horizontal section was done around cementoenamel junction. Exposed dentin surface was cut to approximately $8{\times}8{\;}mm$ rectangular shape and was ground against 320, 400, 600 grade silicon carbide abrasive paper serially. After grinding, the dentine surface were soaked in a solution of 2% NaOCl for 30 minutes and twenty of specimens were treated with 17% EDTA solution for 1 minute. The treated specimens were washed and dried, Root canal sealer, AH26 was prepared according to the manufacture's instructions The Gutta-percha and dentin surface were coated with a thin layer of the freshly mixed seal or. The specimens were left overnight at room temperature. After their initial set, they were transferred to an incubator at $37$^{\circ}C$ for 72 h. After 72 hours, resin blocks were made. The resin block was serially sectioned vertically into stick of $1{\cdot}1mm$. Twenty sticks were prepared from each group. After that, tensile bond strength f3r each stick was measured with Microtensile Tester Failure patterns of the specimens at the interface between gutta-percha and dentin were observed under the SEM(x1000) and Stereomicroscope (LEICA M42O, Meyer Inst., TX U.S.A) at 1.25 x25 magnification. The results were statistically analysed by using a One-way ANOVA and Tukey's test. The results were as follows; 1. Tensile bond strengths($mean{\pm}SD$) were expressed with ascending order as follows: Group 1, $3.09{\pm}$ 1.05Mpa : Group 2, $6.23{\pm}1.16MPa$ : Group 3, $7.12{\pm}1.07MPa$ : Group 4, $10.32{\pm}2.06MPa$. 2. Tensile bond strengths of the group 2 and 4 used disks of gutta-percha for conventional obturation were significantly higher than that of the group 1 and 3 used fir thermoplastic obturation. (p < 0.05). 3. Tensile bond strengths of the group 3 and 4 treated with 2% NaOC1+17% EDTA were significantly higher than that of the group 1 and 2 treated with 2% NaOCl. (p < 0.05). 4. In analysis of failure patterns at the interface between sealer and gutta-percha, there were observed 49 (61%)cases of adhesive failure patterns and 31 (39%) cases of mixed failures patterns.

비접촉 초음파 탐상기법을 이용한 스폿용접부 및 탄소복합체의 내부 결함평가 (Internal Defection Evaluation of Spot Weld Part and Carbon Composite using the Non-contact Air-coupled Ultrasonic Transducer Method)

  • 곽남수;이승철
    • 한국산학기술학회논문지
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    • 제15권11호
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    • pp.6432-6439
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    • 2014
  • NAUT(Non contact Air coupled Ultrasonic Testing)기법은 초음파 탐상법 중의 하나로서 공기중 음향 임피던스의 차이로 생기는 에너지 손실을 High Power 초음파 Pulser Receiver, PRE-AMP, 고감도의 탐촉자로 보완하여 비접촉식으로 초음파 탐상을 가능하게 하는 탐상 방법이다. NAUT는 초음파의 송신 및 수신이 안정된 상태에서 이루어지므로 기존의 접촉식 탐상으로는 불가능하였던 고온, 저온의 물질이나 시험편의 표면이 거친 부분, 좁은 지점 등에서도 탐상이 가능하다. 본 연구에서는 NAUT기법의 산업체 실용여부를 알아보기 위해 자동차생산 공정에서 많이 사용하는 스폿용접부 및 CFRP 제품에 있어 상용화 연구를 통해 다음과 같은 결과를 얻었다. 본 연구에서는 NAUT기법의 사용 여부를 알아보기 위해 자동차 부품에서 많이 사용하는 스폿용접부 및 CFRP 부품의 내부결함 검출을 검출하였다. 스폿용접부에서는 초음파의 투과율이 높아 적색으로 나타났으며, 복층으로 된 부분은 투과율이 낮아 청색 화상이 나타났다. 또한 측정 속도를 결정하는 중요요소인 PRF(Pulse Repetition Frequency;송신펄스주기)에 따라 색상 선명도의 차이를 보였다. CFRP 시험편 또한 화상장치를 통해 취득된 각 화상 결과를 보고 내부 결함의 모양, 크기, 위치 등의 파악이 단시간에 가능하였다. 실험을 통해 NAUT기법과 화상화가 동시에 이루어짐을 확인하였고, 스폿 용접부와 CFRP 탐상에 NAUT의 적용이 가능한지 그 실현여부를 확인하였다.

Morphometric analysis of maxillary alveolar regions for immediate implantation

  • Park, Man-Soo;Park, Young-Bum;Choi, Hyunmin;Moon, Hong-Seok;Chung, Moon-Kyu;Cha, In-Ho;Kim, Hee-Jin;Han, Dong-Hoo
    • The Journal of Advanced Prosthodontics
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    • 제5권4호
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    • pp.494-501
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    • 2013
  • PURPOSE. The purpose of this study was to provide an actual guideline in determining the shape, diameter, and position of the implant in immediate implantation by the measurement of the thickness of facial and palatal plate, the thickness of cortical bone on the facial and palatal plate, the diameter of the root, and the distance between the roots in the cadavers. MATERIALS AND METHODS. The horizontal sections of 20 maxillae were measured and analyzed to obtain the average values. Resin blocks were produced and cut serially at 1 mm intervals from the cervical line to the root apex. Images of each section were obtained and the following measurements were performed: The thickness of the facial and palatal residual bone at each root surface, the thickness of the facial and palatal cortical bone at the interdental region, the diameter of all roots of each section on the faciopalatal and mesiodistal diameter, and the interroot distance. Three specimens with measurements close to the average values were chosen and 3-dimensional images were reconstructed. RESULTS. The thickness of the facial and palatal cortical bone at the interdental region in the maxilla, the buccal cortical bone was thicker in the posterior region compared to the anterior region. The interroot distance of the alveolar bone thickness between the roots increased from anterior to posterior region and from coronal to apical in the maxilla. CONCLUSION. In this study, the limited results of the morphometric analysis of the alveolar ridge using the sections of maxilla in the cadavers may offer the useful information when planning and selecting optimal implant for immediate implantation in the maxilla.

아르곤 상압플라즈마를 이용한 CNT 코팅 공정 기술 개발 (Development of CNT Coating Process using Argon Atmospheric Plasma)

  • 김경보;이종필;김무진
    • 산업융합연구
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    • 제20권10호
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    • pp.33-38
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    • 2022
  • 본 논문에서는 용액 기반의 탄소나노튜브(CNT: Carbon Nano-tube)를 전자기기의 전도성 소재로 사용하기 위하여 쉽고 빠르게 형성하는 방법에 대해 연구하였다. 이를 위해 스핀 코팅 방법 및 아르곤 상압플라즈마 공정을 적용하여 글라스 위에 CNT 박막 코팅을 진행하였다. 코팅 횟수에 따른 전기적, 물리적 특성 변화를 관찰하기 위하여 1회부터 5회까지 동일한 방법으로 형성된 샘플을 제작하였고, 각 샘플에 대해 표면 형상, 반사도, 투과도, 흡수율 및 표면 저항을 측정하였다. 현미경을 이용하여 관찰했을 때 횟수가 늘어날 때 글라스 상에 검은 형상이 더 잘 관찰되며, 특히 스핀코팅에 의해 가운데 영역이 더 검게 관찰되는 것을 알 수 있다. 코팅 수가 증가함에 따라 측정 파장의 전 영역에서 투과도는 감소, 반사도 및 흡수율은 증가하였다. 또한, 파장이 감소함에 따라 투과율은 감소, 반사도 및 흡수율은 증가한다. 전기적인 특성의 경우, 2번 코팅했을 때 전도도가 상당히 향상됨을 확인할 수 있었으며, 추가 코팅에 의해서 전도도 감소가 관찰되지만, 큰 변화를 보이지는 않았다. 결론적으로 CNT를 투명전극으로 대체하기 위해서는 반사도 및 전기전도도를 함께 고려하여 코팅 횟수를 고려해야 하며, 2회가 최적임을 알 수 있다.

무작위 격자 모델을 이용한 파이버 보강 콘크리트의 건조수축 균열 거동 해석 (Simulation of Cracking Behavior Induced by Drying Shrinkage in Fiber Reinforced Concrete Using Irregular Lattice Model)

  • 김근휘;박종민;;임윤묵
    • 대한토목학회논문집
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    • 제30권4A호
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    • pp.353-359
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    • 2010
  • 시멘트계 기질을 사용하는 복합재료는 재료 양생 과정에서 발생하는 건조수축 균열에 취약하다. 본 연구에서는 파이버 보강 콘크리트의 건조수축에 의한 파괴 거동을 시뮬레이션 하고, 파이버의 조건이 균열 특성에 미치는 영향에 대해 분석한다. 수치 해석 모델은 무작위 격자 형태의 기하학적 구조를 공유하는 관로 요소와 rigid-body-spring 요소로 구성되는데, 각 요소가 담당하는 비역학적-역학적 거동의 커플링에 의해 건조수축이 표현된다. 파이버 보강을 모델링하기 위해 rigid-bodyspring network 내부의 semi-discrete 파이버 요소를 적용하였다. KS F 2424 자유 건조수축 실험을 해석하고 시간에 따른 건조수축 변형률 변화를 비교함으로써 재료의 건조수축 관련 계수들을 산정한다. 다음으로 여러 파이버 혼입률에 대해 KS F 2595 구속 건조수축 실험을 시뮬레이션 하고 균열 발생 일자를 선행 실험 결과와 비교하여 해석 모델의 타당성을 검증한다. 또한, 파이버의 길이와 표면 형태를 변화시켜 건조수축 균열 해석을 수행하고 최대 균열 폭을 측정하여 시뮬레이션에서 나타나는 균열 제어 효과를 판단한다.

구면조화해석(球面調和解析)에 의(依)한 한반도내(韓半島內)의 지구자기장(地球磁氣場)의 분포(分布)에 관(關)한 연구(硏究) (Geomagnetic Field Distribution in the Korean Peninsula by Spherical Harmonic Analysis)

  • 민경덕;이선희
    • 자원환경지질
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    • 제12권2호
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    • pp.95-104
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    • 1979
  • The position of any point on the earth's surface can be. represented in the spherical coordinates by surface spherical harmonics. Since geomagnetic field is a function of position on the earth, it can be also expressed by spherical harmonic analysis as spherical harmonics of trigonometric series of $a_m({\theta})$ cos $m{\phi}$ and $b_m({\theta})$ sin $m{\phi}$. Coefficients of surface spherical harmonics, $a_m({\theta})$ and $b_m({\theta})$, can be drawn from the components of the geomagnetic field, declination and inclination, and vice versa. In this paper, components of geomagnetic field, declination and inclination in the Korean peninsula are obtained by spherical harmonic analysis using the Gauss coefficients calculated from the world-wide magnetic charts of 1960. These components correspond to the values of normal geomagnetic field having no disturbances of subsurface mass, structure, and so on. The vertical and total components offer the zero level for the interpretation of geomagnetic data obtained by magnetic measurement in the Korean peninsula. Using this zero level, magnetic anomaly map is obtained from the data of airborne magnetic. prospecting carried out during 1958 to 1960. The conclusions of this study are as follows; (1) The intensity of horizontal component of normal geomagnetic field in Korean peninsula ranges from $2{\times}10^4$ gammas to $2.45{\times}10^4$ gammas. It decreases about 500 with the increment of $1^{\circ}$ in latitude. Along the same. latitude, it increases 250 gammas with the increment of $1^{\circ}$ in longitude. (2) Intensity of vertical component ranges from $3.85{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases. about 1000 gammas with the increment of $1^{\circ}$ in latitude. Along the same latitude, it decreases. 150~240 gammas with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude than in lower latitude. (3) Total intensity ranges from $4.55{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases 600~700 gammas with the increament of $1^{\circ}$ in latitude. Along the same latitude, it decreases 10~90 gammas. with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude as the case of vertical component. (4) The declination ranges from $-3.8^{\circ}$ to $-11.5^{\circ}$. It increases $0.6^{\circ}$ with the increment of $1^{\circ}$ in latitude. Along the same latutude, it increases $0.6^{\circ}$ with the increment of l O in longitude. Unlike the cases of vertical and total component, the rate of change is considerably larger in lower latitude than in higher latitude. (5) The inclination ranges from $57.8^{\circ}$ to $66.8^{\circ}$. It increases about $1^{\circ}$ with 'the increment of $1^{\circ}$ in latitude Along the same latitude, it dereases $0.4^{\circ}$ with the increment of $1^{\circ}$ in longitude. (6) The Boundaries of 5 anomaly zones classified on the basis of the trend and shape of anomaly curves correspond to the geologic boundaries. (7) The trend of anomaly curves in each anomaly zone is closely related to the geologic structure developed in the corresponding zone. That is, it relates to the fault in the 3rd zone, the intrusion. of granite in the 1st and 5th zones, and mountains in the 2nd and 4th zones.

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곡립(穀粒)의 치수, 표면적(表面積) 및 체적(體積)에 관(關)한 연구(硏究) (A Study on the Dimensions, Surface Area and Volume of Grains)

  • 박종민;김만수
    • 농업과학연구
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    • 제16권1호
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    • pp.84-101
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    • 1989
  • 본(本) 연구(硏究)의 공시(供試) 곡물(穀物)로서 벼 6 품종(品種)(Japonica 3 품종(品種), Indica ${\times}$ Japonica 3 품종(品種)), 콩 2 품종(品種), 밀 2 품종(品種), 보리 2 품종(品種)을 택(澤)하였다. 함수율(含水率)은 약(約) 13%~27%(w.b.)까지 4 수준(水準)으로 변화(變化)시키면서 곡립(穀粒)의 크기, 표면적(表面積) 및 체적(體積)을 각(各) 품종(品種) 및 함수율(含水率) 각(各) 수준(水準)에서 10~15반부(反復)으로 측정(測定)하여 함수율(含水率) 변화(變化)가 이들에 미치는 영향(影響)을 분석(分析)하고, 곡립(穀粒)의 주요(主要) 치수와 체적(體積) 및 표면적(表面積)과의 상호관계(相互關係), 체적(體積)을 인자(因子)로 하는 표면적(表面積)의 예측식(豫測式)에 관(關)한 연구(硏究) 결과(結果)를 요약(要約)하면 다음과 같다. 1. 본(本) 연구(硏究)에서 적용(適用)한 표면적(表面積) 및 체적(體積)의 측정(測定) 방법(方法)을 검정(檢定)하기 위(爲)하여 이론적(理論的)으로 계산(計算)이 가능(可能)한 0.0375m인 탁구(卓球)공으로 그 표면적(表面積)과 체적(體積)을 측정(測定)했던 결과, 회전각(回轉角) 증분(增分)을 $15^{\circ}$로 했을때 공식(公式)에 의한 계산치(計算値)와의 오차(誤差)가 각각(各各) 0.65% 및 0.77% 이었다. 2. 벼의 일반계(一般系)와 다수계(多收系) 사이와 콩, 밀의 품종간(品種間)에 본(本) 연구(硏究)에서 대상(對象)으로한 물리량(物理量)들에 대(對)하여 t-test한 결과(結果), 벼의 두 계통(系統)사이와 콩, 밀의 품종간(品種間)에는 5%의 유의수준(有意水準)에서 그 차이(差異)가 인정(認定)되었다. 3. 곡립(穀粒)의 길이, 폭, 두께는 함수율(含水率)의 증가(增加)에 따라 직선적(直線的)으로 증가(增加)하였으며, 길이와 두께의 비(比)(L/T)와 폭과 두께의 비(比)(W/T)는 벼의 모든 품종(品種)에서 함수율(含水率)의 증가(增加)에 따라 감소(減少)하는 반면(反面), 콩에서는 모두 증가(增加)했다. 그러나 밀, 보리에서는 품종(品種)에 따라 일률적(一律的)인 경향(傾向)이 나타나지 않았다. 4. 공시(供試) 곡립(穀粒)의 표면적(表面積)은 일반계(一般系) 벼 약(約) $45{\sim}51{\times}10^{-6}m^2$, 다수계(多收系) 벼 $42{\sim}47{\times}10^{-6}m^2$, 장엽콩 약(約) $188{\sim}200{\times}10^{-6}m^2$, 황금콩 약(約) $180{\sim}201{\times}10^{-6}m^2$, 대맥(大麥) 약(約) $60{\sim}69{\times}10^{-6}m^2$, 나맥(裸麥) 약(約) $47{\sim}60{\times}10^{-6}m^2$, 은파밀 약(約) $51{\sim}20{\times}10^{-6}m^2$, 그루밀은 약(約) $57{\sim}69{\times}10^{-6}m^2$ 이었으며, 체적(體積)은 일반계(一般系) 벼 약(約) $25{\sim}30{\times}10^{-9}m^3$ 다수계(多收系) 벼 약(約) $21{\sim}26{\times}10^{-9}m^3$, 장엽콩 약(約) $277{\sim}300{\times}10^{-9}m^3$, 황금콩 약(約) $190{\sim}253{\times}10^{-9}m^3$, 대맥(大麥) 약(約) $36{\sim}45{\times}10^{-9}m^3$, 나맥(裸麥) 약(約) $22{\sim}28{\times}10^{-9}m^3$, 은파일 약(約) $23{\sim}31{\times}10^{-9}m^3$, 그루밀 약(約) $27{\sim}34{\times}10^{-9}m^3$이었다. 5. 함수율(含水率)에 따른 표면적(表面積) 및 체적(體積)의 증가율(增加率)은 콩이 가장 컸고, 다음은 밀, 보리, 벼 순(順) 이였으며, 벼에서는 일반계(一般系) 벼가 다수계(多收系) 벼 보다 약간(若干) 높게 나타났다. 6. 함수율(含水率) 변화(變化)에 따른 곡립(穀粒)의 크기(결이, 폭, 두께), 표면적(表面積) 및 체적(體積)에 대한 1차(次) 회귀(回歸) 방정식(方程式), 곡립(穀粒)의 길이, 폭, 두께를 인자(因子)로 하는 표면적(表面積) 및 체적(體積)에 대한 지수(指數) 방정식(方程式)과 곡립(穀粒)의 체적(體積)을 인자(因子)로 하는 표면적(表面積)의 회귀(回歸) 방정식(方程式)을 공시(供試) 곡물(穀物) 및 품종별(品種別)로 각각(各各) 유도(誘導)하였다.

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Flowable Composite Resin의 미세변연누출 및 전단결합강도 (MICROLEAKAGE AND SHEAR BOND STRENGTH OF FLOWABLE COMPOSITE RESIN)

  • 박성준;오명환;김오영;이광원;엄정문;권혁춘;손호현
    • Restorative Dentistry and Endodontics
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    • 제26권4호
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    • pp.332-340
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    • 2001
  • Flowable composite resin has lower filler content, increased flow, and lower modules of elasticity. It is suggested that flowable composite resin can be bonded to the tooth structure intimately and absorb or dissipate the stress. Therefore, it may be advantageous to use flowable composite resin for the base material of class II restoration and for the class V restoraton. The purpose of this study was to evaluate the microleakage and shear bond strength of four flowable composite resins (Aeliteflo, Flow-It, Revolution, Ultraseal XT Plus) compared to Z100 using Scotchbond Multi Purpose dentin bonding system. To evaluate the microleakage, notch-shaped class V cavities were prepared on buccal and lingual surfaces of 80 extracted human premolars and molars on cementum margin. The teeth were randomly divided into non-thermocycling group (group 1) and thermocycling group (group 2) of 40 teeth each. The experimental teeth of each group were randomly divided onto five subgroups of eight samples (sixteen surfaces). The Scotchbond Multi-Purpose and composite resin were applied for each group following the manufacturer's instructions. the teeth of group 2 were thermocycled five hundred times between 5$^{\circ}C$ and 55$^{\circ}C$. The teeth of group 2 were placed in 2% methylene blue dye for 24 hours, then rinsed with tab water. The specimens were embedded in clear resin, and sectioned longitudinally with a diamond saw. The dye penetration on each of the specimen were observed with a stereomicioscope at $\times$20 magnification. To evaluate the shear bond strength, 60 teeth were divided into five groups of twelve teeth each. The experimental teeth were ground horizontally below the dentinoenamel junction, so that no enamel remained. After applying Scotchbond Multi-Purpose on the dentin surface, composite resin was applied in the shape of cylinder. The cylinder was 4mm in diameter and 2mm in thickness. Shear bond strength was measured using Instron with a cross-head speed of 0.5mm/min. After shear bond strength measurement, mode of failure was evaluated with a stereomicroscope at $\times$30 magnification. All data were statistically analyzed by One Way ANOVA and Student-Newman-Keuls method. The correlation between microleakage and shear bond strength was analyzed by linear regression. The results of this study were as follows ; 1. In non-thermocycling group, the leakage value of Z100 was significantly lower than those of flowable composite resins at the enamel and dentin margin, margin, except that Revolution showed the lower leakage value than that of Z100 at the dentin margin (p<0.05). 2. In thermocycling group, the leakage values of Z100 and Ultraseal XT Plus were lower than those of other subgroup at the enamel and dentin margin, except that Flow-It showed the lower leakage value than that of Ultraseal XT Plus at the dentin margin (p<0.05). 3. The leakage value of Z100 and Ultraseal XT Plus in thermocycling group were not higher than that in non-thermocycling group at the enamel margin. The leakage value of Z100 in thermocycling group was not higher than that in non-thermocycling group at the dentin margin (p<0.05). 4. As for the shear bond strength measurement, there were no statistically significant differences among groups (p<0.05). The shear bond strengths given in descending order were as follows: Z100(16.81$\pm$2.98 MPa), Flow-It(14.8$\pm$4.43 MPa), Aeliteflo(14.34$\pm$3.69 MPa), Revolution(13.46$\pm$4.23 MPa), Ultraseal XT Plus(12.83$\pm$3.16 MPa). 5. Failure modes of all specimens were adhesive failures. 6. There was no correlation between microleakage and shear bond strength.

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The intrinsic instabilities of fluid flow occured in the melt of Czochralski crystal growth system

  • Yi, Kyung-Woo;Koichi Kakimoto;Minoru Eguchi;Taketoshi Hibiya
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.179-200
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    • 1996
  • The intrinsic instabilities of fluid flow occurred in the melt of the Czochralski crystal growth system Czochralski method, asymmetric flow patterns and temperature profiles in the melt have been studied by many researchers. The idea that the non-symmetric structure of the growing equipment is responsible for the asymmetric profiles is usually accepted at the first time. However further researches revealed that some intrinsic instabilities not related to the non-symmetric equipment structure in the melt could also appear. Ristorcelli had pointed out that there are many possible causes of instabilities in the melt. The instabilities appears because of the coupling effects of fluid flow and temperature profiles in the melt. Among the instabilities, the B nard type instabilities with no or low crucible rotation rates are analyzed by the visualizing experiments using X-ray radiography and the 3-D numerical simulation in this study. The velocity profiles in the Silicon melt at different crucible rotation rates were measured using X-ray radiography method using tungsten tracers in the melt. The results showed that there exits two types of fluid flow mode. One is axisymmetric flow, the other is asymmetric flow. In the axisymmetric flow, the trajectory of the tracers show torus pattern. However, more exact measurement of the axisymmetrc case shows that this flow field has small non-axisymmetric components of the velocity. When fluid flow is asymmetric, the tracers show random motion from the fixed view point. On the other hand, when the observer rotates to the same velocity of the crucible, the trajectory of the tracer show a rotating motion, the center of the motion is not same the center of the melt. The temperature of a point in the melt were measured using thermocouples with different rotating rates. Measured temperatures oscillated. Such kind of oscillations are also measured by the other researchers. The behavior of temperature oscillations were quite different between at low rotations and at high rotations. Above experimental results means that the fluid flow and temperature profiles in the melt is not symmetric, and then the mode of the asymmetric is changed when rotation rates are changed. To compare with these experimental results, the fluid flow and temperature profiles at no rotation and 8 rpm of crucible rotation rates on the same size of crucible is calculated using a 3-dimensional numerical simulation. A finite different method is adopted for this simulation. 50×30×30 grids are used. The numerical simulation also showed that the velocity and flow profiles are changed when rotation rates change. Futhermore, the flow patterns and temperature profiles of both cases are not axisymmetric even though axisymmetric boundary conditions are used. Several cells appear at no rotation. The cells are formed by the unstable vertical temperature profiles (upper region is colder than lower part) beneath the free surface of the melt. When the temperature profile is combined with density difference (Rayleigh-B nard instability) or surface tension difference (Marangoni-B nard instability) on temperature, cell structures are naturally formed. Both sources of instabilities are coupled to the cell structures in the melt of the Czochralski process. With high rotation rates, the shape of the fluid field is changed to another type of asymmetric profile. Because of the velocity profile, isothermal lines on the plane vertical to the centerline change to elliptic. When the velocity profiles are plotted at the rotating view point, two vortices appear at the both sides of centerline. These vortices seem to be the main reason of the tracer behavior shown in the asymmetric velocity experiment. This profile is quite similar to the profiles created by the baroclinic instability on the rotating annulus. The temperature profiles obtained from the numerical calculations and Fourier transforms of it are quite similar to the results of the experiment. bove esults intend that at least two types of intrinsic instabilities can occur in the melt of Czochralski growing systems. Because the instabilities cause temperature fluctuations in the melt and near the crystal-melt interface, some defects may be generated by them. When the crucible size becomes large, the intensity of the instabilities should increase. Therefore, to produce large single crystals with good quality, the behavior of the intrinsic instabilities in the melt as well as the effects of the instabilities on the defects in the ingot should be studied. As one of the cause of the defects in the large diameter Silicon single crystal grown by the

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